Cation Exchange Capacity of Loess and its Relation to Engineering Properties

2009 ◽  
pp. 10-10-19
Author(s):  
Donald T. Davidson ◽  
John B. Sheeler
Clay Minerals ◽  
2006 ◽  
Vol 41 (4) ◽  
pp. 827-837 ◽  
Author(s):  
Y. Yukselen ◽  
A. Kaya

AbstractIn many areas of geotechnical engineering it is necessary to have an estimate of the cation exchange capacity (CEC) of a soil in order to allow preliminary design estimates. Standard methods of CEC determination are time-consuming and involve several steps (e.g. displacement of the saturating cation requires several washings with alcohol). Therefore, a rapid method of CEC estimation would be very useful. During preliminary site investigations, the soil engineering parameters can be estimated from the considerable number of correlations available in the literature. In this study, relationships between CEC and various other soil engineering properties have been investigated, resulting in a quick method for estimating CEC.Simple correlations were developed between CEC and specific surface area (SSA), soil organic matter (OM), clay fraction (CF), activity (A), Atterberg limits (liquid (LL), plastic (PL), and shrinkage (SL)), and modified free swell index (MFSI) of the soils. Strong correlations are observed between the CEC values and those for ethylene glycol monoethyl ether (EGME) uptake and methylene blue (MB) titration. However, no significant correlation was found between CEC and N2_SSA. No unique relationship was seen between CEC and CF (r2 <0.5). No relationship was observed between CEC and OM in this study. The best correlation coefficient between the CEC and Atterberg limits exists between CEC and LL (r2 = 0.61). No significant relationship was seen between CEC and PL or SL. The correlation coefficient between CEC and MFSI was 0.65. Multiple linear regression analyses were developed to investigate the contributions of different soil parameters to CEC. These analyses show that EGME_SSA, in combination with LL, accounted for 91% of the variation in CEC. Correlations between CEC and EGME_SSA, MB_SSA and LL appear to be sufficiently good to enable an indication of CEC to be estimated from these parameters.


2018 ◽  
Vol 4 (1) ◽  
Author(s):  
Mardi Wibowo

Since year 1977 until 2005, PT. ANTAM has been exploited nickel ore resources at Gebe Island – Center ofHalmahera District – North Maluku Province. Mining activity, beside give economically advantages also causedegradation of environment quality espicially land quality. Therefore, it need evaluation activity for change ofland quality at Gebe Island after mining activity.From chemical rehabilitation aspect, post mining land and rehabilitation land indacate very lack and lackfertility (base saturated 45,87 – 99,6%; cation exchange capacity 9,43 – 12,43%; Organic Carbon 1,12 –2,31%). From availability of nutrirnt element aspect, post mining land and rehabilitation land indicate verylack and lack fertility (nitrogen 0,1 – 1,19%). Base on that data, it can be concluded that land reclamationactivity not yet achieve standart condition of chemical land.Key words : land quality, post mining lan


Author(s):  
Geraldo R. Zuba Junio ◽  
Regynaldo A. Sampaio ◽  
Altina L. Nascimento ◽  
Luiz A. Fernandes ◽  
Natália N. de Lima ◽  
...  

ABSTRACTThis study aimed to evaluate the chemical attributes of an Inceptisol cultivated with castor bean (Ricinus communis L.), variety ‘BRS Energia’, fertilized with sewage sludge compost and calcium (Ca) and magnesium (Mg) silicate. The experiment was conducted at the ICA/UFMG, in a randomized block design, using a 2 x 4 factorial scheme with three replicates, and the treatments consisted of two doses of Ca-Mg silicate (0 and 1 t ha-1) and four doses of sewage sludge compost (0, 23.81, 47.62 and 71.43 t ha-1, on dry basis). Soil organic matter (OM), pH, sum of bases (SB), effective cation exchange capacity (CEC(t)), total cation exchange capacity (CEC(T)), base saturation (V%) and potential acidity (H + Al) were evaluated. There were no significant interactions between doses of sewage sludge compost and doses of Ca-Mg silicate on soil attributes, and no effect of silicate fertilization on these attributes. However, fertilization with sewage sludge compost promoted reduction in pH and increase in H + Al, OM and CEC. The dose of 71.43 t ha-1 of sewage sludge compost promoted the best soil chemical conditions.


Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2617
Author(s):  
Alicja Szatanik-Kloc ◽  
Justyna Szerement ◽  
Agnieszka Adamczuk ◽  
Grzegorz Józefaciuk

Thousands of tons of zeolitic materials are used yearly as soil conditioners and components of slow-release fertilizers. A positive influence of application of zeolites on plant growth has been frequently observed. Because zeolites have extremely large cation exchange capacity, surface area, porosity and water holding capacity, a paradigm has aroused that increasing plant growth is caused by a long-lasting improvement of soil physicochemical properties by zeolites. In the first year of our field experiment performed on a poor soil with zeolite rates from 1 to 8 t/ha and N fertilization, an increase in spring wheat yield was observed. Any effect on soil cation exchange capacity (CEC), surface area (S), pH-dependent surface charge (Qv), mesoporosity, water holding capacity and plant available water (PAW) was noted. This positive effect of zeolite on plants could be due to extra nutrients supplied by the mineral (primarily potassium—1 ton of the studied zeolite contained around 15 kg of exchangeable potassium). In the second year of the experiment (NPK treatment on previously zeolitized soil), the zeolite presence did not impact plant yield. No long-term effect of the zeolite on plants was observed in the third year after soil zeolitization, when, as in the first year, only N fertilization was applied. That there were no significant changes in the above-mentioned physicochemical properties of the field soil after the addition of zeolite was most likely due to high dilution of the mineral in the soil (8 t/ha zeolite is only ~0.35% of the soil mass in the root zone). To determine how much zeolite is needed to improve soil physicochemical properties, much higher zeolite rates than those applied in the field were studied in the laboratory. The latter studies showed that CEC and S increased proportionally to the zeolite percentage in the soil. The Qv of the zeolite was lower than that of the soil, so a decrease in soil variable charge was observed due to zeolite addition. Surprisingly, a slight increase in PAW, even at the largest zeolite dose (from 9.5% for the control soil to 13% for a mixture of 40 g zeolite and 100 g soil), was observed. It resulted from small alterations of the soil macrostructure: although the input of small zeolite pores was seen in pore size distributions, the larger pores responsible for the storage of PAW were almost not affected by the zeolite addition.


Soil Research ◽  
1981 ◽  
Vol 19 (1) ◽  
pp. 93 ◽  
Author(s):  
GP Gillman

The cation exchange capacity of six surface soils from north Queensland and Hawaii has been measured over a range of pH values (4-6) and ionic strength values (0.003-0.05). The results show that for variable charge soils, modest changes in electrolyte ionic strength are as important in their effect on caton exchange capacity as are changes in pH values.


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