scholarly journals Polyfluoroalkylated 2-ethoxymethylene- 3-oxo esters: synthesis and chemical properties overview

2017 ◽  
Vol 89 (8) ◽  
pp. 1209-1222 ◽  
Author(s):  
Victor I. Saloutin ◽  
Yulia S. Kudyakova ◽  
Marina V. Goryaeva ◽  
Yanina V. Burgart ◽  
Oleg N. Chupakhin
Keyword(s):  
Metal Complexes ◽  
Organic Synthesis ◽  
Bioactive Compounds ◽  
Chemical Properties ◽  
Building Blocks ◽  
High Reactivity ◽  
Organic Reagents ◽  
Fine Organic Synthesis ◽  
Fine Organic ◽  
And Chemical Properties

AbstractThe review focuses on the synthesis and chemical properties of polyfluoroalkylated 2-ethoxymethylene-3-oxo esters. The scope and peculiarities of their use as organic reagents in reactions with various N-, C-, O-, mono- and dinucleophiles are discussed in detail. The high reactivity of such derivatives is employed in the construction of enaminoketone, arene and heterocycle frameworks. Particular attention is paid to applications of these building blocks as chemicals for fine organic synthesis, bioactive compounds and metal complexes synthesis.

Synthesis, Characterization and Applications of Dicationic Ionic Liquids in Organic Synthesis

2020 ◽  
Vol 17 (4) ◽  
pp. 450-464
Author(s):  
Mohammad Javaherian ◽  
Seyyed Jafar Saghanezhad
Keyword(s):  
Ionic Liquids ◽  
Organic Synthesis ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Dicationic Ionic Liquids ◽  
Physical And Chemical ◽  
Reaction Media ◽  
And Chemical Properties

Dicationic ionic liquids are an emerging group of Ionic Liquids (ILs) that are currently receiving much attention as green reaction media and catalysts. Because of a great number of possible combinations of cations and anions, the physical and chemical properties of dicationic ionic liquids are more tunable and broader than monocationic ILs. Therefore, their unique properties have made them the target of many applied and fundamental researches. Actually, dicationic ionic liquids are more effective and rather fascinating than traditional monocationic ILs. So, due to greater versatility and diversity, their applications in organic synthesis have been extensively grown. In this review, we have focused on the synthesis, characterization and applications of dicationic ionic liquids, especially, in organic synthesis.

Deep purification of thionyl chloride for fine organic synthesis

1996 ◽  
Vol 30 (11) ◽  
pp. 720-721
Author(s):  
T. A. Taktashkina ◽  
I. P. Zaitseva ◽  
S. B. Germanov ◽  
F. V. Guss
Keyword(s):  
Organic Synthesis ◽  
Thionyl Chloride ◽  
Fine Organic Synthesis ◽  
Deep Purification ◽  
Fine Organic

Some organic syntheses with clay-supported reagents

Clay Minerals ◽  
1983 ◽  
Vol 18 (4) ◽  
pp. 437-445 ◽  
Author(s):  
A. Cornelis ◽  
P. Laszlo ◽  
P. Pennetreau
Keyword(s):  
Organic Synthesis ◽  
Quaternary Ammonium ◽  
Phase Transfer ◽  
Ferric Nitrate ◽  
Organic Syntheses ◽  
Carbonyl Derivatives ◽  
Fine Organic Synthesis ◽  
Fine Organic

AbstractSome uses of clay-supported reagents in fine organic synthesis are discussed, in particular the catalysis of the phase-transfer preparation of formaldehyde acetals by quaternary ammonium montmorillonites. The preparation and some applications of clay-supported ferric nitrate, a new reagent which oxidizes alcohols into carbonyl derivatives, couples thiols into disulphides, nitrates phenols, and oxidatively couples pyrrole and benzaldehyde into tetra-phenylporphyrin, are also described

Levoglucosenone: the properties, reactions, and use in fine organic synthesis

1994 ◽  
Vol 63 (10) ◽  
pp. 869-882 ◽  
Author(s):  
Mansur S Miftakhov ◽  
Farid A Valeev ◽  
Irina N Gaisina
Keyword(s):  
Organic Synthesis ◽  
Fine Organic Synthesis ◽  
Fine Organic

Microchannel systems for fine organic synthesis

2016 ◽  
Vol 85 (2) ◽  
pp. 139-155 ◽  
Author(s):  
L L Makarshin ◽  
Z P Pai ◽  
V N Parmon
Keyword(s):  
Organic Synthesis ◽  
Fine Organic Synthesis ◽  
Fine Organic
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