Determination of some heavy metals in vegetable garden soil and waste dumpsite soil in Mubi North, Adamawa State, Nigeria

2019 ◽  
Vol 11 (3) ◽  
Author(s):  
Z.B. Mshelia
Keyword(s):  
Heavy Metals ◽  
Health Effect ◽  
Soil Samples ◽  
Permissible Limit ◽  
World Health ◽  
Garden Soil ◽  
Acid Mixture ◽  
Different Depths ◽  
Vegetable Garden Soil

Abstract. A research conducted on soil samples using different depths were carried out on the determination of heavy metals (Pb, Cu, Zn, Ni, Cd and As) in Wuro-Gude vegetable garden soil and waste dumpsite soil, Mubi Metropolis Adamawa State, Nigeria. The soil samples were collected on different depths and were transported to the department of animal production laboratory for digestion. The mixtures were digested with tri-acid mixture (HNO3: HCO4: H2SO4) and determination of the heavy metals was done using a Buck Scientific 200A Model, Atomic Absorption Spectrophotometer (AAS). It was found that the heavy metals concentration in both types of soils at the depth of 5, 15 and 25cm was as follows: a) Vegetable garden soil: Ni – 7.33mg/g, 5.06mg/g and 3.04mg/g; Zn – 16.31mg/g, 13.08mg/g and 8.37mg/g; Cu – 6.94mg/g, 4.77mg/g and 3.28mg/g; Pb – 1.07mg/g, 0.57mg/g and 0.42mg/g and Cd – 0.35mg/g, 0.31mg/g and 0.29mg/g, respectively; As was not detected in all the depths; b) Waste dumpsite soil: Ni – 6.75mg/g, 4.33mg/g and 1.95mg/g; Zn – 14.67mg/g, 12.55mg/g and 9.04mg/g; Cu – 8.34mg/g, 5.72mg/g and 3.82mg/g; Pb – 2.15mg/g, 1.06mg/g and 0.67mg/g and Cd – 0.68mg/g, 0.57mg/g and 0.84mg/g, respectively; As was not detected in all the samples. All measured heavy metals concentrations were within the permissible limit set by the World Health Organization, except Cd which was above the permissible limit in waste dumpsite soil. Therefore, waste dumpsite soil should not be used for farming and effort should be made to educate the public on the health effect of these metals when ingested, to avoid bioaccumulation and biomagnification in the food chain.

scholarly journals Determination of Molybdenum Contents and Relation of Some Heavy Metals in the Soil of Meadow-Pasture Terraces Between Kırıkhan-Reyhanlı

2019 ◽  
Vol 7 (1) ◽  
pp. 13 ◽  
Author(s):  
Mehmet Yalçın ◽  
Kerim Mesut Çimrin
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Pollution ◽  
Soil Samples ◽  
Molybdenum Content ◽  
Limit Values ◽  
Significant Relationships ◽  
Metal Contents ◽  
Different Depths

This study was aimed to determine the molybdenum content of meadow - pasture soil between Kırıkhan and Reyhanlı in Hatay province and to determine the relations of the molybdenum content with some heavy metals in the soil. For this purpose, two different depths (0-20 and 20-40 cm) representing grassland pasture lands and 80 soil samples from 40 different points were taken. Cadmium (Cd), Cobalt (Co), Nickel (Ni), Lead (Pb), Copper (Cu), Iron (Fe), and Molybdenum (Mo) contents were determined in the soil samples. The contents of the available Cd, Co, Pb, Cu, Fe, Ni and Mo of the soil were determined by reading the 0.005 M DTPA + 0.01 M CaCl2 + 0.1 M TEA extracts in the ICP instrument. The results of the research shows that the Cd contents of the soils are between 0.01-0.32 ppm; Co contents are from 0.01 to 4.97 ppm; Ni contents 0.00 to 20.00 ppm; Pb contents 3.00-67.00 ppm; Cu contents 0.26-7.48 ppm; The Fe contents are between 4.00 and 61.00 and the Mo contents are between 0.001 and 0.064 ppm. It was determined that there are significant positive relationships between Co, Ni, Pb, Cu and Fe contents of Mo in the soil. It was also determined that there are significant positive significant relationships between Cd and Co; Co with Ni, Pb, Fe and Pb and Cu, Fe and Cu and Fe. No heavy metal pollution was found when the heavy metal contents of the regional soils were compared with the limit values.

