scholarly journals ALLUVIAL PLATINUM-GROUP MINERALS AS INDICATORS OF PRIMARY PGE MINERALIZATION (placers of southern Siberia)

2016 ◽  
Keyword(s):  
Southern Siberia ◽  
Platinum Group Minerals ◽  
Pge Mineralization ◽  
Platinum Group

Alluvial platinum-group minerals as indicators of primary PGE mineralization (placers of southern Siberia)

2016 ◽  
Vol 57 (10) ◽  
pp. 1437-1464 ◽  
Author(s):  
S.M. Zhmodik ◽  
G.V. Nesterenko ◽  
E.V. Airiyants ◽  
D.K. Belyanin ◽  
V.V. Kolpakov ◽  
...  
Keyword(s):  
Southern Siberia ◽  
Platinum Group Minerals ◽  
Pge Mineralization ◽  
Platinum Group

scholarly journals Micrometric Inclusions in Platinum-Group Minerals from Gornaya Shoria, Southern Siberia, Russia: Problems and Genetic Significance

Minerals ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 327 ◽  
Author(s):  
Gleb V. Nesterenko ◽  
Sergey M. Zhmodik ◽  
Dmitriy K. Belyanin ◽  
Evgeniya V. Airiyants ◽  
Nikolay S. Karmanov
Keyword(s):  
Energy Dispersive Spectrometry ◽  
Present Contribution ◽  
Southern Siberia ◽  
Good Convergence ◽  
Wavelength Dispersive Spectrometry ◽  
Platinum Group Minerals ◽  
Genetic Significance ◽  
Sulfide Melt ◽  
The Subject ◽  
Platinum Group

Micrometric inclusions in platinum-group minerals (PGMs) from alluvial placers carry considerable information about types of primary rocks and ores, as well as conditions of their formation and alteration. In the present contribution, we attempt to show, with concrete examples, the significance of the data on the composition and morphology of micrometric inclusions to genetic interpretations. The PGM grains from alluvial placers of the Gornaya Shoria region (Siberia, Russia) were used as the subject of our investigation. In order to determine the chemical composition of such ultrafine inclusions, high-resolution analytical methods are needed. We compare the results acquired by wavelength-dispersive spectrometry (WDS; electron microprobe) and energy-dispersive spectrometry (EDS) and scanning electron microscopy (SEM) methods. The results obtained have good convergence. The EDS method is multi-elemental and more effective for mineral diagnostics in comparison with WDS, which is its certain advantage. The possible conditions for the formation of inclusions and layers of gold, sulfoarsenides and arsenides in Pt3Fe grains, which have an original sub-graphic and layered texture pattern, are discussed. They are the result of solid solution and eutectic decompositions and are associated with the magmatic stages of grain transformation, including the result of the interaction of Pt3Fe with a sulfide melt enriched with Te and As.

Magnetic signature of magnetite‐enriched rocks hosting platinum‐group element mineralization within the Archean Boston Creek Flow, Ontario

Geophysics ◽  
1998 ◽  
Vol 63 (2) ◽  
pp. 440-445 ◽  
Author(s):  
Michelle S. Larson ◽  
William E. Stone ◽  
William A. Morris ◽  
James H. Crocket
Keyword(s):  
Platinum Group Element ◽  
Magnetic Anomalies ◽  
Ore Deposits ◽  
Group Element ◽  
Rock Types ◽  
Platinum Group Minerals ◽  
Pge Mineralization ◽  
Geophysical Surveys ◽  
Close Proximity ◽  
Platinum Group

