Potential solvent for reconditioning polyolefin waste materials

2012 ◽  
Vol 32 (8-9) ◽  
pp. 585-591 ◽  
Author(s):  
Arkan J. Hadi ◽  
Ghazi Faisal Najmuldeen ◽  
Iqbal Ahmed
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Fourier Transform ◽  
High Density Polyethylene ◽  
Waste Materials ◽  
Scanning Calorimetry ◽  
Polymer Recycling ◽  
Significant Difference ◽  
Before And After ◽  
Waste Polymer

Abstract Waste polymer reconditioning was examined by a method of dissolution/reprecipitation on low- and high-density polyethylene (PE) and polypropylene (PP). Toluene and petroleum ether, in different proportions, were used as solvents, and n-hexane was used as a non-solvent. Commercial polymer products used on an everyday basis were used with a virgin polymer, to optimize the qualities of the final product, and 98% polymer was recovered in each case. Fourier transform infrared spectroscopy (FTIR) images and tensile mechanical properties of the samples, before and after recycling, were analyzed. The potential recycling-based degradation of the polymer was further investigated by measuring the thermal properties (melting point and crystallinity) before and after recycling, using differential scanning calorimetry (DSC). High reconditioning was observed in most recycled samples, with no significant difference from the virgin materials. The studied technique seems to be viable for waste polyolefin polymer recycling.

Dissolution/reprecipitation technique for waste polyolefin recycling using new pure and blend organic solvents

2013 ◽  
Vol 33 (5) ◽  
pp. 471-481 ◽  
Author(s):  
Arkan J. Hadi ◽  
Ghazi Faisal Najmuldeen ◽  
Kamal Bin Yusoh
Keyword(s):  
High Density Polyethylene ◽  
Raw Materials ◽  
Scanning Calorimetry ◽  
Polymer Recycling ◽  
Plastic Materials ◽  
Pure Solvent ◽  
Significant Difference ◽  
Before And After ◽  
Reprecipitation Method ◽  
Waste Polymer

Abstract Restoration of waste polymer based on low-density polyethylene (LDPE), high-density polyethylene (HDPE) and polypropylene (PP) is studied using the dissolution/reprecipitation method. In this technique, pure turpentine, turpentine/petroleum ether (PetE) and turpentine/benzene as solvents with different fractions and PetE and n-hexane as non-solvents were examined. Commercial polymer products (packaging food, bags, laboratory plastic materials, detergent containers) used as raw materials were optimized with model polymers. Polymer recoveries in every case were <94%. Fourier transform infrared (FTIR) spectra and tensile mechanical properties of the samples before and after recycling were measured. Potential recycling-based degradation of the polymer was further investigated by measuring the thermal properties (melting point and crystallinity), before and after recycling, using differential scanning calorimetry (DSC). The blend solvents were seen as good solvents for all polyolefins used and the dissolution temperature was less than the pure solvent at the same time. High reconditioning was observed in most recycled samples, with no significant difference from the virgin materials. The studied technique seems to be viable for waste polyolefin polymer recycling.

scholarly journals Mechanical Properties, Wettability and Thermal Degradation of HDPE/Birch Fiber Composite

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1459
Author(s):  
Agbelenko Koffi ◽  
Fayçal Mijiyawa ◽  
Demagna Koffi ◽  
Fouad Erchiqui ◽  
Lotfi Toubal
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Thermal Degradation ◽  
Coupling Agent ◽  
High Density Polyethylene ◽  
Fiber Composite ◽  
Flexural Modulus ◽  
High Density ◽  
Wood Fibers ◽  
Scanning Calorimetry

Wood–plastic composites have emerged and represent an alternative to conventional composites reinforced with synthetic carbon fiber or glass fiber–polymer. A wide variety of wood fibers are used in WPCs including birch fiber. Birch is a common hardwood tree that grows in cool areas such as the province of Quebec, Canada. The effect of the filler proportion on the mechanical properties, wettability, and thermal degradation of high-density polyethylene/birch fiber composite was studied. High-density polyethylene, birch fiber and maleic anhydride polyethylene as coupling agent were mixed and pressed to obtain test specimens. Tensile and flexural tests, scanning electron microscopy, dynamic mechanical analysis, differential scanning calorimetry, thermogravimetry analysis and surface energy measurement were carried out. The tensile elastic modulus increased by 210% as the fiber content reached 50% by weight while the flexural modulus increased by 236%. The water droplet contact angle always exceeded 90°, meaning that the material remained hydrophobic. The thermal decomposition mass loss increased proportional with the percentage of fiber, which degraded at a lower temperature than the HDPE did. Both the storage modulus and the loss modulus increased with the proportion of fiber. Based on differential scanning calorimetry, neither the fiber proportion nor the coupling agent proportion affected the material melting temperature.

scholarly journals Performance Analysis of Colored PLA Products with a Fused Filament Fabrication Process

