The Use of Anodic Polarization to Determine the Effectiveness of Calcium Nitrite as an Anodic Inhibitor

2008 ◽  
pp. 78-78-14
Author(s):  
NS Berke
Keyword(s):  
Anodic Polarization ◽  
Calcium Nitrite

scholarly journals An Electrochemical Study to Evaluate the Effect of Calcium Nitrite Inhibitor to Mitigate the Corrosion of Reinforcement in Sodium Chloride Contaminated Ca(OH)2Solution

2017 ◽  
Vol 2017 ◽  
pp. 1-14 ◽  
Author(s):  
Hwa-Sung Ryu ◽  
Jitendra Kumar Singh ◽  
Han-Seung Lee ◽  
Won-Jun Park
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Sodium Chloride ◽  
Anodic Polarization ◽  
Open Circuit Potential ◽  
Electrochemical Impedance ◽  
Open Circuit ◽  
Nacl Solution ◽  
Steel Rebar ◽  
Calcium Nitrite ◽  
Corrosion Of Steel

The effect of calcium nitrite (Ca(NO2)2) was assessed by electrochemical means such as open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), and potentiodynamic studies in saturated Ca(OH)2solution contaminated with 0.99 and 7.91 g/L NaCl. The preliminary results of OCP showed that the potential is shifted towards positive (noble) side as content of inhibitor increased. The EIS results indicate that Ca(NO2)2works effectively in reduction and initiation of corrosion of steel rebar in NaCl contaminated Ca(OH)2solution. Potentiodynamic studies revealed the pitting tendency of steel rebar exposed in 0.99 g/L NaCl at [Cl−/NO2-] = 1.2 attributed to low conductivity of passive film which causes interference for Cl−ions attack during anodic polarization. The 85.75% efficiency is found in 0.99 g/L at [Cl−/NO2-] = 1.2. The Ca(NO2)2inhibitor transformed the unstable iron oxides/hydroxides into stable and protective oxides/hydroxides due to its strong oxidizing nature. Therefore, this inhibitor is sufficiently and significantly reducing the corrosion of steel rebar at even its low concentration with 0.99 and 7.91 g/L NaCl solution.

Sem Studies of Co-Cr-Mo Surgical Implant Alloy Corrosion Behavior

1982 ◽  
Vol 40 ◽  
pp. 520-521
Author(s):  
Ann Chidester Van Orden ◽  
John L. Chidester ◽  
Anna C. Fraker ◽  
Pei Sung
Keyword(s):  
Electron Microscopy ◽  
Corrosion Behavior ◽  
Anodic Polarization ◽  
Saline Solution ◽  
Saturated Calomel Electrode ◽  
Physiological Saline ◽  
X Ray ◽  
Physiological Saline Solution ◽  
Scanning Electron

The influence of small variations in the composition on the corrosion behavior of Co-Cr-Mo alloys has been studied using scanning electron microscopy (SEM), energy dispersive x-ray analysis (EDX), and electrochemical measurements. SEM and EDX data were correlated with data from in vitro corrosion measurements involving repassivation and also potentiostatic anodic polarization measurements. Specimens studied included the four alloys shown in Table 1. Corrosion tests were conducted in Hanks' physiological saline solution which has a pH of 7.4 and was held at a temperature of 37°C. Specimens were mechanically polished to a surface finish with 0.05 µm A1203, then exposed to the solution and anodically polarized at a rate of 0.006 v/min. All voltages were measured vs. the saturated calomel electrode (s.c.e.).. Specimens had breakdown potentials near 0.47V vs. s.c.e.

Corrosion. Anodic Polarization Behavior of Cr Carbide/Ni-Cr Composite Alloy.

1995 ◽  
Vol 44 (506) ◽  
pp. 1326-1331 ◽  
Author(s):  
Yasuyuki TAKATANI ◽  
Tomoki TOMITA ◽  
Kazumi TANI ◽  
Mitsuharu INABA ◽  
Yoshio HARADA
Keyword(s):  
Anodic Polarization ◽  
Composite Alloy ◽  
Polarization Behavior

Effect of various cations on the initial rate of formation of peroxodisulphates

1980 ◽  
Vol 45 (8) ◽  
pp. 2272-2282 ◽  
Author(s):  
Jan Balej ◽  
Martin Kadeřávek
Keyword(s):  
Sulphuric Acid ◽  
Oxygen Evolution ◽  
Anodic Polarization ◽  
Initial Rate ◽  
Degree Of Conversion ◽  
Polarization Curves ◽  
Mixed Solutions ◽  
Low Degree ◽  
Partial Polarization

Preparation of peroxodisulphates by electrolysis of mixed solutions of sulphuric acid and various sulphates was studied at low degree of conversion; the partial polarization curves of peroxodisulphate formation and of oxygen evolution obtained from the overall anodic polarization curves and current yields of the principal anodic processes were examined. The mechanism of the effect of various cations on the rate of anodic formation of peroxodisulfates is discussed.

