Novel paper sizing agents from renewables. Part 1: Preparation of a paper sizing agent derived from natural plant oils

Holzforschung ◽  
2011 ◽  
Vol 65 (1) ◽  
pp. 3-11 ◽  
Author(s):  
Elisabeth Lackinger ◽  
Leo Schmid ◽  
Jürgen Sartori ◽  
Akira Isogai ◽  
Antje Potthast ◽  
...  
Keyword(s):  
Oleic Acid ◽  
Fatty Acid ◽  
Maleic Anhydride ◽  
Plant Oils ◽  
Natural Plant ◽  
Natural Oils ◽  
Paper Sizing ◽  
Sizing Agents ◽  
Product Viscosity ◽  
Increased Pressure

Abstract Natural oils derived from linseed, rapeseed, soybean, and a special breed of sunflower were tested for the production of maleated fatty oils for paper sizing in the ene-reaction with maleic anhydride. All these maleated oils were subjected to a conventional sizing test proving their ability to hydrophobize handsheets. Natural oils having only monounsaturated fatty acid residues (oleic acid) in the triglycerides worked best by having lower product viscosity and higher yields. The optimized production procedure employs antioxidant addition, an increased maleic anhydride:triglyceride ratio of 4:1, as well as increased pressure to reduce undesired polymeric byproducts and to increase yield.

STUDY OF PHYSICAL AND CHEMICAL COMPOSITION AND SENSORY PROPERTIES OF MIX OILS DERIVED FROM FLAX SEEDS AND THISTLE SPOTTY AS INGREDIENT OF COSMETICS

2019 ◽  
Author(s):  
Т.В. ПЕЛИПЕНКО ◽  
С.К. МУСТАФАЕВ ◽  
М.Р. БРУЯКА
Keyword(s):  
Fatty Acids ◽  
Fatty Acid Composition ◽  
Oleic Acid ◽  
Fatty Acid ◽  
Acid Composition ◽  
Linseed Oil ◽  
Sensory Properties ◽  
Biologically Active ◽  
Natural Oils ◽  
Flax Seeds

Разработана композиция из натуральных масел из семян льна и расторопши пятнистой. Жирнокислотный состав смеси масел обеспечивает нормальное функционирование и регенерацию кожи и достаточно стабилен к окислению. Масла из семян льна высоколиноленового типа и расторопши пятнистой получены методом холодного отжима на лабораторном прессе FarmetDUO PF3. Выполнены расчеты, определяющие концентрацию исходных масел в смеси с заданным составом жирных кислот, и составлены образцы смеси масел: образец 1 при соотношении 6 : 3 жирных кислот 1 : 1 содержал 33 масла расторопши пятнистой и 67 льняного масла образец 2 при соотношении 6 : 3 жирных кислот 4 : 1 соответственно содержал 27 льняного и 73 масла расторопши. Установлено, что фактическое соотношение жирных кислот 6 : 3 в образце 1 соответственно составило 0,97 : 1, в образце 2 3,8 : 1, что близко к оптимальному. Доля олеиновой кислоты (9) в смеси масел, повышающей их устойчивость к окислению, составила 25 от общего количества жирных кислот. Образцы смеси масел характеризуются средней растекаемостью, невысоким поверхностным натяжением и низкой вязкостью. Введение смеси масел из семян льна и расторопши пятнистой с заданным жирнокислотным составом в рецептуры косметических средств позволит получить биологически активные продукты кремы для сухой кожи, а также питательные кремы с высокими сенсорными свойствами. The composition of natural oils of flax seeds and thistle spotty is developed. The fatty acid composition of the oil mix ensures the normal functioning and regeneration of the skin and is sufficiently stable to oxidation. Samples of the oil from the seeds of the flax with high oleic acid and thistle spotty oil is obtained by cold pressing in a laboratory press FarmetDUO PF3. Calculations determining the concentration of the starting oils in a mixture with given of composition of fatty acids were carried. Samples of the mix of oils composed of: sample 1 when the ratio of 6 : 3 fatty acids of 1 : 1 respectively consists of 33 oil thistle spotty and 67 linseed oil sample 2 when the ratio 6 : 3 fatty acids is 4 : 1 respectively consists of 27 linen 73 oil thistle spotty. It was found that the actual ratio of fatty acids 6: 3 in sample 1 was 0,97 : 1 respectively, in sample 2 3,8 : 1, which is close to optimal. The share of oleic acid (9) in the mix of oils, which increases their resistance to oxidation, was 25 of the total amount of fatty acids. Oil mixture samples are characterized by medium spreadability, low surface tension and low viscosity. The introduction of a mix of flax seed oil and thistle spotty oil with a given fatty acid composition in the formulation of cosmetics will allow to obtain biologically active products creams for dry skin, as well as nourishing creams with high sensory properties.

