Thermal Stability of Polyvinyl Chloride Insulating Compounds

Author(s):  
R. C. Bartlett
Author(s):  
Farshad Farahbod ◽  
Narges Bagheri ◽  
Fereshteh Madadpour

Today's pipe made of polyvinyl chloride (PVC) is used as basic good in different industries. The thermal stability of the PVC while is filled with ZnO nanoparticles was studied in this paper. This paper show that the stability of the PVC resin mixed with ZnO nanoparticles solution and Sn was better than that of the PVC resin mixed with Sn alone. The UV (ultraviolet)–vis spectra is showed that under certain heat treatment conditions, the PVC samples without ZnO nanoparticles solution embodied relatively high content of the conjugated double bonds with the chain length of about 3–5. However, the content of the conjugated double bond with the chain length of about 6 was greatly increased when the nanoparticles was filled into the PVC resin. This work shows the ZnO nanoparticles could inhibit the thermal degradation process of PVC resin in ionic mechanism.


2020 ◽  
Vol 869 ◽  
pp. 218-223
Author(s):  
Timur A. Borukaev ◽  
Luiza I. Kitieva ◽  
Zakhirat Kh. Sultigova ◽  
Rukhsara M. Martazova

Compounds based on polyvinylchloride plasticate containing a complex stabilizer based on salts of calcium and zinc stearates were obtained. The thermal properties of the obtained compounds are investigated. It was found that the introduction of a complex stabilizer in PVC compound leads to increased thermal stability of the compound. It is shown that the complex stabilizer affects the destructive processes that occur in the polymer matrix at elevated temperatures. It was found that the introduction of a complex stabilizer based on a mixture of calcium and zinc stearates in polyvinyl chloride plastics results in materials with improved processability.


2012 ◽  
Vol 535-537 ◽  
pp. 1167-1170
Author(s):  
Jian Ping Liu ◽  
Xia Song ◽  
Wei Yuan ◽  
Xiao Yan Wang

Here, we synthesized a series of polymeric thermal stabilizers for polyvinyl chloride (PVC) based on maleic anhydride derivatives, including N-phenylmaleimide (NPMI), N-p-chlorophenyl maleimide (NCIPMI), N-p-nitrophenyl maleimide (NNOPMI), dibutyltin maleate (DBTM) and dioctyltin maleate (DOTM). Five specimens were prepared by mixing and rolling through a blending machine and a double-roller mixer, respectively. These samples were first subjected to thermal degradation in a 180°C hot oven, and fractions were collected every 10 min, followed by spotting on a slip of test paper. From the degree of color change in the test paper, the influences of these compounds on the thermal stability of PVC were estimated and such mechanisms were also discussed.


1983 ◽  
Vol 62 (2-3) ◽  
pp. 355-359 ◽  
Author(s):  
Ibtisam M. Kamal ◽  
Georgius A. Adam ◽  
Husen K.Al Getta

Author(s):  
Shiro Fujishiro ◽  
Harold L. Gegel

Ordered-alpha titanium alloys having a DO19 type structure have good potential for high temperature (600°C) applications, due to the thermal stability of the ordered phase and the inherent resistance to recrystallization of these alloys. Five different Ti-Al-Ga alloys consisting of equal atomic percents of aluminum and gallium solute additions up to the stoichiometric composition, Ti3(Al, Ga), were used to study the growth kinetics of the ordered phase and the nature of its interface.The alloys were homogenized in the beta region in a vacuum of about 5×10-7 torr, furnace cooled; reheated in air to 50°C below the alpha transus for hot working. The alloys were subsequently acid cleaned, annealed in vacuo, and cold rolled to about. 050 inch prior to additional homogenization


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