scholarly journals Influence of Organic Molecules on the Luminescent Properties of Composites Based on CdS Quantum Dots

2017 ◽  
Vol 18 (4) ◽  
pp. 426-430
Author(s):  
V. A. Smyntyna ◽  
V. M. Skobeeva ◽  
K. A. Verheles ◽  
M. V. Malushin

The influence of methylene blue (MB) and acridine yellow (AY) dyes on the spectra of luminescence of CdS with quantum dots (QD) dye composites is investigated. It is shown that the luminescence spectrum of the heterosystem of nanocrystals (NC) CdS – the dye depends on the absorption region of it. The spectrum of the luminescence of the quantum dots is shifted to the red region by the introduction into the colloidal solution of the MB dye and in a case of the insertion of AY the spectrum is shifted into the blue region. The obtained results are explained in a point of view of the transferring the energy from the CdS quantum dots to the dyes by the Forster mechanism.

2011 ◽  
Vol 306-307 ◽  
pp. 1334-1337 ◽  
Author(s):  
Meng Zhang ◽  
Fu Wei Wan ◽  
Shen Guang Ge ◽  
Jing Hua Yu

We report the synthesis and characterization of a low-cost high-quality CdS quantum dots (QDs).The synthesis was performed in aqueous system. The aqueous CdS colloidal solution was prepared using thioglycollic acid as a capping agent. Zetasizer Nano ZS (Malvern, UK) was employed to characterize the partical size of CdS QDs. The UV-vis and photoluminescence (PL) spectra of samples were systematically characterized (the full width at half maximum was 38 nm). The maximum photoluminescence (PL) quantum yield (QY) was as high as 68.5 %. The fluorescence intensity was enhanced by copper (II). The relative fluorescence intensity was linear to copper (II) concentration over the range 4.0 ×10-6 - 2.8×10-5 g mL-1. The regression equation was ΔIF= 59.07+ 90.57c (c / μg mL-1). The highly monodispersed CdS QDs could be used in many fields.


2014 ◽  
Vol 16 (3) ◽  
Author(s):  
Oleg V. Ovchinnikov ◽  
Michail S. Smirnov ◽  
Tamara S. Shatskikh ◽  
Vladimir Yu. Khokhlov ◽  
Boris I. Shapiro ◽  
...  

2019 ◽  
Vol 90 ◽  
pp. 162-170 ◽  
Author(s):  
Oluwasesan Adegoke ◽  
Hanieh Montaseri ◽  
Sifiso A. Nsibande ◽  
Patricia B.C. Forbes

2014 ◽  
Vol 156 ◽  
pp. 212-218 ◽  
Author(s):  
M.S. Smirnov ◽  
O.V. Ovchinnikov ◽  
T.S. Shatskikh ◽  
A.G. Vitukhnovsky ◽  
S.A. Ambrozevich ◽  
...  

Author(s):  
S. A. Tikhomirov

The transient absorption spectra dynamics for hybrid associates of colloidal CdS quantum dots, passivated by thioglycolic acid (CdS/TGA QDs), and methylene blue cationic dye molecules (MB+) were studied by femtosecond spectroscopy. It was established that one of the main channels of relaxation of the CdS/TGA QDs excitation energy in hybrid associates based on CdS/TGA QDs and MB+ is a fast energy transfer to the reduced forms of MB+ (MBOH•, MB•) that are formed still at the synthesis stage of samples. This channel strongly competes with the resonant energy transfer from the centers of radiative recombination in quantum dots to MB+. Therefore, for hybrid associates based on QDs/TGA and methylene blue, there is no any noticeable signal of the transient absorption corresponding to the triplet state of MB+ dye, which is then known to be actively involved in charge transfer.


Sign in / Sign up

Export Citation Format

Share Document