Ground‐based magnetometer surveys detect high‐positive magnetic anomalies (up to 72 000 nT) which coincide with the location of subeconomic, magnetite‐associated platinum‐group element (PGE) mineralization within the Boston Creek Flow iron‐rich basalt, Archean Abitibi Greenstone Belt, Ontario. The magnetic anomalies confirm the presence of magnetite‐enriched zones (up to 20 modal%), and reveal that they are ovoid in shape, up to 10 m in size, and along strike from each other in the central gabbro‐diorite layer. Geological and geochemical surveys and mineralogical studies indicate that these zones host smaller zones of disseminated chalcopyrite + pyrite, some of which, in turn, host platinum‐group minerals (PGM) and are enriched in PGE and related metals (whole‐rock [Formula: see text], Ag = 1300 ppb, Cu = 0.3%, V = 0.1%, Ni = 0.05%, Ti = 2.5%, and Fe = 25%). The coincidence of the high‐positive magnetic anomalies with the location of PGE mineralization, points to ground‐based magnetometer surveys as a valuable exploration tool for magnetite‐associated PGE ore deposits. The distribution of the residual magnetic field anomalies indicate that such surveys are especially useful in: (1) identifying rock types and mapping their distribution in areas of limited outcrop exposure; (2) locating magnetite‐enriched gabbroic rock bodies, even in close proximity to serpentinized olivine cumulate rocks; and (3) delineating the detailed geometry of magnetite‐enriched rocks that may carry significant amounts of PGE and PGMs. Exploration strategies should be designed to use ground‐based geophysical surveys, in conjunction with geological and geochemical surveys, to locate and delineate the geometry of magnetite‐enriched zones within thick, differentiated mafic‐ultramafic volcanic flows and plutonic bodies.

Ophiolite-related associations of platinum-group minerals at Rudnaya, western Sayans and Miass, southern Urals, Russia

2018 ◽  
Vol 82 (3) ◽  
pp. 515-530 ◽  
Author(s):  
Andrei Y. Barkov ◽  
Nadezhda D. Tolstykh ◽  
Gennadiy I. Shvedov ◽  
Robert F. Martin
Keyword(s):  
Southern Urals ◽  
Chromian Spinel ◽  
Type Alloy ◽  
Chelyabinsk Oblast ◽  
The Southern Urals ◽  
Platinum Group Minerals ◽  
Pge Mineralization ◽  
Fe Alloys ◽  
Platinum Group ◽  
Western Sayan

ABSTRACTWe describe similar assemblages of minerals found in two placers in Russia, both probably derived from an ophiolitic source. The first is located along the River Rudnaya in the western Sayan province, Krasnoyarskiy kray, and the second pertains to the Miass placer zone, Chelyabinsk oblast, in the southern Urals. The platinum-group element (PGE) mineralization in both cases is mostly (at least 80%) represented by alloy minerals in the system Ru–Os–Ir, in the order of occurrence osmium, ruthenium and iridium. The remainder consists of Pt–Fe alloys and species of PGE sulfides, arsenides, sulfarsenides, etc. The associated olivine and amphiboles are supermagnesian, and the chromian spinel has a high Cr# value. The observed enrichment in Ru, typical of an ophiolitic source, may be due to high-temperature hydrothermal equilibration and mobilization in the ophiolite, as is the enrichment in Mg and Cr. Low-temperature replacement of the alloys led to the development of laurite, sulfoarsenides and arsenides. Some placer grains in both suites reveal unusual phases of sulfo-arsenoantimonides of Ir–Rh, e.g. the unnamed species (Rh,Ir)SbS and (Cu,Ni)1+x(Ir,Rh)1–xSb, wherex= 0.2, and rhodian tolovkite, (Ir,Rh)SbS. Two series of natural solid-solutions appear to occur in the tolovkite-type phases. Among the oddities in the Rudnaya suite are globules of micrometric PGE sulfides, crystallites of platinum-group minerals, amphibole, and chalcopyrite bearing skeletal micrometric monosulfide-like compounds (Cu,Pt,Rh)S and (Pd,Cu)S1–x. Pockets of fluxed evolved melt seem to have persisted well below the solidus of the host Pt3Fe-type alloy.

Platinum-group minerals of the F and T zones, Waterberg Project, far northern Bushveld Complex: implication for the formation of the PGE mineralization

2018 ◽  
Vol 82 (3) ◽  
pp. 539-575 ◽  
Author(s):  
Matthew J. G. McCreesh ◽  
Marina A. Yudovskaya ◽  
Judith A. Kinnaird ◽  
Christian Reinke
Keyword(s):  
Bushveld Complex ◽  
Magmatic Sulfides ◽  
Platinum Group Minerals ◽  
Pge Mineralization ◽  
Base Metal Sulfides ◽  
Fe Alloys ◽  
Platinum Group ◽  
Current Stage ◽  
Southern Marginal Zone ◽  
Sulfide Assemblage

