Evaluation of In-Service Thermoplastic Olefin (TPO) Roofing Membranes

Author(s):  
TR Simmons ◽  
RM Paroli ◽  
KKY Liu ◽  
AH Delgado ◽  
JD Irwin
Keyword(s):  
2010 ◽  
Vol 50 (11-12) ◽  
pp. 881-895 ◽  
Author(s):  
Amirhossein Maani ◽  
Marie-Claude Heuzey ◽  
Pierre J. Carreau

1998 ◽  
Vol 71 (4) ◽  
pp. 778-794 ◽  
Author(s):  
N. Dharmarajan ◽  
L. G. Kaufman

Abstract Polymer blends of ethylene-propylene elastomers and polypropylene plastics, referred to as thermoplastic olefins, are finding increasing use in automotive applications. The combination of attractive mechanical properties, low raw material cost and recyclability make these materials ideal substitutes for expensive engineering thermoplastics (polycarbonate/polybutylene terephthalate alloys) and nonrecyclable polyurethane systems. The primary application is in automotive bumper fascia. This paper describes the addition of long chain branched ethylene-propylene elastomers in thermoplastic olefin compounds containing a high flow polypropylene resin matrix. In such compounds, the modifier molecular architecture plays an important role in impact toughening. The results clearly indicate that linear modifiers such as traditional ethylene-propylene copolymers are ineffective in impact toughening, while long chain branched polymers provide enhanced impact resistance with a ductile failure mode in high flow polypropylenes.


Langmuir ◽  
1998 ◽  
Vol 14 (9) ◽  
pp. 2426-2434 ◽  
Author(s):  
Hannah R. Morris ◽  
Branka Munroe ◽  
Rose A. Ryntz ◽  
Patrick J. Treado

1983 ◽  
Vol 56 (1) ◽  
pp. 68-82 ◽  
Author(s):  
C. C. Ho ◽  
E. G. Kontos

Abstract We have presented a method for evaluating the vacuum forming performance of polymers by comparing their forming window. The window is determined by (a) the sag of the heated sheet and (b) the material's ability to reproduce mold details. We also showed that the vacuum forming window of polypropylene homopolymer can be widened through modification with an olefinic thermoplastic elastomer. Compared to polypropylene homopolymer, TPE-modified polypropylene requires lower tensile stress to extend the sample at temperatures below the polypropylene melting point. In the melt stage. TPE modification enhances the melt viscosity of polypropylene. TPE modification increases significantly the low temperature impact of polypropylene. The flexural modulus becomes lower.


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