Novel paper sizing agents based on renewables. Part 5: characterization of maleated oleates by ozonolysis

Holzforschung ◽  
2012 ◽  
Vol 66 (1) ◽  
Author(s):  
Elisabeth Lackinger ◽  
Jürgen Sartori ◽  
Antje Potthast ◽  
Thomas Rosenau
Keyword(s):  
Oleic Acid ◽  
Double Bond ◽  
Structural Analysis ◽  
Molecular Fragments ◽  
Acid Moiety ◽  
High Oleic Sunflower Oil ◽  
High Oleic ◽  
Paper Sizing ◽  
Sizing Agents

Abstract Maleated high oleic sunflower oil (maleated SOHO, MSOHO) is a promising substitute for alkenyl succinic anhydrides (ASA) that are widely used as sizing agents for paper. The part of the MSOHO molecule that is believed to be responsible for adhesion of the molecule onto cellulose, i.e., the maleated oleic acid moiety, was separately prepared and analytically characterized. Structural analysis was completed by studies of the molecular fragments obtained upon ozonolysis. The interesting question of whether there was a preferential reactivity during the ene-reaction of maleic anhydride with oleates was answered in a way that the newly formed double bond was placed to either side with no apparent selectivity.

scholarly journals The effect of fatty acid profile on the stability of non-traditional and traditional plant oils

10.5219/1064 ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 744-750
Author(s):  
Josef Soukup ◽  
Lenka Kouřimská
Keyword(s):  
Fatty Acids ◽  
Oleic Acid ◽  
Fatty Acid ◽  
Sunflower Oil ◽  
Plant Oils ◽  
Weight Changes ◽  
High Oleic ◽  
Peroxide Values ◽  
Sunflower Oils ◽  
The Stability

The effect of fatty acid composition on the autoxidation of selected plant oils (rapeseed (canola) oil, corn oil, frying oil, grapeseed oil, pomace olive oil, rice bran oil, sunflower oil and high oleic sunflower oil) during their storage was studied. Oils were purchased in retail food stores. Oxidative stability of plant oils was monitored during the storage under the Schaal test conditions at 60 °C in 100 mL beakers and the dark for 40 days. The weight changes, the peroxide and acid values were analysed during the storage. Changes in the composition of fatty acids were analyzed by the gas chromatography-mass spectrometry. The results obtained by monitoring the weight changes of oils correlated with their peroxide values. The induction period in case of grapeseed and sunflower oils was 27 and 28 days respectively. The induction period for frying and rapeseed oils were around 35 days. The remaining four oils had induction periods over 40 days. The acid values at the end of experiment correspond to both the relative weight gain and the the peroxide values. The stability of oils depended mainly on the degree of fatty acids unsaturation. A strong negative correlation between oleic acid content and oil stability expressed as the peroxide value was found. The significant positive correlation was found in case of linoleic acid. The relative content of polyunsaturated fatty acids decreased during the storage while the content of saturated and monounsaturated fatty acids increased. The highest relative increase in oleic acid was found at the least stable oils, grapeseed and sunflower oils, by 37.5% and 25.3% respectively. The initial content of free fatty acids monitored by the acid value did not affect the oxidation rate. With consideration to all monitored parameters the grapeseed and the sunflower oils were the least stable. The most stable ones were olive pomace and high oleic sunflower oils.