ABSTRACTThis study provides the first detailed mineralogical data on platinum-group element (PGE) mineralization of the Waterberg Project, in a previously unknown segment of the Bushveld Complex located in the Southern Marginal Zone of the Limpopo Belt. The lower ultramafic F zone is dominated by sperrylite (up to 82 area%) with minor Pt–Pd bismuthotellurides, Pd–Ni arsenides, Au–Ag alloy, Rh–Pt sulfoarsenides and rare Pt–Fe alloys. The upper more felsic-rich gabbroic T zone is dominated by Pt–Pd bismuthotellurides (up to 90 area%), Pd tellurides and Au–Ag alloy with rare sperrylite, braggite, Pd stannides and antimonides. The platinum-group minerals (PGM) of the F zone are associated mainly with magmatic base-metal sulfides (pyrrhotite, troilite, chalcopyrite and pentlandite), that have undergone alteration during significant serpentinization, accompanied by the formation of the secondary sulfide assemblage. The T zone in a leucogabbroic sequence contains relics of magmatic sulfides and is characterized by the development of the indicative chalcopyrite-millerite-pyrite assemblage, which is associated with widespread hydrothermal quartz and hydrous silicates (amphiboles, phlogopite, epidote and chlorite). The fluid-induced style of PGM remobilization, the high Au/PGE and the high proportion of native gold in the high-grade T zone ores in the magnetite-bearing leucogabbroic rocks are unique to the Bushveld Complex. The genesis of the T ores is interpreted as a result of primary PGE enrichment in the zone of interaction between the first influxes of the Upper Zone fertile melt and a resident gabbroic melt at the top of the Troctolite-Gabbronorite-Anorthosite (TGA) fractionated sequence with subsequent fluid remobilization. Whether the hydrothermal overprint facilitated the PGE sequestration in a favourable setting or dispersed the pre-existing magmatic concentrations along fluid pathways remains essentially unresolved at the current stage.

scholarly journals Tamuraite, Ir5Fe10S16, a New Species of Platinum-Group Mineral from the Sisim Placer Zone, Eastern Sayans, Russia

Minerals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 545
Author(s):  
Andrei Y. Barkov ◽  
Nadezhda D. Tolstykh ◽  
Robert F. Martin ◽  
Andrew M. McDonald
Keyword(s):  
National Laboratory ◽  
X Ray Diffraction ◽  
Calculated Density ◽  
Cell Parameters ◽  
Reflected Light ◽  
Platinum Group Minerals ◽  
Platinum Group ◽  
Probable Space ◽  
Layered Complex ◽  
Residual Melt

Tamuraite, ideally Ir5Fe10S16, occurs as discrete phases (≤20 μm) in composite inclusions hosted by grains of osmium (≤0.5 mm across) rich in Ir, in association with other platinum-group minerals in the River Ko deposit of the Sisim Placer Zone, southern Krasnoyarskiy Kray, Russia. In droplet-like inclusions, tamuraite is typically intergrown with Rh-rich pentlandite and Ir-bearing members of the laurite–erlichmanite series (up to ~20 mol.% “IrS2”). Tamuraite is gray to brownish gray in reflected light. It is opaque, with a metallic luster. Its bireflectance is very weak to absent. It is nonpleochroic to slightly pleochroic (grayish to light brown tints). It appears to be very weakly anisotropic. The calculated density is 6.30 g·cm−3. The results of six WDS analyses are Ir 29.30 (27.75–30.68), Rh 9.57 (8.46–10.71), Pt 1.85 (1.43–2.10), Ru 0.05 (0.02–0.07), Os 0.06 (0.03–0.13), Fe 13.09 (12.38–13.74), Ni 12.18 (11.78–13.12), Cu 6.30 (6.06–6.56), Co 0.06 (0.04–0.07), S 27.23 (26.14–27.89), for a total of 99.69 wt %. This composition corresponds to (Ir2.87Rh1.75Pt0.18Ru0.01Os0.01)Σ4.82(Fe4.41Ni3.90Cu1.87Co0.02)Σ10.20S15.98, calculated based on a total of 31 atoms per formula unit. The general formula is (Ir,Rh)5(Fe,Ni,Cu)10S16. Results of synchrotron micro-Laue diffraction studies indicate that tamuraite is trigonal. Its probable space group is R–3m (#166), and the unit-cell parameters are a = 7.073(1) Å, c = 34.277(8) Å, V = 1485(1) Å3, and Z = 3. The c:a ratio is 4.8462. The strongest eight peaks in the X-ray diffraction pattern [d in Å(hkl)(I)] are: 3.0106(26)(100), 1.7699(40)(71), 1.7583(2016)(65), 2.7994(205)(56), 2.9963(1010)(50), 5.7740(10)(45), 3.0534(20)(43) and 2.4948(208)(38). The crystal structure is derivative of pentlandite and related to that of oberthürite and torryweiserite. Tamuraite crystallized from a residual melt enriched in S, Fe, Ni, Cu, and Rh; these elements were incompatible in the Os–Ir alloy that nucleated in lode zones of chromitites in the Lysanskiy layered complex, Eastern Sayans, Russia. The name honors Nobumichi Tamura, senior scientist at the Advanced Light Source of the Lawrence Berkeley National Laboratory, Berkeley, California.

