Barrier Coatings for the Protection of Steel and Aluminum Alloys in the Marine Atmosphere

2008 ◽  
pp. 206-206-14
Author(s):  
BA Shaw ◽  
DM Aylor
2013 ◽  
Vol 49 (7) ◽  
pp. 891-893
Author(s):  
S. A. Kharimova ◽  
V. P. Zhilikov ◽  
A. A. Mikhailov ◽  
D. V. Chesnokov ◽  
T. N. Igonin ◽  
...  

Author(s):  
M. Raghavan ◽  
J. Y. Koo ◽  
J. W. Steeds ◽  
B. K. Park

X-ray microanalysis and Convergent Beam Electron Diffraction (CBD) studies were conducted to characterize the second phase particles in two commercial aluminum alloys -- 7075 and 7475. The second phase particles studied were large (approximately 2-5μm) constituent phases and relatively fine ( ∼ 0.05-1μn) dispersoid particles, Figures 1A and B. Based on the crystal structure and chemical composition analyses, the constituent phases found in these alloys were identified to be Al7Cu2Fe, (Al,Cu)6(Fe,Cu), α-Al12Fe3Si, Mg2Si, amorphous silicon oxide and the modified 6Fe compounds, in decreasing order of abundance. The results of quantitative X-ray microanalysis of all the constituent phases are listed in Table I. The data show that, in almost all the phases, partial substitution of alloying elements occurred resulting in small deviations from the published stoichiometric compositions of the binary and ternary compounds.


Author(s):  
Ozer Unal

Interest in ceramics as thermal barrier coatings for hot components of turbine engines has increased rapidly over the last decade. The primary reason for this is the significant reduction in heat load and increased chemical inertness against corrosive species with the ceramic coating materials. Among other candidates, partially-stabilized zirconia is the focus of attention mainly because ot its low thermal conductivity and high thermal expansion coefficient.The coatings were made by Garrett Turbine Engine Company. Ni-base super-alloy was used as the substrate and later a bond-coating with high Al activity was formed over it. The ceramic coatings, with a thickness of about 50 μm, were formed by EB-PVD in a high-vacuum chamber by heating the target material (ZrO2-20 w/0 Y2O3) above its evaporation temperaturef >3500 °C) with a high-energy beam and condensing the resulting vapor onto a rotating heated substrate. A heat treatment in an oxidizing environment was performed later on to form a protective oxide layer to improve the adhesion between the ceramic coating and substrate. Bulk samples were studied by utilizing a Scintag diffractometer and a JEOL JXA-840 SEM; examinations of cross-sectional thin-films of the interface region were performed in a Philips CM 30 TEM operating at 300 kV and for chemical analysis a KEVEX X-ray spectrometer (EDS) was used.


TAPPI Journal ◽  
2018 ◽  
Vol 17 (01) ◽  
pp. 31-37
Author(s):  
Bryan McCulloch ◽  
John Roper ◽  
Kaitlin Rosen

Barrier coatings are used in applications including food packaging, dry goods, and consumer products to prevent transport of different compounds either through or into paper and paperboard substrates. These coatings are useful in packaging to contain active ingredients, such as fragrances, or to protect contents from detrimental substances, such as oxygen, water, grease, or other chemicals of concern. They also are used to prevent visual changes or mechanical degradation that might occur if the paper becomes saturated. The performance and underlying mechanism depends on the barrier coating type and, in particular, on whether the barrier coating is designed to prevent diffusive or capillary transport. Estimates on the basis of fundamental transport phenomena and data from a broad screening of different barrier materials can be used to understand the limits of various approaches to construct barrier coatings. These estimates also can be used to create basic design rules for general classes of barrier coatings.


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