CRYSTAL STRUCTURE, ELECTROCHEMICAL AND MAGNETIC PROPERTIES OF A NEW BINUCLEAR COPPER(II) COMPLEX WITH BENZOIC ACID AS A LIGAND

2017 ◽  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Benzoic Acid ◽  
Binuclear Copper ◽  
Electrochemical And Magnetic Properties

Crystal structure and magnetic properties of binuclear copper(II) complex with 2-N-(phenylhydrazono)-3-((ethyl-2-olato)imino)-1-phenyl-1,2,3-butanetrione

2016 ◽  
Vol 42 (2) ◽  
pp. 81-84
Author(s):  
L. D. Popov ◽  
S. I. Levchenkov ◽  
I. N. Shcherbakov ◽  
V. V. Tkachev ◽  
G. V. Shilov ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Binuclear Copper

Antiferromagnetic Coupling In A (μ-Hydroxo)(μ-Pyrazolato)Dicopper(II) Complex. Synthesis, Crystal Structure, Magnetic Properties, And Theoretical Studies

2001 ◽  
Vol 56 (8) ◽  
pp. 719-727 ◽  
Author(s):  
H. Kara ◽  
Y. Elerman ◽  
K. Prout
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Variable Temperature ◽  
Magnetic Behaviour ◽  
Antiferromagnetic Coupling ◽  
Theoretical Studies ◽  
Powdered Sample ◽  
Structural Factors ◽  
Binuclear Copper ◽  
Ligand Orbital

Preparation, crystal structure and magnetic properties of a 3,5-dimethylpyrazolate bridged binuclear copper(II) complex [Cu2(L1)(3,5 prz)] (L1 = 1,3-Bis(2-hydroxy-1-napthylideneamino) propan-2-ol) (1) are reported. Variable-temperature magnetic susceptibility measurements for a powdered sample of the complex were carried out in the temperature range 5 - 350 K and analysed to obtain values of the parameter J in the exchange Hamiltonian H = -2JS1·S2 . In the dicopper(II) complex [Cu2(L2)(3,5 prz)], (L2 = l,3-Bis(2-hydroxy-5-chlorosalicylideneamino) propan-2-ol) (2) reported recently the antiferromagnetic interaction is much less than that of 1 (-27 = 440 cm-1 ), as result which is difficult to explain in terms of structural factors on the basis of widely accepted criteria. The differences in the magnetic behaviour now have been rationalized using the “ligand orbital complementary” concept

Synthesis, crystal structure and magnetic properties of a new oxalato-bridged binuclear copper(II) complex with a tridentate Schiff base ligand

Polyhedron ◽  
2001 ◽  
Vol 20 (17) ◽  
pp. 2113-2116 ◽  
Author(s):  
Bappaditya Bag ◽  
Nijhuma Mondal ◽  
Samiran Mitra ◽  
Volker Gramlich ◽  
Joan Ribas ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Binuclear Copper ◽  
Tridentate Schiff Base
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