Effect of chemical modification on slip resistance and mechanical properties of rubber

2015 ◽  
Vol 35 (2) ◽  
pp. 119-125
Author(s):  
Ranganathan Mohan ◽  
Raja Sundaresan ◽  
Bhabendra Nath Das
Keyword(s):  
Mechanical Properties ◽  
Surface Modification ◽  
Photoelectron Spectroscopy ◽  
Abrasion Resistance ◽  
Material Design ◽  
Surface Modifications ◽  
Vertical Force ◽  
Water Contact ◽  
Slip Resistance ◽  
Surface Modified

Abstract Shoe sole material, design, tread pattern and surface modifications influence slip resistance while walking and running. Thermoplastic styrene-butadine-styrene rubber, commercially known as TPR, is one of the materials widely used as shoe soles. This type of sole is subjected to chemical treatment known as halogenation to increase adhesion characteristic with the upper. The coefficient of friction (COF) is the ratio between the horizontal force and the vertical force when tested with the help of slip resistance test equipment SATRA STM 603. It is also known that footwear outsole surface modification affects COF at the footwear floor interfaces. In this study, plain TPR shoe sole samples were surface modified by treating with 2.0 wt% trichloroisocyanuric acid (TCI) in methyl ethyl ketone (MEK). The effect of surface modifications was studied by water contact angle measurements, Fourier transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS), surface roughness and scanning electron microscopy (SEM). The surface modified sole samples were also tested for other mechanical properties such as tensile strength, elongation at break, hardness and abrasion resistance to find out the extent of changes in those essential functional properties. It was observed that surface modification of TPR sole increased COF and reduced strength, elasticity and abrasion resistance properties. However, there was no significant change in hardness.

scholarly journals Facile Preparation of Efficient WO3Photocatalysts Based on Surface Modification

2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Min Liu ◽  
Hongmei Li ◽  
Yangsu Zeng
Keyword(s):  
Photocatalytic Activity ◽  
Surface Modification ◽  
Visible Light ◽  
Photoelectron Spectroscopy ◽  
Impregnation Method ◽  
Light Spectra ◽  
Simple Strategy ◽  
Visible Light Active ◽  
Efficient Charge ◽  
Surface Modified

Tungsten trioxide (WO3) was surface modified with Cu(II) nanoclusters and titanium dioxide (TiO2) nanopowders by using a simple impregnation method followed by a physical combining method. The obtained nanocomposites were studied by scanning electron microscope, X-ray photoelectron spectroscopy spectra, UV-visible light spectra, and photoluminescence, respectively. Although the photocatalytic activity of WO3was negligible under visible light irradiation, the visible light photocatalytic activity of WO3was drastically enhanced by surface modification of Cu(II) nanoclusters and TiO2nanopowders. The enhanced photocatalytic activity is due to the efficient charge separation by TiO2and Cu(II) nanoclusters functioning as cocatalysts on the surface. Thus, this simple strategy provides a facile route to prepare efficient visible-light-active photocatalysts for practical application.

scholarly journals Superhydrophilic Coating with Antibacterial and Oil-Repellent Properties via NaIO4-Triggered Polydopamine/Sulfobetaine Methacrylate Polymerization

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2008
Author(s):  
Hsiu-Wen Chien ◽  
Hong-Yu Lin ◽  
Chau-Yi Tsai ◽  
Tai-Yu Chen ◽  
Wei-Nian Chen
Keyword(s):  
Surface Modification ◽  
Photoelectron Spectroscopy ◽  
Deposition Process ◽  
Water Contact ◽  
Water Separation ◽  
Force Microscopy ◽  
Atomic Force ◽  
Oil Water Separation ◽  
One Step ◽  
Oil Repellent

Superhydrophilic coatings have been widely used for the surface modification of membranes or biomedical devices owing to their excellent antifouling properties. However, simplifying the modification processes of such materials remains challenging. In this study, we developed a simple and rapid one-step co-deposition process using an oxidant trigger to fabricate superhydrophilic surfaces based on dopamine chemistry with sulfobetaine methacrylate (SBMA). We studied the effect of different oxidants and SBMA concentrations on surface modification in detail using UV–VIS spectrophotometry, dynamic light scattering, atomic force microscopy, X-ray photoelectron spectroscopy, and surface plasmon resonance. We found that NaIO4 could trigger the rate of polymerization and the optimum ratio of dopamine to SBMA is 1:25 by weight. This makes the surface superhydrophilic (water contact angle < 10°) and antifouling. The superhydrophilic coating, when introduced to polyester membranes, showed great potential for oil/water separation. Our study provides a complete description of the simple and fast preparation of superhydrophilic coatings for surface modification based on mussel-inspired chemistry.

