Mathematical model involving chemical reaction and mass transfer for the ozonation of dimethyl phthalate in water in a bubble column reactor

2017 ◽  
Vol 20 (1) ◽  
Author(s):  
Jianbing Wang ◽  
Zhilin Xia ◽  
Zuhai Cao ◽  
Shaoxia Yang ◽  
Wanpeng Zhu

AbstractThis research investigated the establishment of a mathematical model for the ozonation of dimethyl phthalate (DMP) through the analysis of the mass transfer and reactions in a semi-batch bubble column reactor. Negative step tracer experiments were conducted with ozone as a tracer, which indicated that the gas phase is perfectly well mixed at the gas flow rate of 400 mL/min. Based on the results from ozone absorption experiments the mass transfer coefficient of ozone was determined to be 0.0054 s

2020 ◽  
Vol 13 (1) ◽  
pp. 67-73
Author(s):  
Elaf Thamera ◽  
Salih Abduljabbar Rushdi

In this work, an absorption technology   was used actually to investigation the  mass transfer coefficient of carbon dioxide from a gaseous mixture (air, carbon dioxide) in  blended solution Monoethanolamine (MEA) and Diethanolamine (DEA)  in a bubble column reactor (BCR) . The bubble column reactor(BCR) was made of Plexiglas with 1.5 m high and 0.1 m inside diameter. The overall mass transfer coefficient (  was evaluated at different operating conditions , gas flow rate, air Flow rate ,liquid flow rate .Where the gas flow rates were 10, 15 and 20 L /min ,  air flow rate 100,150 and 200 L/h ,and liquid flow rate 5 ,10,15 L /min . This experiment  by   using  continuous   process with helping centrifugal  pump  . High-performance gas chromatographic (GC) was performed to evaluate  loading during absorption experiment . The  experimental results have shown that the   loading in range of  0.581-1.367 (mol  /mole amine),and the maximum value of overall mass transfer coefficient ( KG) was 0.04 S-1 .


REAKTOR ◽  
2019 ◽  
Vol 18 (04) ◽  
pp. 177 ◽  
Author(s):  
Aji Prasetyaningrum ◽  
Dyah Arum Kusumaningtyas ◽  
Purbo Suseno ◽  
Ratnawati Ratnawati

This research was conducted to calculate the mass transfer coefficient value for ozonation reaction of κ-carrageenan solution in the bubble column reactor. Ozone gas was produced using ozone generator type corona discharge. In this study, operating conditions were regulated at ozone gas flow rate 2- 5 L min-1, pH 4-10, and temperature 29 ± 1 oC. Samples were tested every 5 minutes to determine the dissolved ozone concentration. The results showed that dissolved ozone concentrations increased with increasing ozonation time and ozone gas flow rate. However, a very high gas flow rate can increase turbulence so that the mass transfer coefficient (kLa) value decreased. In alkaline conditions, the formation of free radicals (HO*) increases so that the amount of dissolved ozone decreases. The kLa value of ozone gas in κ-carrageenan solution is slightly lower than the kLa value of the ozone gas in the water. The results of this study indicate that (kLa) ozone gas in water is 0.131 / minute while the value (kLa) in κ-carrageenan solution is 0.128 / minute.


2010 ◽  
Vol 4 (7) ◽  
Author(s):  
D. Devakumar ◽  
K. Saravanan ◽  
T. Kannadasan ◽  
B. Meenakshipriya

Sign in / Sign up

Export Citation Format

Share Document