scholarly journals MODIFICATION TECHNOLOGY OF MONTMORILLONITE BY POLYIONENES

2018 ◽  
Vol 26 (1) ◽  
pp. 1-8
Author(s):  
Kostyantyn M Sukhyy ◽  
Elena Belyanovskaya ◽  
Mikhaylo P Sukhyy
Keyword(s):  
Ion Exchange ◽  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Processing Time ◽  
Reaction Medium ◽  
Aqueous Dispersion ◽  
Organic Cations ◽  
Optimal Conditions ◽  
Exchange Adsorption

Technology of obtaining montmorillonite modified by polyionenes is developed. Macromolecular polymer intercalation of a quaternary ammonium salt of montmorillonite intercrystalline space is shown to be accompanied with increased interlayer distances from 1.08 nm to 1.67 nm. The technique of synthesis of montmorillonite modified by polyionenes is suggested. Optimal conditions for sorption of polyionenes molecules with montmorillonite are found to be: the concentration of aqueous dispersion of montmorillonite is 1 %, the temperature of the reaction medium is 40 °C, the montmorillonite-polyionene ratio is 3 : 1, the processing time is 24 hours. The mechanism of montmorillonite modification is suggested to involve the next steps: connection of organic cations to montmorillonite surface determined by attachment of organic cations to exchange position during ion-exchange adsorption and adsorption of organic cations with acid sylanol groups, i.e. torn bonds on crystal faces. These processes are shown to result in more perfect structure by organic cations adsorption with acid sylanol groups (torn bonds on crystal faces).

scholarly journals Organo-montmorillonite modified by polyionenes for polymer composites

2020 ◽  
Vol 3 (2) ◽  
pp. 187-190
Author(s):  
M. P. Sukhyi ◽  
◽  
V. I. Tomilo ◽  
K. M. Sukhyi ◽  
E. A. Belyanovskaya ◽  
...  
Keyword(s):  
Polymer Composites ◽  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Processing Time ◽  
Reaction Medium ◽  
Aqueous Dispersion ◽  
Optimal Conditions

The technology for producing montmorillonite modified with polyionenes has been developed. It was shown that macromolecular polymer intercalation of the quaternary ammonium salt of montmorillonite intercrystalline space is accompanied by an increase in interlayer distances from 1.08 to 1.67 nm. A method for the synthesis of montmorillonite modified with polyionenes is proposed. The optimal conditions for the sorption of polymeonene molecules by montmorillonite were found: the concentration of the aqueous dispersion of montmorillonite is 1%, the temperature of the reaction medium is 40 ° C, the ratio of montmorillonite-polyionene is 3: 1, the processing time is 24 hours.

Catalyst- and oxidant-free electrochemical para-selective hydroxylation of N-arylamides in batch and continuous-flow

2020 ◽  
Vol 22 (19) ◽  
pp. 6437-6443
Author(s):  
Cheng-Kou Liu ◽  
Meng-Yi Chen ◽  
Xin-Xin Lin ◽  
Zheng Fang ◽  
Kai Guo
Keyword(s):  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Continuous Flow ◽  
Quaternary Ammonium Salt ◽  
Selective Hydroxylation

A catalyst-, oxidant-, acidic solvent- and quaternary ammonium salt-free electrochemical para-selective hydroxylation of N-arylamides at rt in batch and continuous-flow was developed.

Synthesis and Performance of Polyoxy-ethylene Ester Quaternary Ammonium Salt

2013 ◽  
Vol 50 (1) ◽  
pp. 9-13 ◽  
Author(s):  
Yong-Qiang Sun ◽  
Wen-Jing Li ◽  
Wan-Xu Wang ◽  
Qiu-Xiao Li ◽  
Wieslaw Hreczuch ◽  
...  
Keyword(s):  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
And Performance

Instability of Solutions of Quaternary Ammonium Permanganates in Dichloromethane

1997 ◽  
Vol 62 (6) ◽  
pp. 849-854 ◽  
Author(s):  
Vladislav Holba ◽  
Renata Košická
Keyword(s):  
Ammonium Salt ◽  
Rate Constants ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Activation Parameters ◽  
The Stability

The paper deals with instability of solutions of quaternary ammonium permanganates, QMnO4 (Q = tetraethyl-, tetra-1-propyl-, tetra-1-butyl-, tetra-1-pentyl-, tetra-1-octyl-, and cetyltrimethylammonium), in dichloromethane and presents the rate constants and activation parameters of the reduction of permanganate. Attention was paid to the properties of colloidal Mn(IV) intermediate. The stability of the solutions depends markedly on the quaternary ammonium salt used.

Systematic exploration of quaternary ammonium salt adsorption on oxidized coal based on experiments and MD simulations

Fuel ◽  
2021 ◽  
Vol 287 ◽  
pp. 119434
Author(s):  
Jun Chen ◽  
Hongliang Li ◽  
Chunfu Liu ◽  
Lingyun Liu ◽  
Yu Sun ◽  
...  
Keyword(s):  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Md Simulations ◽  
Oxidized Coal ◽  
Systematic Exploration

scholarly journals Antibacterial performance of polymer quaternary ammonium salt–capped silver nanoparticles on Bacillus subtilis in water

RSC Advances ◽  
2019 ◽  
Vol 9 (44) ◽  
pp. 25667-25676 ◽  
Author(s):  
Jingyu Wang ◽  
Minghao Sui ◽  
Zhanfang Ma ◽  
Hongwei Li ◽  
Bojie Yuan
Keyword(s):  
Silver Nanoparticles ◽  
Bacillus Subtilis ◽  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Antibacterial Performance ◽  
Antibacterial Capacity

Polymer quaternary ammonium salt–capped silver nanoparticles (PQAS–AgNPs) were synthesized, and they exhibited significant antibacterial capacity against Bacillus subtilis.

Synthesis and Applications of Tri-Quaternary Ammonium Salt Gemini Surfactant

2013 ◽  
Vol 34 (1) ◽  
pp. 106-110 ◽  
Author(s):  
Xiongjun Wu ◽  
Lin Zhao ◽  
Xiaojun Wang ◽  
Jinjie Wang ◽  
Yuli Zhang
Keyword(s):  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Gemini Surfactant

Antibacterial activity of quaternary ammonium salt grafted cotton

2007 ◽  
Vol 98 (3) ◽  
pp. 209-218 ◽  
Author(s):  
N. Ladhari ◽  
M. H. V. Baouab ◽  
Abdelbasset Ben Dekhil ◽  
Amina Bakhrouf ◽  
P. Niquette
Keyword(s):  
Antibacterial Activity ◽  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt
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