scholarly journals Assessment of some heavy metals concentrations in soil and groundwater around refuse dumpsite in Ibadan Metropolis, Nigeria

2020 ◽  
Vol 39 (1) ◽  
pp. 301-305
Author(s):  
I.O. Saheed ◽  
S.O. Azeez ◽  
A.A. Jimoh ◽  
V.A. Obaro ◽  
S.A. Adepoju
Keyword(s):  
Heavy Metals ◽  
Ground Water ◽  
Atomic Absorption Spectrophotometry ◽  
Soil Samples ◽  
World Health ◽  
Heavy Metal Concentrations ◽  
Absorption Spectrophotometry ◽  
Dug Wells ◽  
Health Organization

This study reports the determination of some heavy metals’ concentration in soil and groundwater around refuse dumpsites in five locations in Ibadan Metropolis, Nigeria. Five samples were collected from each soil and ground water locations and analysed for heavy metals(Cd, Co, Pb, Cr, Zn, Mn and Ni)using Atomic Absorption Spectrophotometry. The soil samples were obtained in triplicates at 25cm depth intervals whereas the water samples were obtained from hand dug wells less than 10 m deep. The range of the values of heavy metal concentrations obtained in water is Co (0.01-0.04), Pb (0.01-0.02), Cr (0.02-0.05), Zn (0.40-0.70), Mn (0.02-0.05) and Ni (0.02-0.05), but Cadmium was not detected. The concentrations of Pb and Ni in ground water obtained from Arapaja, Aleshinloye and Alafara were higher than the World Health Organization (WHO) and Standard Organisation of Nigeria (SON) limits. The results obtained showed that the concentrations of Cd, Co, Pb, Ni and Cr in soil exceeded the WHO and SON permissible limits. However, Zn and Mn were below the limit. Keywords: Heavy metals, Dumpsite, Groundwater, Soil samples, Concentrations.

scholarly journals The Safety Assessment of Toxic Metals in Commonly Used Herbs, Spices, Tea, and Coffee in Poland

2021 ◽  
Vol 18 (11) ◽  
pp. 5779
Author(s):  
Grażyna Kowalska
Keyword(s):  
Heavy Metals ◽  
Environmental Protection Agency ◽  
Inductively Coupled Plasma ◽  
Raw Materials ◽  
Hazard Quotient ◽  
World Health Organisation ◽  
World Health ◽  
Target Hazard Quotient ◽  
Plant Materials

The presented study was aimed at the determination of the level of contamination with heavy metals (Cd, Pb, As, and Hg) in 240 samples of plant materials, i.e., herbal raw materials, spices, tea, and coffee. Moreover, a probabilistic risk assessment (noncarcinogenic and carcinogenic risks) was estimated by models including target hazard quotient (THQ) and cancer risk (CR). The samples were subjected to microwave mineralisation with the use of HNO3 (65%), while the determination of the content of the elements was performed with the use of inductively coupled plasma mass spectrometer (ICP–MS) and a mercury analyser. The element which was characterised by the highest level of accumulation in the analysed samples was lead (from 0.010 to 5.680 mg/kg). Among the heavy metals under analysis, the lowest concentration was noted in the case of mercury (from 0.005 to 0.030 mg/kg). A notably higher level of contamination with heavy metals was noted in the analysed samples of herbs and spices (0.005–5.680 mg/kg), compared to samples of tea and coffee (0.005–0.791 mg/kg). According to the guidelines of the World Health Organisation (WHO) concerning the limits of contamination of samples of herbal raw materials with heavy metals, lead levels exceeding the limits were only noted in 24 samples of herbs (18%). In all of the analysed samples of spices, tea, and coffee, no instances of exceeded limits were noted for any of the analysed heavy metals. The values of TTHQmax (in relation to the consumption of the analysed products) were as follows: up to 4.23 × 10−2 for spices, up to 2.51 × 10−1 for herbs, up to 4.03 × 10−2 for China tea, and up to 1.25 × 10−1 for roasted coffee beans. As the value of THQ ≤1, there is no probability of the appearance of undesirable effects related to the consumption of the analysed group of raw materials and products of plant origin. The CR value for As (max. value) was 1.29 × 10−5, which is lower than the maximum acceptable level of 1 × 10−4 suggested by United States Environmental Protection Agency (USEPA).