DETRITAL PLATINUM-GROUP MINERALS IN RIVERS DRAINING THE EASTERN BUSHVELD COMPLEX, SOUTH AFRICA

2004 ◽  
Vol 42 (2) ◽  
pp. 563-582 ◽  
Author(s):  
T. Oberthur ◽  
F. Melcher ◽  
L. Gast ◽  
C. Wohrl ◽  
J. Lodziak
Keyword(s):  
South Africa ◽  
Bushveld Complex ◽  
Platinum Group Minerals ◽  
Platinum Group

Sulfide mineral chemistry and platinum-group minerals of the UG-2 chromitite in the northern limb of the Bushveld Igneous Complex, South Africa

2021 ◽  
Vol 59 (6) ◽  
pp. 1339-1362
Author(s):  
Malose M. Langa ◽  
Pedro J. Jugo ◽  
Matthew I. Leybourne ◽  
Danie F. Grobler
Keyword(s):  
Platinum Group Element ◽  
Mineral Chemistry ◽  
Sulfide Mineral ◽  
Sulfide Minerals ◽  
Group Element ◽  
Igneous Complex ◽  
Northern Limb ◽  
Platinum Group Minerals ◽  
Platinum Group ◽  
Bushveld Igneous Complex

ABSTRACT The UG-2 chromitite layer, with its elevated platinum-group element content, is a key marker horizon in the eastern and western limbs of the Bushveld Igneous Complex and the largest platinum-group element chromite-hosted resource of its kind in the world. In contrast, much less is known about its stratigraphic equivalent in the northern limb, the “UG-2 equivalent” (UG-2E) chromitite. Recent studies on chromite mineral chemistry show similarities between the UG-2 and sections of the UG-2E, but also that the UG-2E was partially contaminated by assimilation of local metasedimentary rocks. Here, we provide a detailed characterization of sulfide minerals and platinum-group minerals in a suite of samples from the UG-2E and compare the results with data obtained from a reference suite of samples from the UG-2. Results from petrographic observations, electron probe microanalysis, laser ablation-inductively coupled plasma-mass spectrometry, quantitative evaluation of materials by scanning electron microscopy, and δ34S isotopes show that: (1) sulfide minerals in the UG-2E and UG-2 consist mainly of pentlandite-chalcopyrite-pyrrhotite, but pyrrhotite is significantly more abundant in the UG-2E and almost absent in the UG-2; (2) iron contents in pentlandite from the UG-2E are significantly higher than in the UG-2; (3) platinum-group element contents within sulfide minerals are different between the two chromitites; (4) UG-2E platinum-group minerals are dominated by arsenides and bismuthotellurides, and by alloys and platinum-group element-sulfide minerals in the UG-2; (5) sulfide mineral chemistry and δ34S values indicate some crustal contamination of the UG-2E; and (6) sulfide mineral and secondary silicate mineral textures in both the UG-2E and UG-2 are indicative of minor, millimeter- to centimeter-scale, hydrothermal alteration. From our observations and results, we consider the UG-2E chromitite in the northern limb to be the equivalent to the UG-2 in the eastern and western limbs that has been contaminated by assimilation of Transvaal Supergroup footwall rocks during emplacement. The contamination resulted in UG-2E sulfide mineral elemental contents and platinum-group mineral types and abundances that are distinct from those of the UG-2 in the rest of the Bushveld.

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