scholarly journals Electrophoretic Deposition of Carbon Nanotubes over TiO2Nanotubes: Evaluation of Surface Properties and Biocompatibility

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Jung Eun Park ◽  
Il Song Park ◽  
Tae Sung Bae ◽  
Min Ho Lee
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Corrosion Resistance ◽  
Surface Modification ◽  
Electrophoretic Deposition ◽  
Biomedical Applications ◽  
Controlled Drug Delivery ◽  
Chemical Durability ◽  
Surface Modified ◽  
Excellent Chemical

Titanium (Ti) is often used as an orthopedic and dental implant material due to its better mechanical properties, corrosion resistance, and excellent biocompatibility. Formation of TiO2nanotubes (TiO2NTs) on titanium is an interesting surface modification to achieve controlled drug delivery and to promote cell growth. Carbon nanotubes (CNTs) possess excellent chemical durability and mechanical strength. The use of CNTs in biomedical applications such as scaffolds has received considerable attention in recent years. The present study aims to modify the surface of titanium by anodizing to form TiO2NTs and subsequently deposit CNTs over it by electrophoretic deposition (EPD). Characteristic, biocompatibility, and apatite forming ability of the surface modified samples were evaluated. The results of the study reveal that CNTs coating on TiO2nanotubes help improve the biological activity and this type of surface modification is highly suitable for biomedical applications.

Surface Modification of the ZnO Nanoparticles with γ-Aminopropyltriethoxysilane and Study of Their Photocatalytic Activity, Optical Properties and Antibacterial Activities

2016 ◽  
Vol 14 (3) ◽  
pp. 785-794 ◽  
Author(s):  
Nurun Nahar Rabin ◽  
Jannatul Morshed ◽  
Hashi Akhter ◽  
Md. Saidul Islam ◽  
Md. Asjad Hossain ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Surface Modification ◽  
Zno Nanoparticles ◽  
Photoelectron Spectroscopy ◽  
Dye Degradation ◽  
Antibacterial Activities ◽  
Bet Analysis ◽  
Modified Zno Nanoparticles ◽  
Grafted Nanoparticles ◽  
Surface Modified

Abstract Surface modification of Zinc oxide nanoparticles (ZnO) with γ-aminopropyltriethoxy silane (APTES) was investigated. Successful surface modification of the nanoparticles was confirmed experimentally by X-ray Photoelectron Spectroscopy (XPS) and Fourier transform infrared spectroscopy (FT-IR). The effect of the surface modifier concentration on the grafting density and surface area was studied by CHN elemental analysis and Brunauer–Emmett–Teller (BET) analysis. The photocatalytic activity and UV shielding ability of the surface-modified particles prepared in water-ethanol solvent in the presence of the surface modifiers were compared to those of non-modified particles. As a case study, It was observed by methylene blue (MB) dye degradation experiment that the photocatalytic activity in the presence of modified nanoparticles was lower than that observed with non-modified ZnO nanoparticles. Dispersion stability tests visually showed that APTES grafted nanoparticles had acquired better stability than non-modified ZnO nanoparticles in aqueous solution.

scholarly journals UV-Curable Hydrophobic Coatings of Functionalized Carbon Microspheres with Good Mechanical Properties and Corrosion Resistance

Coatings ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 439 ◽  
Author(s):  
Jiajia Wen ◽  
Chengchen Feng ◽  
Huijie Li ◽  
Xinghai Liu ◽  
Fuyuan Ding ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Corrosion Resistance ◽  
Thermogravimetric Analysis ◽  
Photoelectron Spectroscopy ◽  
Carbon Microspheres ◽  
Sem Images ◽  
Water Contact ◽  
Pencil Hardness ◽  
Uv Curable ◽  
Functional Product

Polyurethane acrylates (PUAs) are a kind of UV curable prepolymer with excellent comprehensive performance. However, PUAs are highly hydrophilic and when applied outdoors, presenting serious problems caused by rain such as discoloring, losing luster and blistering. Thus, it’s important to improve their hydrophobicity and resistance against corrosion. In this paper, carbon microspheres (CMSs) were modified through chemical grafting method. Active double bonds were introduced onto the surface of organic carbon microspheres (OCMSs) and the functional product was referred to as FCMS. The results of Transmission Electron Microscope (TEM), X-ray Photoelectron Spectroscopy (XPS) and Thermogravimetric analysis (TGA) showed that organic chain segments were successfully connected to the surface of OCMSs and the grafting efficiency was as high as 16%. FCMSs were successfully added into UV-curable polyurethane acrylate prepolymer to achieve a hydrophobic coating layer with good mechanical properties, thermal stability and corrosion resistance. When the addition of FCMSs were 1%, thermogravimetric analysis (TGA) results showed that 5% of the initial mass was lost at 297 °C. The water absorption decreased from 52% to 38% and the water contact angle of the PUA composite increased from 72° to 106°. The pencil hardness increased to 4H and obvious crack termination phenomenon was observed in SEM images. Moreover, the corrosion rate was decreased from 0.124 to 0.076 mm/a.