scholarly journals INVESTIGATION ON THE ENVIROMENTAL EFFECT OF LOCAL PRODUCTION METHOD OF ALUMINIUM UTENSIL IN KANO

2020 ◽  
Vol 4 (3) ◽  
pp. 256-262
Author(s):  
Y. I. Yakubu ◽  
I. A. Yola
Keyword(s):  
Heavy Metals ◽  
Water Samples ◽  
Production Method ◽  
Soil Samples ◽  
Permissible Limit ◽  
Limit Set ◽  
Local Production ◽  
Two Samples ◽  
S Model ◽  
Concentration Levels

This research investigated the environmental effect of local production methods of aluminium utensils in Bachirawa, Ungogo local government Kano. Three soil samples and two samples of water were collected from sites A, B,C, D and E. The samples were then taken to faculty of agriculture for analysis. Atomic absorption spectrophotometer (A A S model No 240 FSAA) was used to determine the concentration levels of heavy metals in the samples. The results show that, the concentration levels of  heavy metals in the soil samples A, B and C are:  Zn ranges between  (1158.13 - 11,117.80)  mg/kg; Mn  between  (285.719 – 1809.672) mg/kg; Cd between (0.026 – 0.540) mg/kg; Cr (0.498 – 0.832) mg/kg and Pb between (42.54 - 285.53) mg/kg. The observed concentration levels in water samples for Zn ranges between (0.2411 – 0.4435)mg/l; Cd between (0.091 – 0.123) mg/l; Cr between (0.015 – 0.022) mg/l; Mn between (0.284 – 0.728) mg/l and Pb between (0.00-0.08) mg/l. Zinc and Manganese have higher concentration levels than the recommended  permissible limit set by European Union (EU) and  United Kingdom(UK)  while Cd, Cr and  Pb have lower concentration levels than the recommended permissible limit set by EU and UK in soil samples  A, B and C. The concentration levels of Mn, Cd and Pb in water samples were higher than the permissible limit set by World Healh Organization (WHO) whereas Zn and Cr have concentrations lower than the recommended permissible limit set by 

scholarly journals Levels of heavy metals in soils and food crops cultivated within selected mining sites in Ebonyi State, Nigeria

2021 ◽  
Vol 2 (1) ◽  
pp. 84-95
Author(s):  
David Okechukwu Okeke ◽  
◽  
Jonathan Chinenye Ifemeje ◽  
Keyword(s):  
Heavy Metals ◽  
Control Site ◽  
Soil Samples ◽  
World Health ◽  
Food Crops ◽  
Food Crop ◽  
Mining Site ◽  
Mining Sites ◽  
Health Association ◽  
Health Organization

The level of heavy metals (Fe, Cu, As, Pb, Cd, Mg, Ca, Hg, Ni, Cr, Zn, Ag, Co, Mo, Se and Al) in soils and food crops (okra, cassava and rice) cultivated within selected mining sites in Ebonyi State, Nigeria were determined using FS240AA Atomic Absorption Spectrophotometer (AAS) according to the method of American Public Health Association (APHA). Soil samples were collected from Enyigba mining site, Ikwo mining site, AmeriAmekamining site, Izza mining site, MkpumeAkwatakwa mining site and MpumeAkwaokuku mining site while the food crop samples (okra, cassava and rice) were collected from the farmlands within the mining sites. Control samples were collected 500m away from the mining destinations were there was no evidence of mining activities on the soils. A total of sixty sub-samples and six control soil samples were collected for this study. Generally, the values of all the heavy metals analyzed for soil and food crop samples were higher than the values recommended by the World Health Organization (WHO), and those from the control site suggesting possible mobility of the metals from mining sites to farmlands through leaching and runoffs. The findings in this study also revealed that the food crops contain heavy metals exceeding the maximum permissible concentration, and could be detrimental to human health when they are consumed.

scholarly journals HEAVY METAL CONTENT IN SOME SEAFOODS COLLECTED FROM MUARA ANGKE FISH AUCTION PLACE, JAKARTA.

