Role of Organic Acids in Cleaning Stainless Steels

2009 ◽  
pp. 43-43-11
Author(s):  
W. J. Blume
Keyword(s):  
Organic Acids ◽  
Stainless Steels

Strain-induced martensite effects on transgranular carbide precipitation in type 304 stainless steels

1991 ◽  
Vol 49 ◽  
pp. 604-605
Author(s):  
A.H. Advani ◽  
L.E. Murr ◽  
D. Matlock
Keyword(s):  
Heat Treatment ◽  
Grain Boundary ◽  
Stress Corrosion Cracking ◽  
Stainless Steels ◽  
Deformation Twin ◽  
Austenitic Stainless Steels ◽  
Carbide Precipitation ◽  
Strain Induced Martensite ◽  
Type 304

Thermomechanically induced strain is a key variable producing accelerated carbide precipitation, sensitization and stress corrosion cracking in austenitic stainless steels (SS). Recent work has indicated that higher levels of strain (above 20%) also produce transgranular (TG) carbide precipitation and corrosion simultaneous with the grain boundary phenomenon in 316 SS. Transgranular precipitates were noted to form primarily on deformation twin-fault planes and their intersections in 316 SS.Briant has indicated that TG precipitation in 316 SS is significantly different from 304 SS due to the formation of strain-induced martensite on 304 SS, though an understanding of the role of martensite on the process has not been developed. This study is concerned with evaluating the effects of strain and strain-induced martensite on TG carbide precipitation in 304 SS. The study was performed on samples of a 0.051%C-304 SS deformed to 33% followed by heat treatment at 670°C for 1 h.

Carbide precipitation and chromium depletion on coherent twin boundaries in deformed 304 stainless steels

1992 ◽  
Vol 50 (2) ◽  
pp. 1216-1217
Author(s):  
A.H. Advani ◽  
L.E. Murr ◽  
D.J. Matlock ◽  
W.W. Fisher ◽  
P.M. Tarin ◽  
...  
Keyword(s):  
Grain Boundaries ◽  
Stainless Steels ◽  
Interfacial Free Energy ◽  
Carbide Precipitation ◽  
Twin Boundaries ◽  
Invariant Structure ◽  
Heat Treated ◽  
Constant Structure ◽  
Cr Depletion

Coherent annealing-twin boundaries are constant structure and energy interfaces with an average interfacial free energy of ∼19mJ/m2 versus ∼210 and ∼835mJ/m2 for incoherent twins and “regular” grain boundaries respectively in 304 stainless steels (SS). Due to their low energy, coherent twins form carbides about a factor of 100 slower than grain boundaries, and limited work has also shown differences in Cr-depletion (sensitization) between twin versus grain boundaries. Plastic deformation, may, however, alter the kinetics and thermodynamics of twin-sensitization which is not well understood. The objective of this work was to understand the mechanisms of carbide precipitation and Cr-depletion on coherent twin boundaries in deformed SS. The research is directed toward using this invariant structure and energy interface to understand and model the role of interfacial characteristics on deformation-induced sensitization in SS. Carbides and Cr-depletion were examined on a 20%-strain, 0.051%C-304SS, heat treated to 625°C-4.5h, as described elsewhere.

The corrosion behaviour of AISI 304L AND 316L stainless steels prepared by powder metallurgy in the presence of organic acids

1997 ◽  
Vol 39 (3) ◽  
pp. 453-463 ◽  
Author(s):  
E. Otero ◽  
A. Pardo ◽  
M.V. Utrilla ◽  
F.J. Pérez ◽  
C. Merino
Keyword(s):  
Powder Metallurgy ◽  
Organic Acids ◽  
Stainless Steels ◽  
Corrosion Behaviour ◽  
Aisi 304L

After-Cooking Discoloration of Potatoes Role of the Organic Acids

1964 ◽  
Vol 29 (5) ◽  
pp. 555-564 ◽  
Author(s):  
E. G. HEISLER ◽  
JAMES SICILIANO ◽  
C. F. WOODWARD ◽  
W. L. PORTER
Keyword(s):  
Organic Acids

scholarly journals Role of Organic Acids on Phosphorus Fractions in Silty Clay Loam Soil

2018 ◽  
Vol 8 (2) ◽  
pp. 12-21
Author(s):  
Abdulmahdi S.ALansari ◽  
Muhammad M.Yassin ◽  
Mahdi W.Seheib
Keyword(s):  
Humic Acid ◽  
Organic Acids ◽  
Incubation Period ◽  
Total Phosphorus ◽  
Phosphate Fertilizer ◽  
Silty Clay ◽  
Clay Loam ◽  
Silty Clay Loam ◽  
Fertilized Soil

This study was conducted to evaluation the role of the organic acids in the phosphorus fractions in silty clay loam texture. The laboratoryexperiment was conducted by adding the organic acids (Humic acid ,Citric acid ,Oxalic acid , Malic acid ,Acetic acid and Lactic acid )to the fertilized soil with conc. super phosphate fertilizer with 100 kg h-1 level with concentrations (0,15,30,45 and60)mg L-1,except Humic acid (500,1000,1500 and 2000) mg L-1.The soil was incubated at 30 C for 14,28,42,56 and 70 days period and the keep of field capacity about of incubation period during the daily weight.Amount of available ,mineral ,organic and total phosphorus after each incubated period were measured. The results showed that theaddition of organic acids of Humic acid ,Citric acid ,Oxalic acid and Malic acid were caused to increaseamount of available ,mineral ,organic and constant of total phosphorus in fertilized soil with conc. super phosphate fertilizer and increased its amount with increasing of organic acid concentration and better of Humic acid 2000mg L-1 significanton all the treatments .The results of the study that theaddition of organic acids were caused to increase amount of available and mineral phosphorus with increasing of incubation period and constant amount of total phosphorus and decreasing of organic phosphorus amount and available for only soil and only fertilizer treatment during increasing of incubation period .The organic acids can be arranged according to its ability toincrease the availabilityof the phosphorus as follow :

scholarly journals Organic compounds in root exudates of Miscanthus × Giganteus greef et deu and limitation of microorganisms in its rhizosphere by nutrients

2010 ◽  
Vol 58 (5) ◽  
pp. 203-208 ◽  
Author(s):  
Hana Kaňová ◽  
Joffrey Carre ◽  
Valerie Vranová ◽  
Klement Rejšek ◽  
Pavel Formánek
Keyword(s):  
Organic Acids ◽  
Organic Compounds ◽  
Respiration Rate ◽  
Root Exudates ◽  
Plant Nutrients ◽  
Rhizospheric Soil ◽  
Polluted Soils ◽  
Rhizosphere Microorganisms ◽  
Miscanthus Giganteus

This study was conducted to determine the composition of sugars and organic acids in root exudates of Miscanthus × Giganteus and to find out if microorganisms of the rhizospheric soil are limited by mi­ne­ral nutrients. The following sugars and organic acids were determined in root exudates of this plant: glucose, saccharose, and acids such as succinic, propionic, citric, tartaric, malic, oxalic, ascorbic, acetic and fumaric. Respiration of soil from rhizosphere of Miscanthus × Giganteus was found to be limited by N, K and Ca. Respiration rate after application of mineral compounds increased in following orther: nitrate > calcium > potassium > ammonium, giving approx. 165, 99, 52 and 31 % increase compared to control. Further research is necessary to determine the role of plant nutrients from the point of their limitations for rhizosphere microorganisms, to broader very rare knowledges in this topic, especially for polluted soils to stimulate efficiency of phytoremediations.

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