scholarly journals Acute Arsine Poisoning Confirmed by Speciation Analysis of Arsenic Compounds in the Plasma and Urine by HPLC‐ICP‐MS

2011 ◽  
Vol 53 (1) ◽  
pp. 45-49 ◽  
Author(s):  
Yukihiro Yoshimura ◽  
Yoko Endo ◽  
Yasuyo Shimoda ◽  
Kenzo Yamanaka ◽  
Ginji Endo
Keyword(s):  
Speciation Analysis ◽  
Arsenic Compounds ◽  
Icp Ms

Speciation Analysis of Arsenic Compounds in Healthy Human Urine by HPLC-ICP-MS for the Evaluation of the Occupational Inorganic Arsenic Exposure

Epidemiology ◽  
2009 ◽  
Vol 20 ◽  
pp. S154-S155 ◽  
Author(s):  
Yoshihiro Suzuki ◽  
Yasuyo Shimoda ◽  
Yoko Endo ◽  
Akihisa Hata ◽  
Kenzo Yamanaka ◽  
...  
Keyword(s):  
Human Urine ◽  
Arsenic Exposure ◽  
Inorganic Arsenic ◽  
Speciation Analysis ◽  
Arsenic Compounds ◽  
Healthy Human ◽  
Icp Ms

scholarly journals Rapid and Effective Speciation Analysis of Arsenic Compounds in Human Urine using Anion‐Exchange Columns in HPLC‐ICP‐MS

2009 ◽  
Vol 51 (4) ◽  
pp. 380-385 ◽  
Author(s):  
Yoshihiro Suzuki ◽  
Yasuyo Shimoda ◽  
Yoko Endo ◽  
Akihisa Hata ◽  
Kenzo Yamanaka ◽  
...  
Keyword(s):  
Anion Exchange ◽  
Human Urine ◽  
Speciation Analysis ◽  
Arsenic Compounds ◽  
Icp Ms

scholarly journals Speciation Analysis of Arsenic Compounds by HPLC-ICP-MS: Application for Human Serum and Urine

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Manh Ha Nguyen ◽  
Tien Duc Pham ◽  
Thi Lien Nguyen ◽  
Hai Anh Vu ◽  
Thi Thao Ta ◽  
...  
Keyword(s):  
Human Serum ◽  
Ethylenediaminetetraacetic Acid ◽  
Limit Of Detection ◽  
Speciation Analysis ◽  
Arsenic Species ◽  
Dimethylarsinic Acid ◽  
Arsenic Compounds ◽  
Serum Samples ◽  
Icp Ms ◽  
Urine And Serum

A high-performance liquid chromatography (HPLC) in combination with inductively coupled plasma mass spectrometry (ICP-MS) as an elemental specific detector was used for the speciation analysis of arsenic compounds in urine and serum samples from Vietnam. Five arsenic species including arsenite (AsIII), arsenate (AsV), monomethylarsonic acid (MMA), dimethylarsinic acid (DMA), and arsenobetaine (AsB) were studied. A gradient elution of ammonium carbonate ((NH4)2CO3), ethylenediaminetetraacetic acid disodium salt (Na2EDTA), and methanol at pH 9.0 utilizing Hamilton PRP-X100 strong anion-exchange column allowed the chromatographic separation of five arsenic species. In this study, urine and serum samples were prepared by dilution in solvent and protein precipitation by trichloroacetic acid, respectively. The extraction efficiency was greater than 91% for urine matrix, and recoveries from spiked samples were in the range of 94–139% for the arsenic species in human serum. The method limit of detection (MDL) and limit of quantification (MQL), which were calculated by signal to noise ratio, were found to be 0.3–1.5 and 1.0–5.0 ng·mL−1, respectively. The concentration of arsenic species in 17 pairs of urine and serum samples from Vietnam was also quantified and evaluated. The major species of arsenic in the urine and serum samples were AsB and DMA.

scholarly journals Mercury determination and speciation analysis in surface waters

2012 ◽  
Vol 10 (4) ◽  
pp. 1175-1182 ◽  
Author(s):  
Elisaveta Mladenova ◽  
Ivanka Dakova ◽  
Dimiter Tsalev ◽  
Irina Karadjova
Keyword(s):  
Surface Waters ◽  
Inductively Coupled Plasma ◽  
Mechanical Stability ◽  
Solid Phase ◽  
Chemical Vapor ◽  
Speciation Analysis ◽  
Regeneration Ability ◽  
Mercury Species ◽  
Icp Ms ◽  
Relative Standard

AbstractA sorbent L-cysteine grafted silica gel has been evaluated for separation and enrichment of dissolved inorganic i-Hg(II) and methylmercury CH3Hg(I) from surface waters at sub-µg L−1 concentrations. Chemical parameters for mercury species enrichment and separation have been optimized. Analytical schemes for the determination of Hg species, using selective column solid phase extraction (SPE) with continuous flow chemical vapor generation atomic absorption spectrometry (CF-CVG-AAS) or inductively coupled plasma-mass spectrometry (ICP-MS) were developed. Possibilities for on-site SPE enrichment were demonstrated as well. The limits of quantification were 1.5 and 5 ng L−1 for dissolved i-Hg(II) and CH3Hg(I) by CF-CVG-AAS and 1 and 2.5 ng L−1 by ICP-MS with relative standard deviations between 7–12% and 7–14%, respectively. The chemically modified SPE sorbent has demonstrated high regeneration ability, chemical and mechanical stability, acceptable capacity and good enrichment factors. Results for total dissolved mercury were in reasonable agreement with those from independent analyses by direct ICP-MS determinations for river waters and for estuarine water certified reference material.

Siloxane compounds in biogas from manure and mixed organic waste: Method development and speciation analysis with GC-ICP-MS

Talanta ◽  
2020 ◽  
Vol 208 ◽  
pp. 120398 ◽  
Author(s):  
Debora Foppiano ◽  
Mohamed Tarik ◽  
Jörg Schneebeli ◽  
Adelaide Calbry-Muzyka ◽  
Serge Biollaz ◽  
...  
Keyword(s):  
Organic Waste ◽  
Method Development ◽  
Speciation Analysis ◽  
Icp Ms

scholarly journals HPLC–ICP-MS speciation analysis and risk assessment of arsenic in Cordyceps sinensis

2018 ◽  
Vol 13 (1) ◽  
Author(s):  
Tian-Tian Zuo ◽  
Yao-Lei Li ◽  
Hong-Yu Jin ◽  
Fei Gao ◽  
Qi Wang ◽  
...  
Keyword(s):  
Risk Assessment ◽  
Speciation Analysis ◽  
Cordyceps Sinensis ◽  
Icp Ms
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