Chapter 14—Irradiation Effects on Impact Properties

Electron Irradiation Effects in Polyoxymethylene Crystals Grown Inside Trioxane Crystals

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010006444x ◽

1971 ◽

Vol 29 ◽

pp. 78-79

Author(s):

J. P. Colson ◽

D. H. Reneker

Keyword(s):

Cross Section ◽

Cross Sections ◽

Detailed Examination ◽

The Other ◽

Electron Micrograph ◽

Irradiation Effects ◽

Threefold Axis ◽

Typical Sample ◽

Polymer Crystals ◽

Chain Axis

Polyoxymethylene (POM) crystals grow inside trioxane crystals which have been irradiated and heated to a temperature slightly below their melting point. Figure 1 shows a low magnification electron micrograph of a group of such POM crystals. Detailed examination at higher magnification showed that three distinct types of POM crystals grew in a typical sample. The three types of POM crystals were distinguished by the direction that the polymer chain axis in each crystal made with respect to the threefold axis of the trioxane crystal. These polyoxymethylene crystals were described previously.At low magnifications the three types of polymer crystals appeared as slender rods. One type had a hexagonal cross section and the other two types had rectangular cross sections, that is, they were ribbonlike.

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In situ TEM studies of irradiation effects for materials improvement

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100086568 ◽

1991 ◽

Vol 49 ◽

pp. 452-453

Author(s):

Charles W. Allen

Keyword(s):

Nuclear Reactor ◽

Austenitic Stainless Steels ◽

High Energy ◽

Point Of View ◽

In Situ Tem ◽

Irradiation Effects ◽

Tem Analysis ◽

Radiation Induced ◽

Analytical Tools

Irradiation effects studies employing TEMs as analytical tools have been conducted for almost as many years as materials people have done TEM, motivated largely by materials needs for nuclear reactor development. Such studies have focussed on the behavior both of nuclear fuels and of materials for other reactor components which are subjected to radiation-induced degradation. Especially in the 1950s and 60s, post-irradiation TEM analysis may have been coupled to in situ (in reactor or in pile) experiments (e.g., irradiation-induced creep experiments of austenitic stainless steels). Although necessary from a technological point of view, such experiments are difficult to instrument (measure strain dynamically, e.g.) and control (temperature, e.g.) and require months or even years to perform in a nuclear reactor or in a spallation neutron source. Consequently, methods were sought for simulation of neutroninduced radiation damage of materials, the simulations employing other forms of radiation; in the case of metals and alloys, high energy electrons and high energy ions.

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Defects in Crystals

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100100962 ◽

1968 ◽

Vol 26 ◽

pp. 244-245

Author(s):

Kenneth R. Lawless

Keyword(s):

Electron Microscope ◽

Point Defects ◽

Surface Defects ◽

Chemical Properties ◽

Material Point ◽

Crystal Defects ◽

Defects In Crystals ◽

Irradiation Effects ◽

Normal Lattice ◽

Line Defects

One of the most important applications of the electron microscope in recent years has been to the observation of defects in crystals. Replica techniques have been widely utilized for many years for the observation of surface defects, but more recently the most striking use of the electron microscope has been for the direct observation of internal defects in crystals, utilizing the transmission of electrons through thin samples.Defects in crystals may be classified basically as point defects, line defects, and planar defects, all of which play an important role in determining the physical or chemical properties of a material. Point defects are of two types, either vacancies where individual atoms are missing from lattice sites, or interstitials where an atom is situated in between normal lattice sites. The so-called point defects most commonly observed are actually aggregates of either vacancies or interstitials. Details of crystal defects of this type are considered in the special session on “Irradiation Effects in Materials” and will not be considered in detail in this session.

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