scholarly journals Patterns of non-traditional thermodynamic functions ΔrG0/n and ΔfG0(averaged) changes for cobalt minerals

2020 ◽  
pp. 22-30
Author(s):  
Khabibulla Ospanov ◽  
Kenzhegali Smailov ◽  
Yeldar Nuruly
Keyword(s):  
Thermodynamic Functions ◽  
General Principle ◽  
Raw Materials ◽  
Scientific Basis ◽  
Chemical Affinity ◽  
Subsequent Reaction ◽  
Mineral Raw Materials ◽  
Liquid Boundary ◽  
The Difference ◽  
Solid Liquid

This article considers general principle of predicting the difference in the reactivity of minerals and solvents in the conditions of their interaction at the interface between solid and liquid for cobalt minerals in the processing of mineral raw materials. The ideas of new properties of chemical affinity which allowed to carry out the forecast of a choice of efficiency of action of the dissolving reagent for opening of hardly soluble minerals of cobalt and the forecast of consecutive passing of the competing reaction proceeding on solid-liquid boundary at processing of mineral raw materials by a hydrochemical method at the level of an electron are stated. Previously unknown pattern of change the effectiveness of the solvent of the reagents and the sequence of passing a competing reaction was established, namely, that the effectiveness of the solvent of the reagent and the sequence of passing the subsequent reaction naturally varies with the calculated values given new chemical affinity (DrG0/n). It is practically proposed to use the average atomic energy of the formation of solids ΔfG0(averaged) and calculated value of the new chemical affinity DrG0/n to create scientific basis for the opening of cobalt minerals contained in the mineral raw materials with the least time.

scholarly journals The regionalization of territorial combinations of mineral deposits and mining territories of Ukraine

2019 ◽  
Keyword(s):  
Mineral Resource ◽  
Raw Materials ◽  
Mining Industry ◽  
Mineral Resources ◽  
Scientific Basis ◽  
Raw Material ◽  
Mineral Deposits ◽  
Resource Base ◽  
Mineral Raw Materials ◽  
Current State

The purpose of the article is using the data of Geoinform of Ukraine on the current state of the mineral resource base of the country, to regionalize its territory by combining explored mineral deposits and production-territorial complexes formed on their basis with a mineral raw material orientation. Research results. The article is written in the context of the constructive-geographical direction of studying the geography of mineral resources, which has been developing in the last decades in Ukraine. In particular, three approaches to regionalization of territorial combinations of mineral deposits are compared and analyzed: geological, economic-geographical and mining, which will contribute to their interconnection in characterizing the mineral-raw materials complexes of individual regions. The authors’ own interpretations of discussion definitions of mining terminology are proposed. Based on the results of previous studies and taking into account the current state of the mineral resource base, economic-geographical and mining zoning of the territory of Ukraine has been carried out for groups of explored mineral deposits. Within Ukraine, four mineral resource zones are allocated: Prydniprovsko-Pryazovska, Eastern Ukrainian, Donetsko-Slovianska and Prykarpatska, as well as several territorially separate structures: Zakarpatskyi, Lvivsko-Volynskyi, Podilskyi, Kerchenskyi, Krymskyi macrodistricts, Zhytomyrskyi and Pobuzkyi districts. A detailed description of the mineral and raw material specifications of these structures and their constituent parts, the features and prospects of their exploitation, the formation of territorial-production complexes of mineral and raw materials orientation are submitted. Scientific novelty. For the first time, various approaches to the regionalization of territorial groupings of mineral deposits and mining territories are compared, the basic definitions of mining regionalization are presented, and on this basis their own variant of zoning the territory of Ukraine on mineral resources is proposed. Practical value. The economic, geographical and mining zoning of the territory of Ukraine according to the forms of concentration of mineral deposits and mining areas will help create the scientific basis for optimizing the structure of the mining industry, ensuring the effective use of mineral raw materials, and developing the country's raw material complex.

scholarly journals Numerical Simulation of Three-Dimensional Dendrite Movement Based on the CA–LBM Method

Crystals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1056
Author(s):  
Qi Wang ◽  
Yingming Wang ◽  
Shijie Zhang ◽  
Binxu Guo ◽  
Chenyu Li ◽  
...  
Keyword(s):  
3D Model ◽  
Three Dimensional ◽  
Solidification Process ◽  
Movement Direction ◽  
Liquid Boundary ◽  
Alloy Microstructure ◽  
The Difference ◽  
Boltzmann Method ◽  
Solid Liquid ◽  
2D Model

