The influence of multi-walled carbon nanotubes on various properties of cementitious materials

2016 ◽  
Author(s):  
Lingshi Meng
2020 ◽  
Vol 9 (1) ◽  
pp. 93-104
Author(s):  
Mingrui Du ◽  
Yuan Gao ◽  
Guansheng Han ◽  
Luan Li ◽  
Hongwen Jing

AbstractMulti-walled carbon nanotubes (MWCNTs) have been added in the plain cementitious materials to manufacture composites with the higher mechanical properties and smart behavior. The uniform distributions of MWCNTs is critical to obtain the desired enhancing effect, which, however, is challenged by the high ionic strength of the cement pore solution. Here, the effects of methylcellulose (MC) on stabilizing the dispersion of MWCNTs in the simulated cement pore solution and the viscosity of MWCNT suspensions werestudied. Further observations on the distributions of MWCNTs in the ternary cementitious composites were conducted. The results showed that MC forms a membranous envelope surrounding MWCNTs, which inhibits the adsorption of cations and maintains the steric repulsion between MWCNTs; thus, the stability of MWCNT dispersion in cement-based composites is improved. MC can also work as a viscosity adjuster that retards the Brownian mobility of MWCNTs, reducing their re-agglomerate within a period. MC with an addition ratio of 0.018 wt.% is suggested to achieve the optimum dispersion stabilizing effect. The findings here provide a way for stabilizing the other dispersed nano-additives in the cementitious composites.


2016 ◽  
Vol 711 ◽  
pp. 232-240 ◽  
Author(s):  
Ling Shi Meng ◽  
Christopher K.Y. Leung ◽  
Geng Ying Li

This paper studies the effects of multi-walled carbon nanotubes (MWCNTs) on the mechanical properties and durability of polymer latex-modified cement mortar. Latex-modified cementitious materials possess many advantages. However, reduction of mechanical properties due to the introduction of an amorphous structure within the cement composite has limited its application. In this study, multi-walled carbon nanotubes functionalised with carboxyl group (MWCNTs-COOH), ranging from 0% to 0.15% by weight, are added into mortar modified with 0.6 wt.% polyvinyl alcohol (PVA) latex. Mechanical properties including compressive strength and flexural strength are measured. Water absorption test and rapid chloride diffusion test are performed to assess durability performance. Results indicate considerable increase of compressive strength and flexural strength, as well as improvement in durability, by the addition of MWCNTs-COOH. With Scanning Electron Microscopy conducted on both the latex solution and cement composite, the microstructural changes resulted from MWCNT addition are revealed.


Acta Naturae ◽  
2011 ◽  
Vol 3 (1) ◽  
pp. 99-106 ◽  
Author(s):  
E A Smirnova ◽  
A A Gusev ◽  
O N Zaitseva ◽  
E M Lazareva ◽  
G E Onishchenko ◽  
...  

2003 ◽  
Vol 772 ◽  
Author(s):  
T. Seeger ◽  
G. de la Fuente ◽  
W.K. Maser ◽  
A.M. Benito ◽  
A. Righi ◽  
...  

AbstractCarbon nanotubes (CNT) are interesting candidates for the reinforcement in robust composites and for conducting fillers in polymers due to their fascinating electronic and mechanical properties. For the first time, we report the incorporation of multi walled carbon nanotubes (MWNTs) into silica-glass surfaces by means of partial surface-melting caused by a continuous wave Nd:YAG laser. MWNTs were detected being well incorporated in the silica-surface. The composites are characterized using scanning electron microscopy (SEM) and Raman-spectroscopy. A model for the composite-formation is proposed based on heatabsorption by MWNTs and a partial melting of the silica-surface.


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