Thermal degradation of high-density polyethylene/soya spent powder blends

2015 ◽  
Vol 35 (5) ◽  
pp. 437-442 ◽  
Author(s):  
Sam Sung Ting ◽  
Norsri Kurniati Achmad ◽  
Hanafi Ismail ◽  
Ragunathan Santiagoo ◽  
Nik Noriman Zulkepli

Abstract This study investigates the properties of high-density polyethylene (HDPE) with different soya spent powder (SSP) blend contents upon oven aging. The aged properties of the HDPE/SSP blends were studied by using tensile test, thermogravimetric analysis, differential scanning calorimetry and Fourier transform infrared analysis. The tensile strength and elongation at break (Eb) decreased inversely proportional to SSP content and aging period. The thermal stability of the blends was significantly reduced after 21 days of aging. After aging, the melting temperature and crystallinity of the blends decreased with increasing aging period. These results revealed that samples with higher SSP content are more brittle upon oven aging.

2015 ◽  
Vol 74 (10) ◽  
Author(s):  
M. P. M. Hanif ◽  
Supri A. G. ◽  
Firuz Zainuddin

The effect of phthalic anhydride as a coupling agent on the tensile properties and thermal stability of recycled high density polyethylene/wood fiber (rHDPE/WF) composites were studied.  Both composites rHDPE/WF and rHDPE/WF/PAH (modified with phthalic anhydride) were prepared using Brabender Plasticorder at a temperature of 160°C and rotor speed of 50 rpm. The result indicated that rHDPE/WF/PAH composites exhibit higher tensile strength and modulus of elasticity than rHDPE/WF composites. It was also found that the addition of phthalic anhydride offers better thermal stability in rHDPE/WF/PAH composites than that of rHDPE/WF composites.


2014 ◽  
Vol 679 ◽  
pp. 132-136 ◽  
Author(s):  
M.P.M. Hanif ◽  
A.G. Supri ◽  
Z. Firuz

The effect of salicylic acid/ethanol as a coupling agent on the tensile properties and thermal stability of recycled high density polyethylene/wood fiber (rHDPE/WF) composites were studied. Both composites rHDPE/WF and rHDPE/WFM (treatment with salicylic acid) were prepared using Brabender Plasticorder at temperature of 160°C and rotor speed of 50 rpm. The result indicated that rHDPE/WFM composites with salicylic acid exhibit higher tensile strength and modulus of elasticity and lower elongation at break than rHDPE/WF composites. It was also found that the addition of salicylic acid/ethanol shows better thermal stability in rHDPE/WFM composites than rHDPE/WF composites.


2019 ◽  
Author(s):  
Andreas Boelke ◽  
Yulia A. Vlasenko ◽  
Mekhman S. Yusubov ◽  
Boris Nachtsheim ◽  
Pavel Postnikov

<p>The thermal stability of pseudocyclic and cyclic <i>N</i>-heterocycle-stabilized (hydroxy)aryl- and mesityl(aryl)-l<sup>3</sup>-iodanes (NHIs) through thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) is investigated. NHIs bearing <i>N</i>-heterocycles with a high N/C-ratio such as triazoles show among the lowest descomposition temperatures and the highest decomposition energies. A comparison of NHIs with known (pseudo)cyclic benziodoxolones is made and we further correlated their thermal stability with reactivity in a model oxygenation. </p>


2018 ◽  
Vol 39 (4) ◽  
pp. 21
Author(s):  
Gilbert Bannach ◽  
Rafael R. Almeida ◽  
Luis G. Lacerda ◽  
Egon Schnitzler ◽  
Massao Ionashiro

Several papers have been described on the thermal stability of the sweetener, C12H19Cl3O8 (Sucralose). Nevertheless no study using thermoanalytical techniques was found in the literature. Simultaneous thermogravimetry and differential thermal analysis (TG-DTA), differential scanning calorimetry (DSC) and infrared spectroscopy, have been used to study the thermal stability and thermal decomposition of sweetener.


2018 ◽  
Vol 6 (41) ◽  
pp. 20383-20392 ◽  
Author(s):  
Yongho Lee ◽  
Hyojun Lim ◽  
Sang-Ok Kim ◽  
Hyung-Seok Kim ◽  
Ki Jae Kim ◽  
...  

The thermal behavior of fully lithiated and sodiated Sn electrodes cycled in a MePF6 (Me = Li or Na)-based electrolyte was studied using differential scanning calorimetry (DSC).


2019 ◽  
Vol 33 (11) ◽  
pp. 1466-1477
Author(s):  
Qingfa Zhang ◽  
Wenyu Lu ◽  
Liang Zhou ◽  
Donghong Zhang ◽  
Hongzhen Cai ◽  
...  

Biocomposites were prepared with corn straw slagging (CSS) and high-density polyethylene (HDPE) at four loading levels (10, 20, 30, and 40 wt%) by extrusion method. CSS/HDPE composites were tested by tension, oxygen index meter, differential scanning calorimetry, X-ray diffraction, and the scanning electron microscopy. The scanning electron microscopy showed that CSS was dispersed uniformly in the HDPE matrix and strong interfacial interaction was achieved, which had an important influence on the tensile strength of the composites. The tensile strength of the composites could be improved with proper increase of CSS and reached maximum value at 30 wt% content. Furthermore, the addition of CSS played an important role in improving the flame-retardant ability of CSS/HDPE composites, and the limited oxygen index was 31.26% at 40 wt% content, good flame-retardant effect achieved.


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