Studies of the Thermal Behaviour of Organosolvent Lignins Extracted from Abies and Aspen Wood

Keyword(s):  
1992 ◽  
Vol 7 (1) ◽  
pp. 17-21a ◽  
Author(s):  
Félix Carrasco ◽  
Jacques J. Garceau ◽  
Aziz Ahmed ◽  
Bohuslav V. Kokta
Keyword(s):  

2017 ◽  
Vol 68 (8) ◽  
pp. 1895-1902
Author(s):  
Ioana Cristina Tita ◽  
Eleonora Marian ◽  
Bogdan Tita ◽  
Claudia Crina Toma ◽  
Laura Vicas

Thermal analysis is one of the most frequently used instrumental techniques in the pharmaceutical research, for the thermal characterization of different materials from solids to semi-solids, which are of pharmaceutical relevance. In this paper, simultaneous thermogravimetry/derivative thermogravimetry (TG/DTG) and differential scanning calorimetry (DSC) were used for characterization of the thermal behaviour of candesartan cilexetil � active substance (C-AS) under dynamic nitrogen atmosphere and nonisothermal conditions, in comparison with pharmaceutical product containing the corresponding active substance. It was observed that the commercial samples showed a different thermal profile than the standard sample, caused by the presence of excipients in the pharmaceutical product and to possible interaction of these with the active substance. The Fourier transformed infrared spectroscopy (FT-IR) and X-ray powder diffraction (XRPD) were used as complementary techniques adequately implement and assist in interpretation of the thermal results. The main conclusion of this comparative study was that the TG/DTG and DSC curves, together with the FT-IR spectra, respectively X-ray difractograms constitute believe data for the discrimination between the pure substance and pharmaceutical forms.


Author(s):  
И.В. Коваленко ◽  
М.А. Чубинский ◽  
Д.С. Русаков ◽  
Г.С. Варанкина

Применение древесины осины в промышленном производстве материалов и изделий ограничено из-за ее низких механических свойств, подверженности поражению коррозионно-деструктивной гнили, отсутствием должного обоснования технологии ее переработки. Невостребованная осина осложняет условия хозяйствования в лесу, ухудшает породный состав древостоев, препятствует восстановлению хвойных пород древесины. Древесина осины хуже смачивается водой по сравнению с другими породами. Изучение ее поверхностных свойств и строения на микроуровне представляет безусловный интерес для изучения взаимодействия древесины с водой, жидкими клеящими и защитно-декоративными веществами. Это сложная многопараметрическая задача, решение которой может явиться новым инструментом для обоснования наукоемких технологических процессов сушки, пропитки, склеивания и облагораживания древесины. Истинная поверхность древесины, образованная в результате обработки резанием (лущением, пилением, фрезерованием) значительно больше ее проекции на плоскости в результате разрезания микроструктурных элементов. Неровности на поверхности искажают результаты измерения поверхностных свойств, определяемых на основе угла смачивания. Учитывая то, что размеры стенок клеток меньше размеров полостей, истинная площадь поверхности древесины, в зависимости от вида разреза, может в десятки раз превышать кажущуюся. Ухудшение способности смачиваться объясняет образование на поверхности капель клея, нанесенного на шпон методом вальцевания. При горячем прессовании фанеры в первый момент времени повышается подвижность молекул клея, снижается упругость древесины, поверхность выравнивается, улучшая условия адгезионного взаимодействия связующего и древесины. Для определения истинных характеристик древесины, обоснования расхода клея, способности древесины поглощать жидкость необходимо знать размеры ее микроструктурных элементов и характер их распределения, объем поверхностных полостей. Эффективный радиус полостей древесины осины может быть описан с использованием теории фракталов. The use of aspen wood in manufacturing of materials and products is limited due to its low mechanical properties, corrosion susceptibility destructive lesion decay, its lack of proper justification processing technology. Unclaimed aspen difficult economic conditions in the forest, degrades the species composition of forest stands and prevents restoration of softwood. Wood aspen worse moistened with water compared to other breeds. The study of its structure and surface properties at the micro level is of great interest to study the interaction of wood with water, liquid adhesives and protective-decorative materials. This is the problem whose solution can be a new tool for the study of science-intensive technological processes of drying, impregnation, gluing and surface finishes. Real wood surface, formed by the machining (peeling, sawing, milling) significantly greater its projection on the plane as a result of cutting the microstructural elements. Surface irregularities distort the results of measurement of surface properties which are determined based on the contact angle. Given that the size of the cell walls is less than the size of the cavities, the true surface area of the veneer, depending on the type of incision, may be ten times the apparent. The deterioration of the ability of wetted explains the formation of droplets on the surface of adhesive deposited on the veneer by rolling. When plywood hot pressing at a first time increases mobility of adhesive molecules, decreases the modulus of elasticity of wood, surface is aligned, improving the conditions of interaction of the glue and the wood. To determine the true characteristics of the wood, glue flow study, the ability of wood to absorb liquid it is necessary to know the size of microstructural elements and their distribution, the amount of surface cavities. The effective radius of aspen wood cavities can be described using fractal theory.


Proceedings ◽  
2020 ◽  
Vol 58 (1) ◽  
pp. 31
Author(s):  
Jeremy Arancio ◽  
Ahmed Ould El Moctar ◽  
Minh Nguyen Tuan ◽  
Faradj Tayat ◽  
Jean-Philippe Roques

In the race for energy production, supplier companies are concerned by the thermal rating of offshore cables installed in a J-tube, not covered by IEC 60287 standards, and are now looking for solutions to optimize this type of system. This paper presents a numerical model capable of calculating temperature fields of a power transmission cable installed in a J-tube, based on the lumped element method. This model is validated against the existing literature. A sensitivity analysis performed using Sobol indices is then presented in order to understand the impact of the different parameters involved in the heating of the cable. This analysis provides an understanding of the thermal phenomena in the J-tube and paves the way for potential technical and economic solutions to increase the ampacity of offshore cables installed in a J-tube.


Holzforschung ◽  
2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Hüseyin Pelit ◽  
Fatih Emiroglu

AbstractIn this study, the effect of thermo-mechanical densification on the density, hardness, compression strength, bending strength (MOR), and modulus of elasticity (MOE) of fir and aspen wood pretreated with water repellents was analyzed. Wood specimens were impregnated with paraffin, linseed oil and styrene after pre-vacuum treatment. Then, the impregnated wood specimens were densified with compression ratios of 20 and 40%, and at 120, 150 and 180 °C. The results indicated that the density, hardness and strength properties of the all densified specimens (untreated and impregnated) increased depending on the compression ratio and temperature. For all tested properties, higher increases were obtained in the paraffin and styrene pretreated specimens compared to untreated samples. However, the increase rates in linseed oil pretreated specimens were generally lower than untreated specimens. Regarding water repellents the most successful results in all tested properties were determined in styrene pretreated specimens. The density, hardness and strength properties of all specimens increased with the increase in compression ratio. On the other hand, the increase in the compression temperature negatively affects the properties of untreated and linseed oil pretreated specimens, while having a generally positive effect on the properties of paraffin pretreated specimens. However, all tested properties of styrene pretreated specimens have increased significantly due to the increase in compression temperature. The increasing strength properties of wood as a result of densification have increased much more with paraffin and especially styrene pretreatment. These combinations can be considered as an important potential for applications that require more hardness and strength.


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