Modification of the Structure and Magnetic Properties of Al2O3/Co(P) Composite Particles during Mechanical Activation

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Xiaopeng Xiong ◽  
Yong Wang ◽  
Weiwei Zou ◽  
Jiangjiang Duan ◽  
Yun Chen

By dispersing aqueous precipitant in liquid paraffin to prepare a W/O emulsion then adding chitosan (CS) solution, CS microcapsules have been successfully prepared. It is a facile way to prepare polymer microcapsules by using aqueous precipitant or nonsolvent as template, which avoids the removal of template and would free from the necessity to cross-link the microcapsule as usual methods to directly form dense shell. The hollow feature of the obtained materials is revealed. The diameter of the microcapsules ranges from severalμm to over 100 μm. Magnetic CS microcapsules have been prepared in this way when Fe3+and Fe2+were mixed with CS to prepare a mixture starting solution. The appearance and microstructure of the composite microcapsules were studied. The results indicate that the formed Fe3O4nanoparticles are embedded in the CS matrix evenly due to strong interaction between the Fe3O4nanoparticles and the CS molecules. The Fe3O4content and the magnetic properties of the composite microcapsule were measured. The composite microcapsules were calcined in air at 700°C to prepare pure inorganic hollow microspheres. It is general to prepare hollow polymeric or composite particles by using this method.


2019 ◽  
Vol 55 (1) ◽  
pp. 85-93 ◽  
Author(s):  
M.M. Vasic ◽  
A.S. Kalezic-Glisovic ◽  
R. Milincic ◽  
Lj. Radovic ◽  
D.M. Minic ◽  
...  

The mechanical activation of the Ni85.8Fe10.6Cu2.2W1.4 powder mixture in the time intervals of 30-210 min in combination with thermal treatment at 393-873 K resulted in microstructural changes, forming the nanostructured mixture of the same composition but improved magnetic properties. The best result were achieved for mechanical activation during 120 min and thermal treatment at temperatures close to the Curie temperature (693K), enhancing the mass magnetization of the starting powder mixture by about 57%. The microstructural changes, which include the structural relaxation, decrease in free volume, density of dislocation and microstrain, improve structural characteristics of material, enabling better mobility of walls of magnetic domains and their better orientation in applied magnetic field and consequently enabling better mass magnetization of the material. With longer time of milling, the growing stress introduced in the sample undergoes easier relief, relocating stress-relieving processes toward lower temperatures.


Author(s):  
S. P. Kubrin ◽  
I. P. Raevski ◽  
V. V. Stashenko ◽  
A. A. Gusev ◽  
V. P. Isupov ◽  
...  

2017 ◽  
Vol 43 (5) ◽  
pp. 4139-4150 ◽  
Author(s):  
H. Fki ◽  
M. Koubaa ◽  
L. Sicard ◽  
W. Cheikhrouhou-Koubaa ◽  
A. Cheikhrouhou ◽  
...  

2015 ◽  
Vol 2 (1) ◽  
pp. 015018 ◽  
Author(s):  
Suiyuan Chen ◽  
Ting Wang ◽  
Yunjie Li ◽  
Jing Liang ◽  
Dan Wellburn ◽  
...  

2009 ◽  
Vol 152-153 ◽  
pp. 15-18 ◽  
Author(s):  
E. Voronina ◽  
Eugene P. Yelsukov ◽  
A. Korolyov ◽  
S. Nagamatsu ◽  
T. Fujikawa ◽  
...  

The results of magnetometric, Mössbauer and XMCD (X-ray Magnetic Circular Dichroism) studies of B2 or DO3–type ordered (25 to 35 at.%Al) and disordered by mechanical activation (35 to 60 at.% Al) Fe-Al alloys are considered. For the description of magnetic characteristics of the studied alloys the validity of local magnetic moments models is discussed. The models suppose that Fe atom local magnetic moments are collinear with magnitude and direction depending on the number of Al atoms in the Fe nearest neighbourhood.


2014 ◽  
Vol 115 (17) ◽  
pp. 17B530 ◽  
Author(s):  
E. A. Denisova ◽  
L. A. Kuzovnikova ◽  
R. S. Iskhakov ◽  
A. A. Bukaemskiy ◽  
E. V. Eremin ◽  
...  

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