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 1984 ◽  
Author(s):  
Roberto Spina
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Performance Analysis ◽  
Processing Parameters ◽  
Fused Filament Fabrication ◽  
Scanning Calorimetry ◽  
Experimental Activity ◽  
Significant Difference ◽  
Thermal Measurements

The objective of the present work is to study the influence of color additives used for the polylactic acid (PLA) filament on the final quality of fused filament fabrication (FFF) parts. The main processing parameters of FFF parts were evaluated, identifying the significant correlations between PLA properties and part performance, using a commercial FFF machine. The quality of the products was evaluated in terms of thermo-mechanical properties such as mechanical strength, principal material temperatures, and viscosity. These last properties were characterized using differential scanning calorimetry (DSC) for the thermal measurements and a rotational rheometry (RHEO) for viscosity measurements. Cylindrical specimens were then produced for the compression test. The experimental activity and related testing of products are fully described, pointing out a significant difference in performance between parts made of different colored filaments.

Accelerated aging and characterization of HDPE pin type insulators (15 kV)

2021 ◽  
pp. 096739112110476
Author(s):  
Cynthia DC Erbetta ◽  
Maria Elisa SR Silva ◽  
Roberto FS Freitas ◽  
Ricardo G Sousa
Keyword(s):  
Differential Scanning Calorimetry ◽  
Fourier Transform ◽  
High Density Polyethylene ◽  
Accelerated Aging ◽  
Natural Aging ◽  
Accelerated Weathering ◽  
Electrical System ◽  
Scanning Calorimetry ◽  
Aging Conditions

The study of the behavior of polymeric material used for insulators in the electrical system is extremely important in order to evaluate their lifetime as well as their performance when exposed to different environmental conditions. In the present work, the behavior of high-density polyethylene (HDPE) pin type insulators (15 kV), under accelerated aging conditions, was studied. Samples were exposed to aging, for 200 h, 1000 h, and 2000 h, in accelerated weathering chambers, according to two different methods. In Method 1, the parameters were established based on natural aging in location conditions, and in Method 2, ASTM G155 standard parameters were used. All samples were characterized by rheometry, Fourier-transform infrared spectroscopy (FTIR), and differential scanning calorimetry (DSC). The accelerated aging conditions, used in Methods 1 and 2, affected the aging of HDPE pin type insulators samples differently, the changes being more intense in Method 1.

Accelerated Ageing of Alkali Treated Olive Husk Flour Reinforced Polylactic Acid (PLA) Biocomposites: Physico-Mechanical Properties

2018 ◽  
Vol 26 (3) ◽  
pp. 223-232 ◽  
Author(s):  
Samra Isadounene ◽  
Dalila Hammiche ◽  
Amar Boukerrou ◽  
Denis Rodrigue ◽  
Hocine Djidjelli
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Tensile Strength ◽  
Fourier Transform ◽  
Poly Lactic Acid ◽  
Accelerated Ageing ◽  
Water Spray ◽  
Scanning Calorimetry ◽  
Biodegradable Composites ◽  
Olive Husk

In this study, olive husk flour was added to poly(lactic acid) (PLA) to produce fully biosourced and biodegradable composites. In particular, untreated and alkali treated particles were used to produce the biocomposites at 20 wt.% via melt extrusion followed by injection moulding. The samples were then subjected to accelerated ageing (UV irradiation and water spray at 50°C) for different amounts of time (120, 240, 360 and 480 h). The results show that accelerated ageing decreased the tensile strength (TS) and Young's modulus (YM) for both untreated and alkali treated biocomposites, but the treated particles presented a lower reduction. Further comparison was made via differential scanning calorimetry (DSC) and Fourier transform infrared spectroscopy (FTIR) to detect any changes in the samples.

scholarly journals Quality restoration of waste polyolefin plastic material through the dissolution-reprecipitation technique

2014 ◽  
Vol 20 (2) ◽  
pp. 163-170 ◽  
Author(s):  
Jasim Hadi ◽  
Faisal Najmuldeen ◽  
Iqbal Ahmed
Keyword(s):  
Mechanical Properties ◽  
Plastic Material ◽  
Polymer Concentration ◽  
Maximum Load ◽  
Recycling Process ◽  
Scanning Calorimetry ◽  
Experimental Conditions ◽  
Waste Plastic ◽  
Before And After ◽  
Waste Polymer

This study examines the restoration of waste plastic polymers based on LDPE, HDPE or PP through dissolution/reprecipitation. Experimental conditions of the recycling process, including type of solvent/non-solvent, original polymer concentration and dissolution temperature were optimized. Results revealed that by using the different prepared solvents/non-solvents at various ratios and temperatures, the polymer recovery was always greater than 94%. The FTIR spectra and the thermal properties (melting point and crystallinity) of the polymers before and after recycling were measured using Differential Scanning Calorimetry (DSC). Mechanical properties of the waste polymer before and after recycling were also measured. Besides small occasional deviations, the properties did not change. The tensile strength at maximum load was 7.1, 18.8, and 7.4 MPa for the recycled LDPE, HDPE and PP, respectively and 7.78, 18.54 and 7.86 MPa for the virgin polymer. For the waste, the strength was 6.2, 15.58 and 6.76 MPa.