Influence of Polymer Charge, Temperature, and Surfactants on Surface Sizing of Liner and Greaseproof Paper With Hydrophobically Modified Starch

TAPPI Journal ◽  
2009 ◽  
Vol 8 (2) ◽  
pp. 33-38 ◽  
Author(s):  
ANNA JONHED ◽  
LARS JÄRNSTRÖM
Keyword(s):  
Phase Separation ◽  
Contact Angles ◽  
Low Ph ◽  
Hydrophobically Modified ◽  
Paper Sizing ◽  
Surface Sizing ◽  
Separation Temperature ◽  
Hydrophobic Nature ◽  
Sizing Agents ◽  
Charge Temperature

The aim of this study was to investigate the properties of hydrophobically modified (HM) quaterna-ry ammonium starch ethers for paper sizing. These starches possess temperature-responsive properties; that is, gelation or phase separation occurs at a certain temperature upon cooling. This insolubility of the HM starches in water at room temperature improved their performance as sizing agents. The contact angles for water on sized liner were substantially larger than on unsized liner. When the application temperature was well above the critical phase-separation temperature, larger contact angles were obtained for liner independently of pH compared with those at the lower application temperature. Cobb60 values for liner decreased upon surface sizing, with a low pH and high application temperature giving lower water penetration. Contact angles on greaseproof paper decreased upon sur-face sizing as compared to unsized greaseproof paper, independently of pH and temperature. Greaseproof paper showed no great difference between unsized substrates and substrates sized with HM starch at different pH. This is probably due to the already hydrophobic nature of greaseproof paper. However, the Cobb60 values increased at low pH and low application temperature. Surfactants were added to investigate how they affect the sized surface. Addition of surfactant reduces the contact angles, in spite of indications of complex formation.

Determination of fatty acid content in some edible insects of Mexico

2016 ◽  
Vol 2 (1) ◽  
pp. 37-42 ◽  
Author(s):  
J.M. Pino Moreno ◽  
A. Ganguly
Keyword(s):  
Oleic Acid ◽  
Fatty Acid ◽  
Acid Content ◽  
Periplaneta Americana ◽  
Fatty Acid Content ◽  
Capric Acid ◽  
Caproic Acid ◽  
Insect Species ◽  
Edible Insects

In the present paper we have determined the fatty acid content of some edible insects of Mexico. A comparative analysis of the insect species studied in this research showed that caproic acid was present in a minimal proportion which ranged between 0.01 for Periplaneta americana (nymphs) and 0.06 (g/100 g, dry basis) for Euschistus strenuus. The highest proportion of caprilic acid (0.09) was found in Tenebrio molitor (adults). Atta sp. had the highest amount of capric acid (0.26). Polistes sp. was found to be rich in lauric acid (0.77) and for myristic acid it had the highest content (5.64). Dactylopius sp. and E. strenuus were rich in palmitic acid (14.89). Euschistus taxcoensis had the highest quantity of palmitoleic acid (12.06). Llaveia axin exhibited the highest quantity of stearic acid (22.75). Polistes sp. was found to be rich in oleic acid (38.28). The highest quantity of linoleic acid was observed in T. molitor (larvae) (10.89), and in L. axin the highest content of linolenic acid (7.82) was obtained. A comparison between the species under the present investigation revealed that, in general, the insects are poor in caproic, caprilic, capric, lauric, myristic, palmitoleic and linolenic acids, because the quantities were either minimal or could not be detected at all. They had moderate quantities of stearic, palmitic and linoleic acids and had high quantities of oleic acid. Finally it was concluded that although a particular insect species is unable to fulfil the total fatty acid need for a human, if consumed in combination they could definitely be able to supply a good amount of this highly valued nutrient.

scholarly journals TILLING-by-Sequencing+ Reveals the Role of Novel Fatty Acid Desaturases (GmFAD2-2s) in Increasing Soybean Seed Oleic Acid Content