At present, the calculation of three-dimensional (3D) dendrite motion using the cellular automata (CA) method is still in its infancy. In this paper, a 3D dendrite motion model is constructed. The heat, mass, and momentum transfer process in the solidification process of the alloy melt are calculated using a 3D Lattice–Boltzmann method (LBM). The growth process for the alloy microstructure is calculated using the CA method. The interactions between dendrites and the melt are assessed using the Ladd method. The solid–liquid boundary of the solute field in the movement process is assessed using the solute extrapolation method. The translational velocity of the equiaxed crystals in motion is calculated using the classical mechanical law. The rationality of the model is verified and the movement of single and multiple 3D equiaxed crystals is simulated. Additionally, the difference between 3D dendrite movement and two-dimensional (2D) dendrite movement is analyzed. The results demonstrate that the growth of moving dendrites is asymmetric. The growth velocity and falling velocity of the dendrite in the 3D model are faster than that in 2D model, while the simulation result is more realistic than that of the 2D model. When multiple dendrites move, the movement direction of the dendrites will change due to the merging of flow fields and other factors.

SELISIH BIAYA PRODUKSI SEBAGAI ALAT PENGENDALIAN MANAJEMEN PT INDO PUSAKA BERAU

2019 ◽  
Vol 3 (02) ◽  
pp. 397
Author(s):  
SAFITRI NURHIDAYATI ◽  
RIZKI AMELYA SYAM
Keyword(s):  
Raw Materials ◽  
Field Research ◽  
Analytical Tool ◽  
Production Costs ◽  
Raw Material ◽  
Labor Costs ◽  
Material Costs ◽  
Library Research ◽  
The Difference ◽  
The Cost

This study aims to analyze whether the difference that occurs in the cost of raw materials, direct labor, and factory overhead costs between the standard costs and the actual costs in PLTU LATI is a difference that is favorable or unfavorable. Data collection techniques with field research and library research. The analytical tool used is the analysis of the difference in raw material costs, the difference in direct labor costs and the difference in factory overhead costs. The hypothesis in this study is that the difference allegedly occurs in the cost of raw materials, direct labor costs, and factory overhead costs at PT Indo Pusaka Berau Tanjung Redeb is a favorable difference. The results showed that the difference in the cost of producing MWh electricity at PT Indo Pusaka Berau Tanjung Redeb in 2018, namely the difference in the price of raw material costs Rp. 548,029.80, - is favorable, the difference in quantity of raw materials is Rp. 957,216,602, - is (favorable) , the difference in direct labor costs Rp 2,602,642,084, - is (unfavorable), and the difference in factory overhead costs Rp 8,807,051,422, - is (favorable) This shows that the difference in the overall production cost budget is favorable or profitable. This beneficial difference shows that the company is really able to reduce production costs optimally in 2018.  

scholarly journals Nondestructive Detection of the Gel State of Preserved Eggs Based on Dielectric Impedance

Foods ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 394
Author(s):  
Cheng-Han Li ◽  
Chun-Hung Hsieh ◽  
Cheng-Chu Hung ◽  
Ching-Wei Cheng
Keyword(s):  
Decay Rate ◽  
Mechanical Vibration ◽  
Scientific Basis ◽  
Nondestructive Method ◽  
Inspection System ◽  
Nyquist Diagram ◽  
Detection Technology ◽  
The Difference ◽  
The Individual

After completing the production of preserved eggs, traditionally, the degree of gelling is judged by allowing workers to tap the preserved eggs with their fingers and sense the resulting oscillations. The amount of oscillation is used for the quality classification. This traditional method produces varying results owing to the differences in the sensitivity of the individual workers, who are not objective. In this study, dielectric detection technology was used to classify the preserved eggs nondestructively. The impedance in the frequency range of 2–300 kHz was resolved into resistance and reactance, and was plotted on a Nyquist diagram. Next, the diagram curve was fitted in order to obtain the equivalent circuit, and the difference in the compositions of the equivalent circuits corresponding to gelled and non-gelled preserved eggs was analyzed. A preserved egg can be considered an RLC series circuit, and its decay rate is consistent with the decay rate given by mechanical vibration theory. The Nyquist diagrams for the resistance and reactance of preserved eggs clearly showed that the resistance and reactance of gelled and non-gelled eggs were quite different, and the classification of the eggs was performed using Bayesian network (BN). The results showed that a BN classifier with two variables, i.e., resistance and reactance, can be used to classify preserved eggs as gelled or non-gelled, with an accuracy of 81.0% and a kappa value of 0.62. Thus, a BN classifier based on resistance and reactance demonstrates the ability to classify the quality of preserved egg gel. This research provides a nondestructive method for the inspection of the quality of preserved egg gel, and provides a theoretical basis for the development of an automated preserved egg inspection system that can be used as the scientific basis for the determination of the quality of preserved eggs.

scholarly journals Fundamental Study of Palladium Recycling Using “Dry Aqua Regia” Considering the Recovery from Spent Auto-catalyst

