The oxidation of secondary alcohols by dimethyldioxirane: re-examination of kinetic isotope effects

2010 ◽  
Vol 16 (4-6) ◽  
Author(s):  
Alfons L. Baumstark ◽  
Pedro C. Vasquez ◽  
Mark Cunningham ◽  
Pamela M. Leggett-Robinson
Keyword(s):  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Secondary Alcohols ◽  
Kinetic Isotope

scholarly journals Kinetic Isotope Effects in the Chromium(VI) Oxidation of Bicyclic Alcohols

1999 ◽  
Vol 23 (2) ◽  
pp. 146-147
Author(s):  
J. Hodge Markgraf ◽  
Jordan S. Dubow ◽  
Jessica A. Charland ◽  
Elliott H. Sohn
Keyword(s):  
Rate Constants ◽  
Acidic Solution ◽  
Isotope Effects ◽  
Activation Parameters ◽  
Kinetic Isotope Effects ◽  
Secondary Alcohols ◽  
First Order ◽  
Chromium Vi ◽  
Kinetic Isotope ◽  
Pseudo First Order

Pseudo first-order rate constants are determined for the oxidation of a series of secondary alcohols and their monodeutero analogues by ammonium chromate in aqueous acidic solution at several temperatures; the relative rates and activation parameters are consistent with a cyclic, symmetrical transition state.

Theoretical Simulations of Heavy-Atom Kinetic Isotope Effects in Aliphatic Claisen Rearrangement

2020 ◽  
Vol 124 (51) ◽  
pp. 10678-10686
Author(s):  
Yuqing Xu ◽  
Kin-Yiu Wong ◽  
Meishan Wang ◽  
Desheng Liu ◽  
Wenkai Zhao ◽  
...  
Keyword(s):  
Claisen Rearrangement ◽  
Isotope Effects ◽  
Heavy Atom ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope ◽  
Theoretical Simulations

Direct dynamics calculations of reaction rate and kinetic isotope effects in enzyme catalysed reactions

2002 ◽  
Vol 122 ◽  
pp. 223-242 ◽  
Author(s):  
Gary Tresadern ◽  
Sara Nunez ◽  
Paul F. Faulder ◽  
Hong Wang ◽  
Ian H. Hillier ◽  
...  
Keyword(s):  
Reaction Rate ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Direct Dynamics ◽  
Kinetic Isotope

Interpretation of Transient-State Kinetic Isotope Effects†

Biochemistry ◽  
1996 ◽  
Vol 35 (1) ◽  
pp. 83-88 ◽  
Author(s):  
Harvey F. Fisher ◽  
Swapan K. Saha
Keyword(s):  
Isotope Effects ◽  
Transient State ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope ◽  
State Kinetic
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