Synergistic effect on concrete corrosion control in sewer environment achieved by applying surface washing on calcium nitrite admixed concrete

2021 ◽  
Vol 302 ◽  
pp. 124184
Author(s):  
Xuan Li ◽  
Jagadeeshkumar Kulandaivelu ◽  
Liza O'Moore ◽  
Simeon Wilkie ◽  
Lucija Hanzic ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Corrosion Control ◽  
Concrete Corrosion ◽  
Calcium Nitrite

scholarly journals Assessment of Galvanostatic Anodic Polarization to Accelerate the Corrosion of the Bioresorbable Magnesium Alloy WE43

2021 ◽  
Vol 11 (5) ◽  
pp. 2128
Author(s):  
Nils Wegner ◽  
Frank Walther
Keyword(s):  
Magnesium Alloy ◽  
Corrosion Rate ◽  
Dissolution Rate ◽  
Anodic Polarization ◽  
Technical Application ◽  
Efficient Manner ◽  
Corrosion Morphology ◽  
Application Range ◽  
Alloy We43

In the field of surgery, bioresorbable magnesium is considered a promising candidate. Its low corrosion resistance, which is disadvantageous for technical application, is advantageous for surgery since the implant fully degrades in the presence of the water-based body fluids, and after a defined time the regenerating bone takes over its function again. Therefore, knowledge of the corrosion behavior over several months is essential. For this reason, an in vitro short-time testing method is developed to accelerate the corrosion progress by galvanostatic anodic polarization without influencing the macroscopic corrosion morphology. The initial corrosion rate of the magnesium alloy WE43 is calculated by detection of the hydrogen volume produced in an immersion test. In a corresponding experimental setup, a galvanostatic anodic polarization is applied with a three-electrode system. The application range for the polarization is determined based on the corrosion current density from potentiodynamic polarization. To correlate the initial corrosion rate, and accelerated dissolution rate, the corrosion morphologies of both test strategies are characterized by microscopy images, as well as energy dispersive X-ray spectroscopy and Fourier-transform infrared spectroscopy. The results demonstrate that the dissolution rate can be increased in the order of decades with the limitation of a changed corrosion morphology with increasing polarization. With this approach, it is possible to characterize and exclude new unsuitable magnesium alloys in a time-efficient manner before they are used in subsequent preclinical studies.

Effects of Nano-CaCO3 on the Compressive Strength and Microstructure of High Strength Concrete in Different Curing Temperature

2011 ◽  
Vol 121-126 ◽  
pp. 126-131 ◽  
Author(s):  
Qing Lei Xu ◽  
Tao Meng ◽  
Miao Zhou Huang
Keyword(s):  
Compressive Strength ◽  
Low Temperature ◽  
High Strength Concrete ◽  
High Strength ◽  
Curing Temperature ◽  
Test Results ◽  
Strength Concrete ◽  
Calcium Nitrite ◽  
Orientation Index ◽  
Early Strength

In this paper, effects of nano-CaCO3 on compressive strength and Microstructure of high strength concrete in standard curing temperature(21±1°C) and low curing temperature(6.5±1°C) was studied. In order to improve the early strength of the concrete in low temperature, the early strength agent calcium nitrite was added into. Test results indicated that 0.5% dosage of nano-CaCO3 could inhibit the effect of calcium nitrite as early strength agent, but 1% and 2% dosage of nano-CaCO3 could improve the strength of the concrete by 13% and 18% in standard curing temperature and by 17% and 14% in low curing temperature at the age of 3days. According to the XRD spectrum, with the dosage up to 1% to 2%, nano-CaCO3 can change the orientation index significantly, leading to the improvement of strength of concrete both in standard curing temperature and low curing temperature.

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