Crystal structures and luminescence properties of a one-dimensional cadmium coordination polymer derived from a flexible bis(IMIDAZOLE) ligand

2016 ◽  
Keyword(s):  
Coordination Polymer ◽  
Crystal Structures ◽  
Luminescence Properties ◽  
One Dimensional ◽  
Imidazole Ligand ◽  
Cadmium Coordination Polymer

scholarly journals catena-Poly[(acetatochloridozinc)-μ-1,1′-[1,4-phenylenebis(methylene)]di-1H-imidazole]

2013 ◽  
Vol 69 (2) ◽  
pp. m102-m102
Author(s):  
Liang Wang
Keyword(s):  
Coordination Polymer ◽  
Title Compound ◽  
Mirror Plane ◽  
One Dimensional ◽  
Axis Direction ◽  
Imidazole Ligand ◽  
Cl Atom ◽  
Zigzag Structure

The title compound, [Zn(CH3CO2)Cl(C14H14N4)]n, is a one-dimensional coordination polymer in which the ZnIIion is tetrahedrally coordinated by two N atoms of a bridging 1,1′-[1,4-phenylenebis(methylene)]di-1H-imidazole ligand, an acetate O atom and a Cl atom. The Cl atom, two acetate O atoms and two acetate C atoms are located on a mirror plane. The coordination of the diimidazole ligand to the ZnIIion gives an infinite one-dimensional zigzag structure along theb-axis direction with the charge balanced by the chloride and acetate ions.

Syntheses, crystal structures, magnetochemistry and catechol oxidase activity of a tetracopper(ii) compound and a new type of dicopper(ii)-based 1D coordination polymer

2017 ◽  
Vol 41 (11) ◽  
pp. 4689-4701 ◽  
Author(s):  
Leena Mandal ◽  
Shuvankar Mandal ◽  
Sasankasekhar Mohanta
Keyword(s):  
Schiff Base ◽  
Coordination Polymer ◽  
Crystal Structures ◽  
Schiff Base Ligand ◽  
Oxidase Activity ◽  
Catechol Oxidase ◽  
Tetranuclear Cluster ◽  
One Dimensional ◽  
1D Coordination Polymer ◽  
New Type

One phenoxo–hydroxo bridged tetranuclear cluster and one phenoxo-µ1,1-azido-µ1,3-azido bridged one-dimensional coordination polymer of copper(ii) derived from a Schiff base ligand are described.

A Two-Dimensional Coordination Polymer Formed from Cobalt(II) and an Extended Dipyridyl Ligand

2020 ◽  
Vol 73 (6) ◽  
pp. 547 ◽  
Author(s):  
Hydar A. AL-Fayaad ◽  
Rashid G. Siddique ◽  
Kasun S. Athukorala Arachchige ◽  
Jack K. Clegg
Keyword(s):  
Coordination Polymer ◽  
Cell Volume ◽  
Crystal Structures ◽  
Unit Cell Volume ◽  
Suzuki Coupling ◽  
Unit Cell ◽  
Square Lattice ◽  
Two Dimensional ◽  
Cobalt Ions ◽  
One Dimensional

The synthesis of the extended dipyridyl ligand 4,4′-(2,5-dimethyl-1,4-phenylene)dipyridine (L) in an improved yield via the palladium catalysed Suzuki coupling of 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine (1) and 1,4-dibromo-2,5-dimethylbenzene (2) is reported along with its use to form a two-dimensional coordination polymer [Co2L2(OAc)4(H2O)2]n. The coordination polymer consists of one-dimensional chains of octahedral cobalt ions bridged by acetate ligands which are connected to form two dimensional sheets with square lattice (sql) topology via the dipyridyl ligands (L). The structure contains small voids totalling ~6.6% of the unit cell volume. The crystal structures 1, L, L·2H2O, and L·2HNO3 are also reported.

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