scholarly journals Chemical composition of different types of natural waters in Ukraine

2018 ◽  
Vol 27 (1) ◽  
pp. 68-80 ◽  
Author(s):  
V. K. Khilchevskyi ◽  
S. M. Kurylo ◽  
N. P. Sherstyuk
Keyword(s):  
Chemical Composition ◽  
Black Sea ◽  
Natural Waters ◽  
Water Exchange ◽  
Sea Water ◽  
Atmospheric Precipitation ◽  
The Black Sea ◽  
The South ◽  
Salinity Regime ◽  
Azov Sea

The results of studies of the chemical composition in various types of natural waters of the territory of Ukraine – atmospheric precipitation, surface (river and lake), groundwaters and sea waters are comprehensively summarized and presented for the territory of Ukraine in this paper. The chemical composition of Ukraine's natural waters (rivers, lakes, underground aquifers, seas) is the result of the interaction of a combination of natural factors, as well as their location, mainly in the temperate climatic zone. The average long–term mineralization of atmospheric precipitation is usually in the range of 20–40 mg/l, its chemical composition is predominantly sulfate magnesium–calcium. For the chemical composition of water in the small and medium rivers of Ukraine, hydrochemical zoning is observed in the direction from the northwest to the south-east of the country. Mineralization of river waters also increases in this direction (from 200–300 mg/l to 1,500–3,000 mg/l and more). The composition of the water varies from bicarbonate calcium in the north and west to sodium chloridein the south and southeast. The value of mineralization of lake water varies within very wide limits. There are lakes with very fresh water and low salinity (30 mg/l – small lakes of glacial origin in the Ukrainian Carpathians), and lakes whose water has a mineralization of more than 100 g/l (salt lakes of the Crimea). In the chemical composition of groundwater, the territory of Ukraine mainly exhibits vertical hydrochemical zoning, which manifests itself in the separation of zones of intensive or difficult water exchange. Hydrocarbonate or sulfate waters with a small mineralization (up to 1.0 g/l) are characteristic for the zone of active water exchange. Highly mineralized (50–300 g/l and more) chloride, sodium and chloride-sodiumcalcium waters are common in a zone of hindered water exchange. The ionic composition of the Black Sea water has all the characteristic features of ocean waters but differs from them in relative poverty with ions of chlorine and sodium, the average salinity of the Black Sea waters is 18–19 ‰. In the narrow coastal zone near the mouths of large rivers (the Danube, the Dniester, the Southern Bug, the Dnieper) a decrease in the salinity of the Black Sea waters (up to 5–10 ‰) is observed. The main factors that determine the salinity regime in the Azov Sea (10–13 ‰) are the inflow of saline Black Sea and fresh river (the Don and the Kuban rivers) waters that are mixed in the Azov Sea, as well as the arrival of atmospheric precipitation.

DISTRIBUTION OF DISSOLVED METHANE IN SURFACE COASTAL WATERS OF THE NORTHEASTERN PART OF THE BLACK SEA

2017 ◽  
Author(s):  
Elena Kovaleva ◽  
Elena Kovaleva ◽  
Alexander Izhitskiy ◽  
Alexander Izhitskiy ◽  
Alexander Egorov ◽  
...  
Keyword(s):  
Black Sea ◽  
Natural Waters ◽  
Sea Water ◽  
The Black Sea ◽  
Methane Formation ◽  
Anthropogenic Pressure ◽  
Russian Science ◽  
Southeastern Part ◽  
Dissolved Methane ◽  
Continental Runoff