scholarly journals Properties of Conductive Polyacrylonitrile Fibers Prepared by Using Benzoxazine Modified Carbon Black

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 179 ◽  
Author(s):  
Damiro Ahn ◽  
Hyun-Jung Choi ◽  
Ho-dong Kim ◽  
Sang Young Yeo
Keyword(s):  
Mechanical Properties ◽  
Carbon Black ◽  
Photoelectron Spectroscopy ◽  
Weight Ratio ◽  
Pan Fiber ◽  
Potential Applications ◽  
Conductive Fillers ◽  
Conductive Fibers ◽  
Surface Modified ◽  
Pan Fibers

Composites of carbon black (CB) and polymers are attractive for producing conductive fibers. Herein, to achieve improved interactions with polymers, the surface of CB was modified to form 4-aminobenzoyl-functionalized carbon black (ABCB), benzoxazine-functionalized carbon black (BZCB), and Ag-anchored carbon black (Ag-ABCB). The surface-modified CBs were characterized by Fourier transform infrared spectroscopy and thermogravimetric analysis, and X-ray photoelectron spectroscopy was utilized to confirm the presence of Ag in Ag-ABCB. Conductive polyacrylonitrile (PAN) fibers were wet-spun with conductive fillers (CB, ABCB, Ag-ABCB, and BZCB) to investigate the effects of various functional groups on the electrical and mechanical properties. After annealing the conductive PAN fibers, the conductivity and tensile strength greatly increased, whereas the diameter decreased. Notably, the fiber with a BZCB/PAN weight ratio of 12/88 possessed a conductivity of 8.9 × 10−4 S/cm, and strength of 110.4 MPa, and thus the highest conductivity and best mechanical properties in the conductive PAN fiber. These results indicate that the annealed BZCB/PAN fibers have potential applications in the manufacturing of antistatic fabrics.

scholarly journals Photocatalytic Surface Modification of PI Film for Electroless Copper Plating

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Wenxia Zhao ◽  
Zenglin Wang ◽  
Liang Qiao ◽  
Shiwei Liu ◽  
Hongjian Zhao ◽  
...  
Keyword(s):  
Contact Angle ◽  
Surface Modification ◽  
Adhesion Strength ◽  
Photoelectron Spectroscopy ◽  
Carboxyl Groups ◽  
Electroless Copper Plating ◽  
Electroless Copper ◽  
Surface Contact ◽  
Surface Contact Angle ◽  
Surface Modified

This study investigated the surface modification of polyimide (PI) film through TiO2 photocatalytic treatment. The effects of TiO2 content, treatment duration, and UV power on the surface topography, surface contact angle, and adhesion strength of the surface-modified PI films were investigated. The results indicated that, after surface modification under the optimal photocatalytic conditions, the surface contact angle of the PI film decreased from 84.4° to 38.8°, and the adhesion strength between the PI film and the electroless copper film reached 0.78 kN/m. X-ray photoelectron spectroscopy analysis further demonstrated that carboxyl groups formed on the surface of the PI film after photocatalytic treatment. The surface hydrophilicity and adhesion strength of the surface-modified PI film were enhanced due to the numerous carboxyl groups formed on its surface. Therefore, the photocatalytic treatment is an environmentally friendly and effective method for the surface modification of PI films.

scholarly journals Surface Modification of Hemoglobin-Based Oxygen Carriers Reduces Recognition by Haptoglobin, Immunoglobulin, and Hemoglobin Antibodies

Coatings ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 454 ◽  
Author(s):  
Ausanai Prapan ◽  
Nittiya Suwannasom ◽  
Chiraphat Kloypan ◽  
Saranya Chaiwaree ◽  
Axel Steffen ◽  
...  
Keyword(s):  
Surface Modification ◽  
Biomedical Applications ◽  
Binding Capacity ◽  
Surface Modifications ◽  
The Body ◽  
Laser Scanning Microscopy ◽  
Confocal Laser ◽  
Oxygen Binding ◽  
Oxygen Carriers ◽  
Surface Modified