scholarly journals Comparative thermal research on tetraazapentalene-derived heat-resistant energetic structures

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jing Zhou ◽  
Li Ding ◽  
Yong Zhu ◽  
Bozhou Wang ◽  
Xiangzhi Li ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Fourier Transform ◽  
Energetic Materials ◽  
Great Influence ◽  
Fourier Transform Infrared ◽  
Thermal Decomposition Mechanism ◽  
Scanning Calorimetry ◽  
In Situ Ftir Spectroscopy ◽  
Heat Resistant

AbstractOrganic inner salt structures are ideal backbones for heat-resistant energetic materials and systematic studies towards the thermal properties of energetic organic inner salt structures are crucial to their applications. Herein, we report a comparative thermal research of two energetic organic inner salts with different tetraazapentalene backbones. Detailed thermal decomposition behaviors and kinetics were investigated through differential scanning calorimetry and thermogravimetric analysis (DSC-TG) methods, showing that the thermal stability of the inner salts is higher than most of the traditional heat-resistant energetic materials. Further studies towards the thermal decomposition mechanism were carried out through condensed-phase thermolysis/Fourier-transform infrared (in-situ FTIR) spectroscopy and the combination of differential scanning calorimetry-thermogravimetry-mass spectrometry-Fourier-transform infrared spectroscopy (DSC-TG-MS-FTIR) techniques. The experiment and calculation results prove that the arrangement of the inner salt backbones has great influence on the thermal decompositions of the corresponding energetic materials. The weak N4-N5 bond in “y-” pattern tetraazapentalene backbone lead to early decomposition process and the “z-” pattern tetraazapentalene backbone exhibits more concentrated decomposition behaviors.

Research on compatibility and surface of high impact bio-based polyamide

2021 ◽  
pp. 095400832110055
Author(s):  
Yang Wang ◽  
Yuhui Zhang ◽  
Yuhan Xu ◽  
Xiucai Liu ◽  
Weihong Guo
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Differential Scanning Calorimetry ◽  
Crystallization Behavior ◽  
High Impact ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Scanning Electron

The super-tough bio-based nylon was prepared by melt extrusion. In order to improve the compatibility between bio-based nylon and elastomer, the elastomer POE was grafted with maleic anhydride. Scanning Electron Microscopy (SEM) and Thermogravimetric Analysis (TGA) were used to study the compatibility and micro-distribution between super-tough bio-based nylon and toughened elastomers. The results of mechanical strength experiments show that the 20% content of POE-g-MAH has the best toughening effect. After toughening, the toughness of the super-tough nylon was significantly improved. The notched impact strength was 88 kJ/m2 increasing by 1700%, which was in line with the industrial super-tough nylon. X-ray Diffraction (XRD) and Differential Scanning Calorimetry (DSC) were used to study the crystallization behavior of bio-based PA56, and the effect of bio-based PA56 with high crystallinity on mechanical properties was analyzed from the microstructure.

Physico Chemical Characterization of Nanofibrous Poly(Ε-Caprolactone) Electrospun Templates for Cell Adhesion

MRS Advances ◽  
2017 ◽  
Vol 2 (49) ◽  
pp. 2689-2694
Author(s):  
Karla A. Gaspar-Ovalle ◽  
Juan V. Cauich-Rodriguez ◽  
Armando Encinas
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Cell Adhesion ◽  
Tensile Modulus ◽  
Chemical Characterization ◽  
Mechanical Analysis ◽  
Scanning Calorimetry ◽  
Water Contact ◽  
Physico Chemical ◽  
Static Water

ABSTRACTNanofibrous mats of poly ε-caprolactone (PCL) were fabricated by electrospinning. The nanofiber structures were investigated and characterized by scanning electron microscope, differential scanning calorimetry, thermogravimetric analysis, dynamic mechanical analysis, static water-contact-angle analysis and mechanical properties. The results showed that the nanofibrous PCL is an ideal biopolymer for cell adhesion, owing to its biocompatibility, biodegradability, structural stability and mechanical properties. Differential scanning calorimetry results showed that the fibrous structure of PCL does not alter its crystallinity. Studies of the mechanical properties, wettability and degradability showed that the structure of the electrospun PCL improved the tensile modulus, tensile strength, wettability and biodegradability of the nanotemplates. To evaluate the nanofibrous structure of PCL on cell adhesion, osteoblasts cells were seeded on these templates. The results showed that both adhesion and proliferation of the cells is viable on these electrospun PCL membranes. Thus electrospinning is a relatively inexpensive and scalable manufacturing technique for submicron to nanometer diameter fibers, which can be of interest in the commodity industry.

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