1987 ◽  
Vol 26 ◽  
pp. 51-58
Author(s):  
Horas Hutagalung ◽  
Suwirma Syamsu
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Content ◽  
Heavy Metal Content ◽  
World Health ◽  
Human Consumption ◽  
Zn Content ◽  
Standard Set ◽  
Health Organization

Determination of  heavy  metal  content  (Hg, Pb, Cd, Cu, Cr, Zn) in some seafoods collected from  Muara  Angke  Fish  Auction  Place  were carried out during February to July 1979. The results showed  that Zn  content  in seafoods a nalyzed  was always much higher than the other heavy metals. The concentration levels of  the  six  heavy  metals observed were low. It is almost of the same level as the metal concentration of  other  seafoods  observed  in various parts of the world oceans, but still lower  than the maximum standard set  for human  consumption  as  established  by   Tasmania, Australia and  World Health Organization. The  mean  per capita  consumption of  fish  in Jakarta is only  about 165 g  per week, while  the  Provisional Tolerated Weekly Intake for Hg, set by WHO/FAO at 300 ug level, would be attained by consuming 1500 g Rastrelliger sp., or 698 gPenaeus setiferus, or 545 g Sepia sp., and or 1250 g Pecten sp.  Therefore,  at   present the  level of metal content in fishes sold at TPI  Muara  Angke  can be  considered  as  not  dangerous  to human health as long as these quantities are not surpassed.

scholarly journals Determination of essential and non-essential elements in Xylanthemum macropodum of Balochistan, Pakistan

2021 ◽  
Vol 2 (02) ◽  
pp. 94-103
Author(s):  
Maria Bibi ◽  
Samiullah Khan ◽  
Attiq-Ur-Rehman Kakar ◽  
Naqeebullah Khan ◽  
Abdul Hakeem Tareen ◽  
...  
Keyword(s):  
Medicinal Plants ◽  
Medicinal Plant ◽  
Atomic Absorption ◽  
Essential Elements ◽  
Permissible Limit ◽  
World Health ◽  
Home Remedy ◽  
The World ◽  
Health Organization

Background: Medicinal plants have been used to treat various diseases for several years throughout the world. Xylanthemum macropodum is a medicinal plant with a vast application as a home remedy in Balochistan. Objective: The current study was conducted to determine the levels of essential and non-essential elements in Xylanthemum macropodum collected from Quetta (Balochistan, Pakistan). Methods: Analysis was conducted for eleven elements by using atomic absorption spectrophotometer and flame photometer. Results: The essential and non-essential elements that were detected in Xylanthemum macropodum are K, Na, Ca, Fe, Cu, Co, Ni, Mn, Cr, Cd and Pb, respectively. The result of the concentration of determined elements are in the order of K> Na> Ca> Fe> Cu> Co> Ni> Mn> Cd> Cr> Pb in Xylanthemum macropodum 3000> 1600> 790.25> 92.36> 85.31> 49.24> 40.94> 20.94> 6.655> 1.61> 1.18 µg/g respectively. Conclusions: Mn, Na and Pb were found within the permissible limit given by World Health Organization, while Ca, Cu, Fe, Ni, Cd and Cr were beyond the permissible limits. However, there is no permissible limit for K and Co.

scholarly journals Determination of Heavy Metals in Soil and Plants along Major Road in Hong Local Government Area, Adamawa State, Nigeria

2019 ◽  
pp. 1-10
Author(s):  
Nachana’a Timothy
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Concentration ◽  
Heavy Metal Concentration ◽  
Soil Samples ◽  
Health Concern ◽  
Major Road ◽  
Roadside Soils ◽  
The Road

Heavy metal concentration in roadside soil and plants are increasingly becoming of health concern. This work determined the concentration of selected heavy metals (Cd, Pb, Zn, Cr, Fe, Mg, Mn, Co, Ni and Cu) in roadside soils and plants samples from selected sites (Plaifu, Shiwa, Fadama-rake and Damdrai) along major road in Hong. Soil samples were taken 10 m, 20 m and 30 m away from the edge of the road at the  depth of 0-10 cm, 10-20 cm and 20-30 cm. Plant samples were randomly collected within the vicinity where the soil samples were taken and were analysed using Atomic Absorption Spectrophotometer. The result revealed the trend in soil heavy metal concentration was Fe > Mn > Mg > Pb > Zn > Ni > Co > Cu > Cr > Cd and for plant the trend was Fe > Mn > Mg > Zn > Pb > Ni > Cu > Cd > Co > Cr. The concentrations decreased with increasing distance away from the edge of the road as well as with depth at which the soil sample were taken. The transfer factor showed that the concentration of Zn, Mn, Cu and Mg were greater than 1, which shows that plant were enriched by Zn, Mn, Cu and Mg from the soil. Mg and Cd equal to 1 at Plaifu and Damdrai. Most of the values of TF at the study area super pass 0.5, which implies that generally, the ability of bioaccumulation of these heavy metals in examined plants were relatively high.

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