Influence of Eroding Solution Composition on Dispersive Behavior of a Compacted Clay Shale

Author(s):  
CT Statton ◽  
JK Mitchell
1982 ◽  
Vol 47 (7) ◽  
pp. 1780-1786 ◽  
Author(s):  
Rostislav Kudláček ◽  
Jan Lokoč

The effect of gamma pre-irradiation of the mixed nickel-magnesium oxide catalyst on the kinetics of hydrogenation of maleic acid in the liquid phase has been studied. The changes of the hydrogenation rate are compared with the changes of the adsorbed amount of the acid and with the changes of the solution composition, activation energy, and absorbed dose of the ionizing radiation. From this comparison and from the interpretation of the experimental data it can be deduced that two types of centers can be distinguished on the surface of the catalyst under study, namely the sorption centres for the acid and hydrogen and the reaction centres.


2020 ◽  
Vol 224 (3) ◽  
pp. 1523-1539
Author(s):  
Lisa Winhausen ◽  
Alexandra Amann-Hildenbrand ◽  
Reinhard Fink ◽  
Mohammadreza Jalali ◽  
Kavan Khaledi ◽  
...  

SUMMARY A comprehensive characterization of clay shale behavior requires quantifying both geomechanical and hydromechanical characteristics. This paper presents a comparative laboratory study of different methods to determine the water permeability of saturated Opalinus Clay: (i) pore pressure oscillation, (ii) pressure pulse decay and (iii) pore pressure equilibration. Based on a comprehensive data set obtained on one sample under well-defined temperature and isostatic effective stress conditions, we discuss the sensitivity of permeability and storativity on the experimental boundary conditions (oscillation frequency, pore pressure amplitudes and effective stress). The results show that permeability coefficients obtained by all three methods differ less than 15 per cent at a constant effective stress of 24 MPa (kmean = 6.6E-21 to 7.5E-21 m2). The pore pressure transmission technique tends towards lower permeability coefficients, whereas the pulse decay and pressure oscillation techniques result in slightly higher values. The discrepancies are considered minor and experimental times of the techniques are similar in the range of 1–2 d for this sample. We found that permeability coefficients determined by the pore pressure oscillation technique increase with higher frequencies, that is oscillation periods shorter than 2 hr. No dependence is found for the applied pressure amplitudes (5, 10 and 25 per cent of the mean pore pressure). By means of experimental handling and data density, the pore pressure oscillation technique appears to be the most efficient. Data can be recorded continuously over a user-defined period of time and yield information on both, permeability and storativity. Furthermore, effective stress conditions can be held constant during the test and pressure equilibration prior to testing is not necessary. Electron microscopic imaging of ion-beam polished surfaces before and after testing suggests that testing at effective stresses higher than in situ did not lead to pore significant collapse or other irreversible damage in the samples. The study also shows that unloading during the experiment did not result in a permeability increase, which is associated to the persistent closure of microcracks at effective stresses between 24 and 6 MPa.


2021 ◽  
Vol 13 (13) ◽  
pp. 7301
Author(s):  
Marcin K. Widomski ◽  
Anna Musz-Pomorska ◽  
Wojciech Franus

This paper presents research considering hydraulic as well as swelling and shrinkage characteristics of potential recycled fine particle materials for compacted clay liner for sustainable landfills. Five locally available clay soils mixed with 10% (by mass) of NaP1 recycled zeolite were tested. The performed analysis was based on determined plasticity, cation exchange capacity, coefficient of saturated hydraulic conductivity after compaction, several shrinkage and swelling characteristics as well as, finally, saturated hydraulic conductivity after three cycles of drying and rewetting of tested specimens and the reference samples. The obtained results showed that addition of zeolite to clay soils allowed reduction in their saturated hydraulic conductivity to meet the required threshold (≤1 × 10−9 m/s) of sealing capabilities for compacted clay liner. On the other hand, an increase in plasticity, swelling, and in several cases in shrinkage, of the clay–zeolite mixture was observed. Finally, none of the tested mixtures was able to sustain its sealing capabilities after three cycles of drying and rewetting. Thus, the studied clayey soils mixed with sustainable recycled zeolite were assessed as promising materials for compacted liner construction. However, the liner should be operated carefully to avoid extensive dissication and cracking.


Heliyon ◽  
2021 ◽  
Vol 7 (4) ◽  
pp. e06917
Author(s):  
Chairat Teerawattanasuk ◽  
Panich Voottipruex ◽  
Suksun Horpibulsuk

2018 ◽  
Vol 7 (4.36) ◽  
pp. 424 ◽  
Author(s):  
Maxwel Joseph Henri Nainggolan ◽  
Wiwik Rahayu ◽  
Puspita Lisdiyanti

In recent years, utilization of biotechnology in geotechnical field has rapidly grown. One of the biotechnologies being utilized is urease enzyme, a stabilization material by bio-cementation method studied in this research.  Urease enzyme is manually mixed with additional 10% of clay soil to clay shale. The objective of mixing it is to increase the bearing capacity of the clay shale. Consolidated undrained triaxial test was performed for testing the soil strength performance for samples that had undergone curing for 2, 4, and 6 weeks. The results indicated that the sample stiffens, proved by the increase of shear strength from consolidated undrained triaxial test. The shear strength value produced by the variation of the urease enzyme mixture + 10% the clay is higher than that of without the original clay shale.  


2016 ◽  
Vol 41 (1) ◽  
pp. 54-64 ◽  
Author(s):  
Anton Trník ◽  
Lenka Scheinherrová ◽  
Tereza Kulovaná ◽  
Pavel Reiterman ◽  
Eva Vejmelková ◽  
...  

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