Problems with Current Methodology in Using the Arrhenius Equation to Predict the Long-Term Behavior of Polymeric Materials in Geotechnical Environments

2009 ◽  
pp. 236-236-12
Author(s):  
DG Bright
Keyword(s):  
Arrhenius Equation ◽  
Polymeric Materials ◽  
Long Term Behavior

scholarly journals Can Accelerated Aging Procedures Predict the Long Term Behavior of Polymers Exposed to Different Environments?

Polymers ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2688
Author(s):  
Mariaenrica Frigione ◽  
Alvaro Rodríguez-Prieto
Keyword(s):  
Environmental Conditions ◽  
Accelerated Aging ◽  
Environmental Parameters ◽  
Polymeric Materials ◽  
Vapor Condensation ◽  
Natural Exposure ◽  
Long Term Performance ◽  
Term Performance ◽  
Long Term Behavior

During their useful life, polymers are subject to degradation processes due to exposure to specific environmental conditions over long times. These processes generally lead to changes, almost always irreversible, of properties and performances of polymers, changes which would be useful to be able to predict in advance. To meet this need, numerous investigations have been focused on the possibility to predict the long-term performance of polymers, if exposed to specific environments, by the so called “accelerated aging” tests. In such procedures, the long-term behavior of polymeric materials is typically predicted by subjecting them to cycles of radiations, temperatures, vapor condensation, and other external agents, at levels well above those found in true conditions in order to accelerate the degradation of polymers: this can produce effects that substantially deviate from those observable under natural exposure. Even following the standard codes, different environmental parameters are often used in the diverse studies, making it difficult to compare different investigations. The correlation of results from accelerated procedures with data collected after natural exposure is still a debated matter. Furthermore, since the environmental conditions are a function of the season and the geographical position, and are also characteristic of the type of exposure area, the environmental parameters to be used in accelerated aging tests should also consider these variables. These and other issues concerning accelerated aging tests applied to polymers are analyzed in the present work. However, bearing in mind the limitations of these practices, they can find useful applications for rating the durability of polymeric materials.

Morphology and Long Term Behavior of Polymer Cement Concrete

1989 ◽  
Vol 179 ◽  
Author(s):  
K. P. Grosskurth
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Polymeric Materials ◽  
Heterogeneous Material ◽  
Cement Concrete ◽  
Temperature Dependent ◽  
Dependent Behavior ◽  
Long Term Behavior

AbstractPolymer-modified cement concrete represents a heterogeneous material whose properties are influenced more by the properties of the polymers than by the properties of the cement component. Typical of polymeric materials are their temperature dependent behavior. This temperature dependence can be related to the glass transition temperature of the polymer. In cases where the temperature is higher than the glass transition temperature, strength decreases while deformability simultaneously increases. Polymeric films are formed in the dispersed polymer systems as a result of reactions occurring at the glass transition temperature. A styrene/acrylic modified concrete was studied at different polymer loadings. The tensile and compressive strengths of this system were studied as a function of temperature. Increasing deformability temperatures principally at higher polymer loadings near the glass transition temperature and decreasing strength occurred.

Effects of acute seizures on cell proliferation, synaptic plasticity and long-term behavior in adult zebrafish

2021 ◽  
Vol 1756 ◽  
pp. 147334
Author(s):  
Charles Budaszewski Pinto ◽  
Natividade de Sá Couto-Pereira ◽  
Felipe Kawa Odorcyk ◽  
Kamila Cagliari Zenki ◽  
Carla Dalmaz ◽  
...  
Keyword(s):  
Cell Proliferation ◽  
Synaptic Plasticity ◽  
Adult Zebrafish ◽  
Acute Seizures ◽  
Long Term Behavior

scholarly journals Study of the Ultraviolet Effect and Thermal Analysis on Polypropylene Nonwoven Geotextile