Cells ◽  
2021 ◽  
Vol 10 (5) ◽  
pp. 1245
Author(s):  
Naoufal Lakhssassi ◽  
Valéria Stefania Lopes-Caitar ◽  
Dounya Knizia ◽  
Mallory A. Cullen ◽  
Oussama Badad ◽  
...  
Keyword(s):  
Oleic Acid ◽  
Fatty Acid ◽  
Acid Content ◽  
Edible Oils ◽  
Fatty Acid Desaturase ◽  
Soybean Seed ◽  
Oleic Acid Content ◽  
Fatty Acid Production ◽  
Tilling By Sequencing

Soybean is the second largest source of oil worldwide. Developing soybean varieties with high levels of oleic acid is a primary goal of the soybean breeders and industry. Edible oils containing high level of oleic acid and low level of linoleic acid are considered with higher oxidative stability and can be used as a natural antioxidant in food stability. All developed high oleic acid soybeans carry two alleles; GmFAD2-1A and GmFAD2-1B. However, when planted in cold soil, a possible reduction in seed germination was reported when high seed oleic acid derived from GmFAD2-1 alleles were used. Besides the soybean fatty acid desaturase (GmFAD2-1) subfamily, the GmFAD2-2 subfamily is composed of five members, including GmFAD2-2A, GmFAD2-2B, GmFAD2-2C, GmFAD2-2D, and GmFAD2-2E. Segmental duplication of GmFAD2-1A/GmFAD2-1B, GmFAD2-2A/GmFAD2-2C, GmFAD2-2A/GmFAD2-2D, and GmFAD2-2D/GmFAD2-2C have occurred about 10.65, 27.04, 100.81, and 106.55 Mya, respectively. Using TILLING-by-Sequencing+ technology, we successfully identified 12, 8, 10, 9, and 19 EMS mutants at the GmFAD2-2A, GmFAD2-2B, GmFAD2-2C, GmFAD2-2D, and GmFAD2-2E genes, respectively. Functional analyses of newly identified mutants revealed unprecedented role of the five GmFAD2-2A, GmFAD2-2B, GmFAD2-2C, GmFAD2-2D, and GmFAD2-2E members in controlling the seed oleic acid content. Most importantly, unlike GmFAD2-1 members, subcellular localization revealed that members of the GmFAD2-2 subfamily showed a cytoplasmic localization, which may suggest the presence of an alternative fatty acid desaturase pathway in soybean for converting oleic acid content without substantially altering the traditional plastidial/ER fatty acid production.

scholarly journals GC-MS and HPLC-DAD analysis of fatty acid profile and functional phytochemicals in fifty cold-pressed plant oils in Thailand

Heliyon ◽  
2021 ◽  
Vol 7 (2) ◽  
pp. e06304
Author(s):  
Jitkunya Yuenyong ◽  
Piramon Pokkanta ◽  
Nutthatida Phuangsaijai ◽  
Sila Kittiwachana ◽  
Sugunya Mahatheeranont ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Fatty Acid Profile ◽  
Plant Oils ◽  
Cold Pressed

scholarly journals Effects of exogenous lipids and cold acclimation on lycopene production and fatty acid composition in Blakeslea trispora

AMB Express ◽  
2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Feng Lingran ◽  
Wang Qiang ◽  
Yu Xiaobin ◽  
Fred Kwame
Keyword(s):  
Fatty Acid Composition ◽  
Fatty Acid ◽  
Acid Composition ◽  
Neutral Lipids ◽  
Feedback Regulation ◽  
Total Content ◽  
Blakeslea Trispora ◽  
Plant Oils ◽  
Intracellular Lipids ◽  
Lycopene Production