Studying of methane formation and distribution in natural waters is important for understanding of biogeochemical processes of carbon cycle, searching for oil and gas sections and evaluation of CH4 emissions for investigations of greenhouse effect. The Black Sea is the largest methane water body on our planet. However, relatively low values of methane concentration (closed to equilibrium with the atmospheric air) are typical of the upper aerobic layer. At the same time, the distribution pattern of CH4 in surface waters of coastal areas is complicated by the influence of coastal biological productivity, continental runoff, bottom sources, hydrodynamic processes and anthropogenic effect. The investigation is focused on the spatial variability of dissolved methane in the surface layer of the sea in coastal regions affected by the continental runoff and anthropogenic pressure. Unique in situ data on methane concentrations were collected along the ship track on 2 sections between Sochi and Gelendzhik (2013, 2014) and 2 sections between Gelendzhik and Feodosia (2015). Overall 170 samples were obtained. Gas-chromatographic analysis of the samples revealed increase of CH4 saturation in the southeastern part of the Crimean shelf and the Kerch Strait area. Such a pattern was apparently caused by the influence of the Azov Sea water spread westward along the Crimean shore from the strait. This work was supported by the Russian Science Foundation, Project 14-50-00095 and the Russian Foundation for Basic Research, Project 16-35-00156 mol_a.

DISTRIBUTION OF DISSOLVED METHANE IN SURFACE COASTAL WATERS OF THE NORTHEASTERN PART OF THE BLACK SEA

2017 ◽  
Author(s):  
Elena Kovaleva ◽  
Elena Kovaleva ◽  
Alexander Izhitskiy ◽  
Alexander Izhitskiy ◽  
Alexander Egorov ◽  
...  
Keyword(s):  
Black Sea ◽  
Natural Waters ◽  
Sea Water ◽  
The Black Sea ◽  
Methane Formation ◽  
Anthropogenic Pressure ◽  
Russian Science ◽  
Southeastern Part ◽  
Dissolved Methane ◽  
Continental Runoff

Studying of methane formation and distribution in natural waters is important for understanding of biogeochemical processes of carbon cycle, searching for oil and gas sections and evaluation of CH4 emissions for investigations of greenhouse effect. The Black Sea is the largest methane water body on our planet. However, relatively low values of methane concentration (closed to equilibrium with the atmospheric air) are typical of the upper aerobic layer. At the same time, the distribution pattern of CH4 in surface waters of coastal areas is complicated by the influence of coastal biological productivity, continental runoff, bottom sources, hydrodynamic processes and anthropogenic effect. The investigation is focused on the spatial variability of dissolved methane in the surface layer of the sea in coastal regions affected by the continental runoff and anthropogenic pressure. Unique in situ data on methane concentrations were collected along the ship track on 2 sections between Sochi and Gelendzhik (2013, 2014) and 2 sections between Gelendzhik and Feodosia (2015). Overall 170 samples were obtained. Gas-chromatographic analysis of the samples revealed increase of CH4 saturation in the southeastern part of the Crimean shelf and the Kerch Strait area. Such a pattern was apparently caused by the influence of the Azov Sea water spread westward along the Crimean shore from the strait. This work was supported by the Russian Science Foundation, Project 14-50-00095 and the Russian Foundation for Basic Research, Project 16-35-00156 mol_a.

The influence and importance of daily weather conditions in the supply of chloride, sulphate and other ions to fresh waters from atmospheric precipitation

1958 ◽  
Vol 244 (1236) ◽  
pp. 140-140
Keyword(s):  
Sulphuric Acid ◽  
Atmospheric Pollution ◽  
Natural Waters ◽  
Sea Water ◽  
Atmospheric Precipitation ◽  
Weather Conditions ◽  
Sea Spray ◽  
Lake District ◽  
The South ◽  
Soil Weathering

