scholarly journals A NEW COMPUTATIONAL MODEL TO AUGMENT THE DESIGN OF MICROFLUIDIC SEPARATIONS: ELECTRIC FIELD ASSISTED, HYDRODYNAMIC CHROMATOGRAPHY

2012 ◽  
Author(s):  
Jeffrey D Wells
2012 ◽  
Vol 62 ◽  
pp. 154-164 ◽  
Author(s):  
Morteza Moghimi Waskasi ◽  
Seyed Majid Hashemianzadeh ◽  
Omolbanin (Setare) Mostajabi Sarhangi ◽  
Asqar Pourhassan Harzandi

2021 ◽  
Vol 14 (6) ◽  
pp. 1700
Author(s):  
Gozde Unal ◽  
Jaiti Swami ◽  
Carliza Canela ◽  
Samantha Cohen ◽  
Niranjan Khadka ◽  
...  

Aerospace ◽  
2006 ◽  
Author(s):  
Xingxi He ◽  
Donald J. Leo ◽  
Thomas Wallmersperger

The transport of charge due to electric stimulus is the primary mechanism of actuation for a class of polymeric active materials known as ionomeric polymer transducers (IPTs). A two-dimensional ion hopping model has been built to describe ion transport in the IPT. In a Monte Carlo simulation, a square lattice of 50nm × 50nm is investigated containing 200 cations and 200 anions. Step voltages are applied between the electrodes of the IPT, causing the thermally-activated hopping between multiwell energy structures. The energy barrier height includes three parts: intrinsic energy, energy height due to the electric field and energy height due to ion-ion interactions. Periodic boundary conditions have been applied in the direction perpendicular to the electric field. The influence of the electrodes on both faces of IPT is formulated by the method of image charges. The charge density profile over the material has been calculated by the ion distribution in steady state. The Monte Carlo simulation is repeated multiple times to obtain an average result of the charge density. The averaged profile shows regions of cation depletion close to the anode, charge neutrality in the central part and ion accumulation close to the cathode, which qualitatively agrees with the results from conventional continuum models. To quantatively examine the Monte Carlo simulation of the ion hopping model, comparisons with a computational model of transport and electromechanical transduction are performed. This computational model is based upon a coupled chemo-electrical multi-field formulation and computes the spatio-temporal charge density profile to an applied potential at the boundaries. It can be seen that both methods, the statistical theory and the continuum theory, match quite well and are both able to represent the actual behavior inside the IPT. Moreover, experiments are performed to validate the current density calculated by the Monte Carlo simulation. The active material is Nafion 117 (Dupont) in the form of a cantilevered transducer with conductive electrodes on both surfaces and with mobile Na+ counter-ions. Voltage inputs are provided by a dSPACE DS 1102 DSP and amplified using an HP power amplifier. The current is measured by placing a small resistor in series with the sample, between the sample and ground. The voltage across the resistor is amplified and measured by dSPACE. The electrical current is calculated by dividing the voltage drop across the resistor by its resistance. Current density in both simulation results and experimental results exhibits an exponential decay over time.


Author(s):  
G. F. Rempfer

In photoelectron microscopy (PEM), also called photoemission electron microscopy (PEEM), the image is formed by electrons which have been liberated from the specimen by ultraviolet light. The electrons are accelerated by an electric field before being imaged by an electron lens system. The specimen is supported on a planar electrode (or the electrode itself may be the specimen), and the accelerating field is applied between the specimen, which serves as the cathode, and an anode. The accelerating field is essentially uniform except for microfields near the surface of the specimen and a diverging field near the anode aperture. The uniform field forms a virtual image of the specimen (virtual specimen) at unit lateral magnification, approximately twice as far from the anode as is the specimen. The diverging field at the anode aperture in turn forms a virtual image of the virtual specimen at magnification 2/3, at a distance from the anode of 4/3 the specimen distance. This demagnified virtual image is the object for the objective stage of the lens system.


Author(s):  
Patrick P. Camus

The theory of field ion emission is the study of electron tunneling probability enhanced by the application of a high electric field. At subnanometer distances and kilovolt potentials, the probability of tunneling of electrons increases markedly. Field ionization of gas atoms produce atomic resolution images of the surface of the specimen, while field evaporation of surface atoms sections the specimen. Details of emission theory may be found in monographs.Field ionization (FI) is the phenomena whereby an electric field assists in the ionization of gas atoms via tunneling. The tunneling probability is a maximum at a critical distance above the surface,xc, Fig. 1. Energy is required to ionize the gas atom at xc, I, but at a value reduced by the appliedelectric field, xcFe, while energy is recovered by placing the electron in the specimen, φ. The highest ionization probability occurs for those regions on the specimen that have the highest local electric field. Those atoms which protrude from the average surfacehave the smallest radius of curvature, the highest field and therefore produce the highest ionizationprobability and brightest spots on the imaging screen, Fig. 2. This technique is called field ion microscopy (FIM).


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