Hemoglobin-based oxygen carriers (HBOCs) represent a propitious type of blood substitute to transport oxygen throughout the body while acting as a carrier in biomedical applications. However, HBOCs in blood are recognized and rapidly scavenged by the body’s innate immune systems. To overcome this problem, HBOCs require a surface modification that provides protection against detection and elimination in order to prolong their circulation time after administration. In this study, we investigated different surface modifications of hemoglobin submicron particles (HbMPs) by double/triple precipitation, as well as by adsorption of human serum albumin (HSA), hyaluronic acid (HA), and pluronic (Plu) to discover how diverse surface modifications influence the oxygen binding capacity and the binding of anti-hemoglobin (Hb) antibodies, immunoglobulin G (IgG), and haptoglobin (HP) to HbMPs. The particle size and zeta potential of the six types of HbMP modifications were analyzed by zeta sizer, confocal laser scanning microscopy, and transmission electron microscopy (TEM), and were compared to the unmodified HbMPs. The results revealed that all surface-modified HbMPs had a submicron size with a negative charge. A slight decrease in the oxygen binding capacity was noticed. The specific binding of anti-Hb antibodies, IgG, and HP to all surface-modified HbMPs was reduced. This indicates a coating design able to protect the particles from detection and elimination processes by the immune system, and should lead to a delayed clearance and the required and essential increase in half-life in circulation of these particles in order to fulfill their purpose. Our surface modification method reflects a promising strategy for submicron particle design, and can lead the way toward novel biomedical applications.

Cure Characteristics and Mechanical Properties of NR/ SBR Blends Filled with Nano-sized CaCO3

2005 ◽  
Vol 21 (2) ◽  
pp. 101-115
Author(s):  
Chaoying Wan ◽  
Yong Zhang ◽  
Yin Zhu ◽  
Yinxi Zhang
Keyword(s):  
Mechanical Properties ◽  
Surface Modification ◽  
Stearic Acid ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Cure Rate ◽  
Cure Characteristics ◽  
Cure Time ◽  
Surface Modified ◽  
Styrene Butadiene

Four kinds of nano-sized calcium carbonate (CaCO3) surface-modified with stearic acid, aluminate, titanate and aluminate-titanate complex coupling agents, were used to reinforce natural rubber (NR)/styrene-butadiene rubber (SBR) blends. The effects of surface modification and CaCO3 content on the cure characteristics, swelling behaviour, and mechanical properties of NR/SBR blends were studied. The surface modification of CaCO3 improved the processing and mechanical properties, and the stearic acid coated CaCO3 (SA-CaCO3) had finer dispersion and produced a better reinforcement effect than the other modified CaCO3. Furthermore, a commercial high abrasion furnace carbon black (HAF) was used for comparison. The results showed that both CaCO3 and HAF increased the cure rate, reduced the optimum cure time and improved the mechanical properties of NR/SBR blends at appropriate filler contents. The tensile strength of filled NR/SBR composites reached its maximum value when the SA-CaCO3 content was 50 phr or the HAF content was 30 phr. The modulus at 200%, tear strength, and Shore A hardness of filled NR/SBR composites all increased with increasing filler content. The CaCO3 reinforced the NR/SBR blends to some extent, though it was still not as effective as HAF.

scholarly journals Preparation of CNF/PDMS Superhydrophobic Coatings with Good Abrasion Resistance Using a One-Step Spray Method

Materials ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 5380
Author(s):  
Jingda Huang ◽  
Peihao Cai ◽  
Mengmeng Li ◽  
Qiang Wu ◽  
Qian Li ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Abrasion Resistance ◽  
Substrate Surface ◽  
Cellulose Nanofibers ◽  
Scratch Resistance ◽  
Water Contact ◽  
Preparation Methods ◽  
Superhydrophobic Coatings ◽  
Spray Method ◽  
Complex Preparation

Complex preparation methods and weak mechanical properties of superhydrophobic coatings hinder their applicability. To address these problems, cellulose nanofibers (CNFs) were used as structural materials to augment the roughness properties, while polydimethylsiloxane (PDMS) was used as the adhesive. Based on the results of previous studies, superhydrophobic coatings with good mechanical properties can be prepared by spraying the mixture onto a substrate surface; herein, the mixture comprised modified CNFs and PDMS. The resulting coating possessed excellent superhydrophobicity, which allowed a maximum water contact angle (WCA) of 158°. Furthermore, it exhibited great knife-scratch-resistance properties and good abrasion performance, which was evaluated by abrading with 800-grit sandpaper for 19 cycles (abrasion length of 380 cm) under a 100 g load. Based on the simple operation and abrasion resistance, the coating shows great potential for practical application.

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