This paper deals with chemical analyses for hydrogen, sodium, potassium, calcium, chloride, sulphate and nitrate ions in daily precipitation samples collected in the English Lake District, and examines the correlations of these analyses with ( a ) one another, ( b ) the amount of precipitation, ( c ) wind direction, ( d ) wind velocity, and ( e ) temperature. Highly significant correlations are found between estimates for H, K, Ca, NO 3 and SO 4 ions, and atmospheric pollution appears to supply much of the sulphate in Lake District rain, since it comes largely as sulphuric acid from the south-east. The correlation between Na and Cl is also extremely close, with the proportion between the two ions very similar to that in sea water. Since these two ions are supplied mainly from the south-west, in amounts which are greatly increased by high winds, sea spray may be inferred as the principal source. Nevertheless, evidence is presented for some small supply from atmospheric pollution, and it is furthermore suggested that mixed droplets of sea salt and sulphuric acid may, upon abstraction of moisture by freezing or evaporation, release gaseous hydrogen chloride to the air and so alter the balance of Na and Cl in precipitation. The supply of Na and Cl is also considerably higher in cold than in warm weather, a phenomenon possibly connected with stormier conditions and greater evaporation over the Atlantic Ocean. The atmospheric contribution of ions to natural waters via precipitation is shown to be of great importance, in particular to bog pools, to upland tarns on hard rocks, and to the soil solution in highly organic mor humus layers overlying heavily leached hillside soils. Sodium and chloride in most surface waters appears to be almost wholly supplied by sea spray, while calcium and magnesium bicarbonates are the main products of soil weathering. A net loss of rain acids is evident in all soil waters, although some may be more acid than normal rain water owing to considerable concentration by evaporation. The soil waters are relatively rich in potassium, presumably supplied from decaying vegetation.

scholarly journals Current level of oil hydrocarbons in Russian coastal waters of the Black Sea and and Azov Sea

2020 ◽  
Vol 15 (3) ◽  
pp. 77-85
Author(s):  
O. A. Mironov ◽  
O. G. Mironov
Keyword(s):  
Black Sea ◽  
Coastal Waters ◽  
Sea Water ◽  
Oil Pollution ◽  
Hydrological Regime ◽  
The Black Sea ◽  
Infrared Spectrometry ◽  
Anthropogenic Pressure ◽  
Azov Sea ◽  
Oil Hydrocarbons

Aim. Currently, oil pollution remains one of the primary pollutants of the marine environment. This is especially true for the Black Sea and Azov Sea which experience significant anthropogenic pressure. The study presents the results of two-year monitoring studies of the content of oil hydrocarbons in the surface and bottom horizons of the coastal waters of the Azov-Black Sea regions of Russia.Materials and Methods. The determination of oil hydrocarbons was conducted by infrared spectrometry using a FSM-1201 Fourier spectrophotometer with preliminary transmission of the extracts through a chromatographic column with aluminum oxide. The work was carried out as part of five scientific expeditions (93th, 96th, 100th, 102nd and 105th) of the research vessel, Professor Vodyanitsky, in 2017 and 2018.Results. The general environmental status for this pollutant is characterized as stable, despite in some cases being 3 to 4 times in excess of established standards (MPC). Separate foci of localized oil pollution have been identified and vulnerable areas of the sea coast of southern Russia have been identified. An excess content of petroleum hydrocarbons in the surface layer compared to the bottom layer was noted, which indicates a surface path of entry of petroleum products into sea water.Conclusion. Currently, the coastal waters of the western part of Crimea are most affected by oil, primarily associated with the runoff of European rivers and the peculiarities of the marine hydrological regime, including the Kerch Strait, an area of heavy shipping traffic. The Caucasian coast is less affected by oil pollution than the Crimean. Despite the fact that currently the content of oil hydrocarbons in sea water is far from the quantities dangerous to humans and aquatic organisms, monitoring of this indicator is vital due to the increasing anthropogenic pressure on the recreational zones of the Crimean and Caucasian coasts of the Russian Federation.

scholarly journals MODELLING WATER EXCHANGE BETWEEN COASTAL ELONGATED LAGOON AND SEA: INFLUENCE OF THE MORPHOMETRIC CHARACTERISTICS OF CONNECTING CHANNEL ON WATER RENEWAL IN LAGOON