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1080
Author(s):  
Clever Aparecido Valentin ◽  
Marcelo Kobelnik ◽  
Yara Barbosa Franco ◽  
Fernando Luiz Lavoie ◽  
Jefferson Lins da Silva ◽  
...  
Keyword(s):  
Uv Light ◽  
Polymeric Materials ◽  
Tensile Tests ◽  
Thermomechanical Analysis ◽  
Material Stiffness ◽  
Before And After ◽  
Electron Microscopy Analysis ◽  
Physical Tests ◽  
Nonwoven Geotextile

The use of polymeric materials such as geosynthetics in infrastructure works has been increasing over the last decades, as they bring down costs and provide long-term benefits. However, the aging of polymers raises the question of its long-term durability and for this reason researchers have been studying a sort of techniques to search for the required renewal time. This paper examined a commercial polypropylene (PP) nonwoven geotextile before and after 500 h and 1000 h exposure to ultraviolet (UV) light by performing laboratory accelerated ultraviolet-aging tests. The state of the polymeric material after UV exposure was studied through a wide set of tests, including mechanical and physical tests and thermoanalytical tests and scanning electron microscopy analysis. The calorimetric evaluations (DSC) showed distinct behaviors in sample melting points, attributed to the UV radiation effect on the aged samples. Furthermore, after exposure, the samples presented low thermal stability in the thermomechanical analysis (TMA), with a continuing decrease in their thicknesses. The tensile tests showed an increase in material stiffness after exposition. This study demonstrates that UV aging has effects on the properties of the polypropylene polymer.

Using Generalized Cell Mapping to Approximate Invariant Measures on Compact Manifolds

1997 ◽  
Vol 07 (11) ◽  
pp. 2487-2499 ◽  
Author(s):  
Rabbijah Guder ◽  
Edwin Kreuzer
Keyword(s):  
Dynamical Systems ◽  
Invariant Measures ◽  
Nonlinear Dynamical Systems ◽  
Powerful Method ◽  
Cell Mapping ◽  
Generalized Cell Mapping ◽  
Nonlinear Dynamical ◽  
Long Term Behavior ◽  
Mapping Theory

In order to predict the long term behavior of nonlinear dynamical systems the generalized cell mapping is an efficient and powerful method for numerical analysis. For this reason it is of interest to know under what circumstances dynamical quantities of the generalized cell mapping (like persistent groups, stationary densities, …) reflect the dynamics of the system (attractors, invariant measures, …). In this article we develop such connections between the generalized cell mapping theory and the theory of nonlinear dynamical systems. We prove that the generalized cell mapping is a discretization of the Frobenius–Perron operator. By applying the results obtained for the Frobenius–Perron operator to the generalized cell mapping we outline for some classes of transformations that the stationary densities of the generalized cell mapping converges to an invariant measure of the system. Furthermore, we discuss what kind of measures and attractors can be approximated by this method.

Long-Term Behavior of Wood-Concrete Composite Floor/Deck Systems with Shear Key Connection Detail

2007 ◽  
Vol 133 (9) ◽  
pp. 1307-1315 ◽  
Author(s):  
M. Fragiacomo ◽  
R. M. Gutkowski ◽  
J. Balogh ◽  
R. S. Fast
Keyword(s):  
Shear Key ◽  
Long Term Behavior

Attractors for multi-valued lattice dynamical systems with nonlinear diffusion terms

2021 ◽  
Author(s):  
Panpan Zhang ◽  
Anhui Gu
Keyword(s):  
Dynamical Systems ◽  
Nonlinear Diffusion ◽  
Upper Semicontinuity ◽  
Growth Conditions ◽  
Pullback Attractor ◽  
Random Lattice ◽  
Lipschitz Continuous ◽  
Lattice Dynamical Systems ◽  
Long Term Behavior

This paper is devoted to the long-term behavior of nonautonomous random lattice dynamical systems with nonlinear diffusion terms. The nonlinear drift and diffusion terms are not expected to be Lipschitz continuous but satisfy the continuity and growth conditions. We first prove the existence of solutions, and establish the existence of a multi-valued nonautonomous cocycle. We then show the existence and uniqueness of pullback attractors parameterized by sample parameters. Finally, we establish the measurability of this pullback attractor by the method based on the weak upper semicontinuity of the solutions.

Sign in / Sign up

Export Citation Format

Share Document