scholarly journals Preparation of High Specific Surface Area Micro/Meso-porous SiOC Ceramics by the Low Temperature Phase Separation Method

2018 ◽  
Vol 33 (12) ◽  
pp. 1360
Author(s):  
LI Jia-Ke ◽  
HAN Xiao-Qi ◽  
LIU Xin ◽  
WANG Yan-Xiang ◽  
GUO Ping-Chun ◽  
...  
Keyword(s):  
Phase Separation ◽  
Low Temperature ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
High Specific Surface Area ◽  
Separation Method ◽  
Temperature Phase ◽  
Low Temperature Phase

Spinel-structured Mn–Ni nanosheets for NH3-SCR of NO with good H2O and SO2 resistance at low temperature

2020 ◽  
Vol 10 (22) ◽  
pp. 7486-7501
Author(s):  
Fengyu Gao ◽  
Xiaolong Tang ◽  
Zaharaddeen Sani ◽  
Honghong Yi ◽  
Shunzheng Zhao ◽  
...  
Keyword(s):  
Low Temperature ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
High Specific Surface Area ◽  
Electronic Interaction ◽  
Adsorption Ability ◽  
Nh3 Scr ◽  
Scr Of No ◽  
So2 Resistance

High specific surface area, more NH3 adsorption ability and efficient electronic interaction over Mn–Ni spinel nanosheet leaded to good SCR activity, and Ni-outside with active Mn-inner spinel configuration and nanosheet morphology relieved SO2-poisoning.

scholarly journals LOW-TEMPERATURE SYNTHESIS OF BARIUM TITANITE IN AQUEOUS SOLUTION

2018 ◽  
Vol 61 (12) ◽  
pp. 56-62 ◽  
Author(s):  
Alexandr V. Agafonov ◽  
Konstantin V. Ivanov ◽  
Olga V. Alekseeva
Keyword(s):  
Heat Treatment ◽  
Barium Titanate ◽  
Thermal Treatment ◽  
Low Temperature ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Temperature Phase ◽  
Low Temperature Synthesis ◽  
Temperature Synthesis

Barium titanate powder with average particle size near 300 nm was produced using the low-temperature synthesis. It was established using scanning electron microscopy that at the thermal treatment, the particles gradually decrease with the formation of polydisperse aggregates. Based on the thermogravimetric analysis of the synthesized powder held in air for 4 months, it was shown that along with the low-temperature phase, the sample contains a high-temperature phase of carbonates, which removes at ~ 900 °C. Sorption characteristics of barium titanate thermally treated at various temperatures were obtained from the results of adsorption-desorption of nitrogen vapors. The specific surface area of the BaTiO3 powder was 76 m2/g. It was found that further heat treatment leads to a decrease in the specific surface area. The X-ray diffraction analysis of barium hydroxotitanil annealed at temperatures from 120 °C to 800 °C showed that the thermal treatment of the sample leads to the formation of a completely formed phase of barium titanate. The DSC temperature was used to determine the Curie temperatures for a HTB powder thermally treated in the temperature range from 120 to 800 °C. Dielectric spectra of suspensions of the synthesized powder were obtained during the heat treatment. <span style="opacity: 0;"> . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . </span>

scholarly journals Nanoporous Quasi-High-Entropy Alloy Microspheres

Metals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 345 ◽  
Author(s):  
Lianzan Yang ◽  
Yongyan Li ◽  
Zhifeng Wang ◽  
Weimin Zhao ◽  
Chunling Qin
Keyword(s):  
Mechanical Properties ◽  
Solid Solution ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
High Specific Surface Area ◽  
High Entropy Alloy ◽  
Face Centered Cubic ◽  
High Entropy ◽  
Hierarchical Porous

High-entropy alloys (HEAs) present excellent mechanical properties. However, the exploitation of chemical properties of HEAs is far less than that of mechanical properties, which is mainly limited by the low specific surface area of HEAs synthesized by traditional methods. Thus, it is vital to develop new routes to fabricate HEAs with novel three-dimensional structures and a high specific surface area. Herein, we develop a facile approach to fabricate nanoporous noble metal quasi-HEA microspheres by melt-spinning and dealloying. The as-obtained nanoporous Cu30Au23Pt22Pd25 quasi-HEA microspheres present a hierarchical porous structure with a high specific surface area of 69.5 m2/g and a multiphase approximatively componential solid solution characteristic with a broad single-group face-centered cubic XRD pattern, which is different from the traditional single-phase or two-phase solid solution HEAs. To differentiate, these are named quasi-HEAs. The synthetic strategy proposed in this paper opens the door for the synthesis of porous quasi-HEAs related materials, and is expected to promote further applications of quasi-HEAs in various chemical fields.

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