2019 ◽  
Vol 5 ◽  
pp. 37-46
Author(s):  
Yurii Tuchkovenko ◽  
Oksana Tuchkovenko ◽  
Valeriy Khokhlov
Keyword(s):  
Black Sea ◽  
Water Exchange ◽  
Sea Water ◽  
Reference Points ◽  
Water Volume ◽  
The Black Sea ◽  
Morphometric Characteristics ◽  
Water Renewal ◽  
The North ◽  
North Western

The north-western part of the Black Sea Ukrainian coast is characterized by the presence of 12 marine lagoons which do not presently have permanent natural connections with the sea. Because of regional climate change, these lagoons have experienced a significant deficit of annual freshwater balance during the last decades and, consequently, an increase in salinity and eutrophication of their waters. One way to stabilize the hydroecological regime of lagoons is to maintain their regular connection with the sea via artificial connecting channels. The deepest and most prolonged Tyligulskyi Liman lagoon is used as an example to determine the morphometric characteristics (width, depth) of the artificial connecting channel which ensures bidirectional water exchange of the lagoon with the sea, i. e. its partial flushing. A numerical hydrodynamic model is used to estimate how the morphometric characteristics of the connecting channel influence the intensity of water exchange between the lagoon and the sea and of water renewal by seawater for the various parts of the lagoon. The dynamics of sea water volume concentration in reference points in the lagoon is used as an indicator of seawater intrusion into the lagoon and their degree of water renewal in its various zones. The proposed methodology could be used for other lagoons of the same type in the north-western part of the Black Sea.

The influence and importance of daily weather conditions in the supply of chloride, sulphate and other ions to fresh waters from atmospheric precipitation

1958 ◽  
Vol 241 (679) ◽  
pp. 147-178 ◽  
Keyword(s):  
Sulphuric Acid ◽  
Atmospheric Pollution ◽  
Natural Waters ◽  
Sea Water ◽  
Atmospheric Precipitation ◽  
Weather Conditions ◽  
Sea Spray ◽  
Lake District ◽  
The South ◽  
Soil Weathering

This paper deals with chemical analyses for hydrogen, sodium, potassium, calcium, chloride, sulphate and nitrate ions in daily precipitation samples collected in the English Lake District, and examines the correlations of these analyses with ( a ) one another, ( b ) the amount of precipitation, ( c ) wind direction, ( d ) wind velocity, and ( e ) temperature. Highly significant correlations are found between estimates for H, K, Ca, NO 3 and SO 4 ions, and atmospheric pollution appears to supply much of the sulphate in Lake District rain, since it comes largely as sulphuric acid from the south-east. The correlation between Na and Cl is also extremely close, with the proportion between the two ions very similar to that in sea water. Since these two ions are supplied mainly from the south-west, in amounts which are greatly increased by high winds, sea spray may be inferred as the principal source. Nevertheless, evidence is presented for some small supply from atmospheric pollution, and it is furthermore suggested that mixed droplets of sea salt and sulphuric acid may, upon abstraction of moisture by freezing or evaporation, release gaseous hydrogen chloride to the air and so alter the balance of Na and Cl in precipitation. The supply of Na and Cl is also considerably higher in cold than in warm weather, a phenomenon possibly connected with stormier conditions and greater evaporation over the Atlantic Ocean. The atmospheric contribution of ions to natural waters via precipitation is shown to be of great importance, in particular to bog pools, to upland tarns on hard rocks, and to the soil solution in highly organic mor humus layers overlying heavily leached hillside soils. Sodium and chloride in most surface waters appear to be almost wholly supplied by sea spray, while calcium and magnesium bicarbonates are the main products of soil weathering. A net loss of rain acids is evident in all soil waters, although some may be more acid than normal rain water owing to considerable concentration by evaporation. The soil waters are relatively rich in potassium, presumably supplied from decaying vegetation.

scholarly journals The chemical-microbiological characteristics of sea water and bottom sediments of the Kerch Strait and adjacent water areas