Abstract Exogenous lipids serving as stimulators to improve lycopene production in Blakeslea trispora have been widely reported. However, the selection basis of exogenous lipids and their effects on intracellular lipids are not very clear. In this study, five plant oils with different fatty acid compositions were selected to investigate their effects on lycopene production, fatty acid composition and the desaturation degree of intracellular lipids. Among the oils, soybean oil, with a fatty acid composition similar to that of mycelium, exhibited the best stimulating effect on lycopene formation (improvement of 82.1%). The plant oils enhanced the total content of intracellular lipids and the desaturation degree of reserve lipids due to the alteration of fatty acid composition, especially in neutral lipids. Lycopene production was increased with the improved desaturation degree of intracellular lipids, which may be attributed to the enhancement of storage capacity for lycopene in storage lipid, thus reducing the feedback regulation of free lycopene. In addition, the increase of the desaturation degree of reserve lipids through temperature-changing fermentation also enhanced lycopene production. The present study could serve as a basis for a better understanding of the relationship between the fatty acid composition of reserve lipids and lycopene production.

Fatty Acid Data and Crop Surveys Indicate Sources of Red Sunflower Seed Weevil (Coleoptera: Curculionidae), Populations and Suggest Strategies for Management

2020 ◽  
Author(s):  
Jarrad R Prasifka ◽  
Beth Ferguson ◽  
James V Anderson
Keyword(s):  
Fatty Acids ◽  
Oleic Acid ◽  
Fatty Acid ◽  
Sunflower Seed ◽  
Cultural Practices ◽  
High Oleic ◽  
Fatty Acid Data ◽  
Smicronyx Fulvus ◽  
Combined Data ◽  
Fatty Acid Compositions

Abstract The red sunflower seed weevil, Smicronyx fulvus L., is a univoltine seed-feeding pest of cultivated sunflower, Helianthus annuus L. Artificial infestations of S. fulvus onto sunflowers with traditional (<25% oleic acid), mid-oleic (55–75%), or high oleic (>80%) fatty acid profiles were used to test if fatty acids could be used as natural markers to estimate the proportion of weevils developing on oilseed sunflowers rather than wild Helianthus spp. and confection (non-oil) types. Oleic acid (%) in S. fulvus confirmed the fatty acid compositions of mature larvae and weevil adults reflected their diets, making primary (oleic or linoleic) fatty acids feasible as natural markers for this crop-insect combination. Oleic acid in wild S. fulvus populations in North Dakota suggests at least 84 and 90% of adults originated from mid-oleic or high oleic sunflower hybrids in 2017 and 2018, respectively. Surveys in 2017 (n = 156 fields) and 2019 (n = 120 fields) extended information provided by S. fulvus fatty acid data; no significant spatial patterns of S. fulvus damage were detected in samples, damage to oilseed sunflowers was greater than confection (non-oil) types, and the majority of damage occurred in ≈10% of surveyed fields. Combined, data suggest a few unmanaged or mismanaged oilseed sunflower fields are responsible for producing most S. fulvus in an area. Improved management seems possible with a combination of grower education and expanded use of non-insecticidal tactics, including cultural practices and S. fulvus-resistant hybrids.

scholarly journals Combined thermal analysis of plant oils

2021 ◽  
Author(s):  
Kinga Tamási ◽  
Kálmán Marossy
Keyword(s):  
Thermal Analysis ◽  
Differential Scanning Calorimetry ◽  
Low Temperature ◽  
Glassy State ◽  
Mechanical Analysis ◽  
Plant Oils ◽  
Scanning Calorimetry ◽  
Natural Plant ◽  
The Moment ◽  
Current Reversal

AbstractThe paper deals with the study of seven selected natural plant oils. Differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and thermally stimulated discharge (TSD) methods were used. It has been found that most of the oils tested are in a glassy state at low temperature and have multiple transitions in the low temperature range. DSC shows complex melting-like processes or glass transition. For both DMA and TSD, the scaffold supportive method was used and found as a suitable one. DMA and TSD proved more sensitive than DSC and revealed at least two transitions between − 120 and − 40 °C. In the case of three oils (argan, avocado and sunflower), current reversal was observed by TSD; this symptom cannot be fully explained at the moment.

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