2021 ◽  
Author(s):  
Akihiro Yoshimura ◽  
Shunta Tochigi ◽  
Yasunari Matsuno
Keyword(s):  
Potassium Chloride ◽  
Platinum Group Metals ◽  
Recycling Process ◽  
Fundamental Study ◽  
Aqua Regia ◽  
Sodium Chloride Solutions ◽  
Pure Compounds ◽  
The Difference ◽  
Solid Liquid ◽  
Solid Liquid Separation

AbstractIn this research, a recycling process for palladium using “dry aqua regia,” which consists of iron(III) chloride–potassium chloride, was proposed. Palladium was dissolved in “dry aqua regia,” and the dissolved palladium was recovered by leaching with potassium chloride solution with added ammonium chloride and nitric acid. Palladium was almost completely dissolved in 3 h at 600 K, and the recovery ratio of dissolved palladium was up to 80%. In addition, the dissolution of palladium in coexistence with platinum and the dissolution of platinum-palladium alloy by “dry aqua regia” were also tested. The dissolved palladium and platinum were separated and recovered by solid–liquid separation technique using the difference in solubility of their compounds in potassium chloride and sodium chloride solutions. As a result, pure compounds of each element were recovered. This result suggested the possibility of using “dry aqua regia” for the separation of platinum-group metals. Graphical Abstract

Arc atomic emission determination of noble metals in mineral raw materials and products of their processing

2012 ◽  
Vol 67 (10) ◽  
pp. 823-829 ◽  
Author(s):  
Yu. S. Sukach ◽  
E. N. Savinova ◽  
G. M. Kolesov ◽  
D. A. Tyurin
Keyword(s):  
Noble Metals ◽  
Raw Materials ◽  
Atomic Emission ◽  
Mineral Raw Materials

The Influence Factors of Compressive Strength and Production of Mineral Polymer of Aluminum Rocks in Xiuwen County, Guizhou Province, China

2013 ◽  
Vol 690-693 ◽  
pp. 1086-1090
Author(s):  
Jie Zhang ◽  
Qiong Qiong Li ◽  
Yu Qiang Xiong
Keyword(s):  
Compressive Strength ◽  
Water Glass ◽  
Mineral Water ◽  
Raw Materials ◽  
Influence Factors ◽  
Polymer Materials ◽  
Guizhou Province ◽  
Liquid Ratio ◽  
Alkaline Activator ◽  
Solid Liquid

Aluminous rocks from Xiuwen County, Guizhou are the main raw materials, mixed some kaolin mineral. Water glass and alkaline activators are used to product polymer materials, the main experimental indicators are the compressive strength. Here, the studies on amount of water glass and alkaline activator, solid-liquid ratio, amount of kaolin and effects on compressive strength of Geopolymer have been proceeded respectively. The result shows that: the highest compressive strength of geopolymers is17.94 Mpa, with aluminous rock 40g, solid-liquid ratio 2.2, water glass12g and alkali activator 2.01g, as well as kaolin 18.02g.

Synthesis of Polyurethane Dendrimers and Transfer Properties of Dye

2013 ◽  
Vol 457-458 ◽  
pp. 65-71
Author(s):  
Jing Ru Jia
Keyword(s):  
Methyl Orange ◽  
Phase Transfer ◽  
Raw Materials ◽  
Toluene Diisocyanate ◽  
Polymerization Process ◽  
Process Conditions ◽  
Addition Polymerization ◽  
Different Temperatures ◽  
The Difference ◽  
Transfer Properties

The polyfunctional organic compounds 2- hydroxymethyl -1,4- butanediol (trihydric alcohol) and toluene diisocyanate -2, 4- diisocyanate (TDI) were taken as the raw materials in this study. A polyurethane dendrimer was synthesized by utilizing the difference in the reaction activity of two isocyanate groups of TDI at different temperatures. The polymerization process conditions were studied. The addition polymerization of para-position NCO groups occurred at 50 °C, and that of ortho NCO groups occurred at 90 °C. According to the structure of the dendrimer synthesized, methyl orange was used as the guest molecule. Consequently, the aqueous methyl orange showed a phase transfer. With the increase of dendrimer concentration, the transfer rate of methyl orange increased.

Raman Spectrum Analysis on the Solid–Liquid Boundary Layer of BGO Crystal Growth

2007 ◽  
Vol 24 (7) ◽  
pp. 1898-1900 ◽  
Author(s):  
Zhang Xia ◽  
Yin Shao-Tang ◽  
Wan Song-Ming ◽  
You Jing-Lin ◽  
Chen Hui ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Raman Spectrum ◽  
Crystal Growth ◽  
Spectrum Analysis ◽  
Liquid Boundary ◽  
Solid Liquid ◽  
Liquid Boundary Layer
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