2017 ◽  
Vol 2 (3) ◽  
pp. 75-85
Author(s):  
E. A. Tikhonova ◽  
N. V. Burdiyan ◽  
O. V. Soloveva
Keyword(s):  
Surface Layer ◽  
Black Sea ◽  
Bottom Sediments ◽  
Heterotrophic Bacteria ◽  
Sea Water ◽  
Water Area ◽  
The Black Sea ◽  
Azov Sea ◽  
Sea Bottom ◽  
Oil Hydrocarbons

This paper presents the results of contamination level of sea bottom sediments and seawater in the water areas by the strait of the Black Sea and the Azov Sea by oil hydrocarbons and chloroform-extractable substances studies (spring, autumn 2016). Comparison of marine environment pollution levels with the results of previous studies (2007–2010) and sanitary norms is given. The quantitative characteristics of  heterotrophic and oil-oxidizing microbiota in the designated areas are presented. It was determined that the concentration of oil hydrocarbons in the water surface layer in the water area by the strait of the Azov Sea did not exceed the current norm (0.05 mg·l-1). The single cases of the maximum permissible concentration exceeding were registered in the water area by the strait of the Black Sea (autumn 2016). In the surface layer of Azov Sea water, the number of heterotrophic bacteria ranged from 104 to 105 cells·ml-1, and the oil-oxidizing bacteria were isolated in single quantities. In the water area of the Black Sea region of the strait the number of heterotrophic bacteria was 106, the number of oil-oxidizing bacteria did not exceed 10 cells·ml-1. In comparison with the previous years’ data, there was an increase in quantitative indicators of chloroform-extractable substances and oil hydrocarbons in the sea bottom sediments. The overall level of pollution did not exceed the average values determined for the region. The number of heterotrophic bacteria in the sea bottom sediments varied in the Strait of Azov water area from 2,5·104 to 4,5·104 cells·g-1, while that of oil-oxidizing bacteria varied from 2,5·10 to 4,5·102 cells·g-1. In the sea bottom sediments of the Black Sea, the number of heterotrophic bacteria was 4,5·103 cells·g-1, the number of oil oxidizing bacteria was 10 cells·g-1.

scholarly journals Spatial analysis of seasonal patterns in sea surface temperature and salinity distribution in the Black Sea (1992-2017)

2021 ◽  
Vol 937 (3) ◽  
pp. 032013
Author(s):  
D Krivoguz ◽  
A Semenova ◽  
S Mal’ko
Keyword(s):  
Black Sea ◽  
Water Exchange ◽  
Sea Water ◽  
Shelf Zone ◽  
The Black Sea ◽  
Sea Of Marmara ◽  
Time Period ◽  
Salinity Data ◽  
Living Organisms ◽  
Suitable Environment

Abstract Sea water temperature and water salinity one of the most important environmental factors of the marine ecosystems. Both of them plays an important role in forming suitable environment for marine living organisms and have a great impact on species biodiversity. Our goal for this paper was to identify spatial patterns of interannual variations in the salinity and temperature fluctuations to understand possibilities of future change of the Black Sea ecosystem and its impact on fisheries. We used temperature and salinity data from CMEMS for the 1992-2017 time period. All downloaded data was processed by QGIS 3.14 and R 4.0.3. We found that the temperature regime of the Black Sea in different periods of the year is determined by three main factors - the depth of the shelf zone, the influence of river runoff, and water circulation due to currents. The average salinity of the Black Sea waters is 19 ‰, areas with lower salinity are located near the west shore, due to the flows from the largest rivers (Dnieper, Dniester, Danube) bringing a large amount of fresh water to the Black Sea. The area with higher salinity is located in the south- west due to the water exchange of the Black Sea with the saltier Sea of Marmara (∼ 26 ‰) through the Bosphorus. The currents of the Black Sea pick up the salty water of the Sea of Marmara and slowly moving the water column against the clockwise, carry it across the entire Black Sea, thereby increasing its average salinity.

