scholarly journals Supramolecular poly(L-lactide)s containing terpyridine metal complexes

e-Polymers ◽  
2002 ◽  
Vol 2 (1) ◽  
Author(s):  
Marcel Heller ◽  
Ulrich S. Schubert

AbstractChiral poly(L-lactide)s end-capped with a novel terpyridine ligand are synthesized by a controlled coordinative polymerization procedure. The resulting well-characterized macroligands can be complexed under phase-transfer conditions with iron(II) ions to form well-defined supramolecular poly(L-lactide) complexes. The outstanding stability of such coordinative polymers enables the full characterization by gel permeation chromatography (GPC) and MALDI-TOF mass spectrometry. In addition, in-line diode array UV-Vis spectroscopy coupled to GPC was carried out to verify the formation of the poly(ester) complexes.

Author(s):  
Yana E. Philippova ◽  
Mikhail K. Islyaikin ◽  
Tomas Torres

A monoiododi(tert-butyl)substituted macroheterocyclic compound of ABAB[Formula: see text]AB[Formula: see text]-type 4 was obtained, as a mixture of regioisomers, by statistical condensation of 4-iodophthalonitrile, 4-tert-butylphthalonitrile and 2,5-diamino-1,3,4-thiadiazole in a molar ratio 1:2:3 respectively. The structure of the functionalized hemihexaphyrazine was confirmed by MALDI-TOF mass spectrometry, IR and UV-vis spectroscopy.


2021 ◽  
pp. 103835
Author(s):  
Sébastien Bridel ◽  
Stephen C. Watts ◽  
Louise M. Judd ◽  
Taylor Harshegyi ◽  
Virginie Passet ◽  
...  

2001 ◽  
Vol 34 (7) ◽  
pp. 2389-2393 ◽  
Author(s):  
Weihua Ming ◽  
Xianwen Lou ◽  
Robert D. van de Grampel ◽  
Joost L. J. van Dongen ◽  
Rob van der Linde

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