HYDROGEN FROM HYDROGEN SULPHIDE IN BLACK SEA

2019 ◽  
pp. 49-55
Author(s):  
S. Z. Baykara ◽  
E. H. Figen ◽  
A. Kale ◽  
T. N. Veziroglu
Keyword(s):  
Hydrogen Production ◽  
Black Sea ◽  
Hydrogen Sulphide ◽  
Sea Water ◽  
Economic Value ◽  
Environmental Pollutant ◽  
The Black Sea ◽  
Fuel Processing ◽  
Acid Gas ◽  
Reducing Bacteria

Hydrogen sulphide, an acid gas, is generally considered an environmental pollutant. As an industrial byproduct, it is produced mostly during fuel processing. Hydrogen sulphide occurs naturally in many gas wells and also in gas hydrates and gas-saturated sediments especially at the bottom of the Black Sea where 90% of the sea water is anaerobic.The anoxic conditions exist in the deepest parts of the basin since nearly 7300 years, caused by the density stratification following the significant influx of the Mediterranean water through the Bosphorous nearly 9000 years ago. Here, H2S is believed to be produced by sulphur reducing bacteria at an approximate rate of 10 000 tons per day, and it poses a serious threat since it keeps reducing the life in the Black Sea. An oxygen–hydrogen sulphide interface is established at 150–200 m below the surface after which H2S concentration starts increasing regularly until 1000 m, and finally reaches a nearly constant value of 9.5 mg/l around 1500 m depth.Hydrogen sulphide potentially has economic value if both sulphur and hydrogen can be recovered. Several methods are studied for H2S decomposition, including thermal, thermochemical, electrochemical, photochemical and plasmochemical methods.In the present work, H2S potential in the Black Sea is investigated as a source of hydrogen, an evaluation of the developing prominent techniques for hydrogen production from H2S is made, and an engineering assessment is carried out regarding hydrogen production from H2S in the Black Sea using a process design based on the catalytic solar thermolysis approach. Possibility of a modular plant is considered for production at larger scale.

LUMINESCENCE OF THE BLACK SEA MICROSCOPIC FUNGI CULTURES

2017 ◽  
Author(s):  
Olga Mashukova ◽  
Olga Mashukova ◽  
Yuriy Tokarev ◽  
Yuriy Tokarev ◽  
Nadejda Kopytina ◽  
...  
Keyword(s):  
Fresh Water ◽  
Black Sea ◽  
Ethyl Alcohol ◽  
Light Emission ◽  
Sea Water ◽  
Control Culture ◽  
Chemical Stimulation ◽  
The Black Sea ◽  
The Given ◽  
First Time

We studied for the first time luminescence characteristics of the some micromycetes, isolated from the bottom sediments of the Black sea from the 27 m depth. Luminescence parameters were registered at laboratory complex “Svet” using mechanical and chemical stimulations. Fungi cultures of genera Acremonium, Aspergillus, Penicillium were isolated on ChDA medium which served as control. Culture of Penicillium commune gave no light emission with any kind of stimulation. Culture of Acremonium sp. has shown luminescence in the blue – green field of spectrum. Using chemical stimulation by fresh water we registered signals with luminescence energy (to 3.24 ± 0.11)•108 quantum•cm2 and duration up to 4.42 s, which 3 times exceeded analogous magnitudes in a group, stimulated by sea water (p < 0.05). Under chemical stimulation by ethyl alcohol fungi culture luminescence was not observed. Culture of Aspergillus fumigatus possessed the most expressed properties of luminescence. Stimulation by fresh water culture emission with energy of (3.35 ± 0.11)•108 quantum•cm2 and duration up to 4.96 s. Action of ethyl alcohol to culture also stimulated signals, but intensity of light emission was 3–4 times lower than under mechanical stimulation. For sure the given studies will permit not only to evaluate contribution of marine fungi into general bioluminescence of the sea, but as well to determine places of accumulation of opportunistic species in the sea.

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