scholarly journals Ultrastructure and chemical composition of the proboscis hooks of Acanthocephalus lucii (Muller, 1776) (Acanthocephala: Palaeacanthocephala) using X-ray elemental analysis

2014 ◽  
Vol 61 (6) ◽  
pp. 549-557 ◽  
Author(s):  
Timea Brazova ◽  
Larisa G. Poddubnaya ◽  
Noemi Ramirez Miss ◽  
Vladimira Hanzelova
Keyword(s):  
Chemical Composition ◽  
Elemental Analysis ◽  
X Ray ◽  
Acanthocephalus Lucii

ANALYSIS OF COMPOSITION AND STRUCTURE OF MAMMOTH TUSK THE MAMMUTHUS PRIMIGENIUS BY THERMOGRAMMETRIC AND X-RAY SPECTROSCOPY

2021 ◽  
Vol 0 (2) ◽  
pp. 9-12
Author(s):  
T.M. Solovev ◽  
◽  
E.S. Petukhova ◽  
G.V. Botvin ◽  
T.A. Isakova ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Phase Transformation ◽  
Chemical Composition ◽  
Elemental Analysis ◽  
Wide Temperature Range ◽  
Magnesium Ions ◽  
Spectroscopy Analysis ◽  
Mammuthus Primigenius ◽  
X Ray ◽  
Composition And Structure

The article represents the results of the research of the chemical composition of mammoth tusk Mammuthus Primigenius and its phase transformation using thermogrammetric (TGA) and X-ray spectroscopy analysis (XRD). The elemental analysis of mammoth tusk showed, that besides basic elements in the structure of hydroxyapatite (HAP) contains magnesium ions, i.e. hydroxyapatite in the studied samples is presented in magnesium-substituted form. The thermal decomposition of mammoth tusk components occurs in wide temperature range with a change in the structure of the mineral part from hydroxyapatite to whitlockite. It was found that this process is caused by the presence of magnesium ions.

Initial elemental analysis by X-ray crystallography

2011 ◽  
Vol 44 (3) ◽  
pp. 625-627 ◽  
Author(s):  
Jianglin Feng
Keyword(s):  
Chemical Composition ◽  
Elemental Analysis ◽  
X Ray Diffraction ◽  
Fourier Synthesis ◽  
X Ray ◽  
X Ray Crystallography ◽  
Structure Factors ◽  
Isotropic Displacement Parameter ◽  
Initial Identification ◽  
Scattering Factor

A method is proposed for the initial identification of non-hydrogen atomic species in a crystal from X-ray diffraction intensities when the chemical composition is not available. When atom positions are determined, a portion of the scattering factor curve for each atom can be obtained by Fourier synthesis with reflections from concentric shells. From these curves, the atomic number and the isotropic displacement parameter for all non-H atoms, and the scaling constant of the structure factors, can be approximately determined.

Signal/Noise Ratio and Elemental Detectivity by Eels

1982 ◽  
Vol 40 ◽  
pp. 488-489
Author(s):  
R. F. Egerton
Keyword(s):  
Energy Loss ◽  
Electron Energy ◽  
Elemental Analysis ◽  
Electron Energy Loss Spectroscopy ◽  
Emission Spectroscopy ◽  
X Ray ◽  
Signal Noise ◽  
Characteristic Signal ◽  
Noise Ratio ◽  
Electron Energy Loss

An important parameter governing the sensitivity and accuracy of elemental analysis by electron energy-loss spectroscopy (EELS) or by X-ray emission spectroscopy is the signal/noise ratio of the characteristic signal.

Preparation and properties of green rust type substances

1987 ◽  
Vol 52 (1) ◽  
pp. 93-102 ◽  
Author(s):  
Jaroslav Vinš ◽  
Jan Šubrt ◽  
Vladimír Zapletal ◽  
František Hanousek
Keyword(s):  
Chemical Composition ◽  
Electron Diffraction ◽  
Green Rust ◽  
X Ray ◽  
Synthesis Conditions ◽  
Diffraction Patterns

A method has been worked out for the reproducible preparation of Green Rust substances involving SO42-, Cl-, Br-, and I- anions. The chemical composition of the substances prepared has been followed in dependence on the synthesis conditions. The powder X-ray and electron diffraction patterns and infrared and Moessbauer spectra have been measured and discussed.

scholarly journals 4-vinylpyridine derivatives: Protonation, methylation and silver(I) coordination chemistry

2021 ◽  
pp. 174751982198965
Author(s):  
Guoqi Zhang
Keyword(s):  
Mass Spectrometry ◽  
Schiff Base ◽  
Coordination Chemistry ◽  
Elemental Analysis ◽  
Silver Complex ◽  
Spectroscopic Techniques ◽  
X Ray ◽  
X Ray Crystallography ◽  
Pyridine Moiety ◽  
New Compounds

( E)-4-[2-(Pyridin-4-yl)vinyl]benzaldehyde, containing both a 4-vinylpyridine and an aldehyde functionality, is utilized to develop new, highly conjugated chalcone compounds and a bis-Schiff base azine compound. The chalcone-containing compounds are further explored for their protonation, methylation and silver(I) coordination chemistry using the pyridine moiety. In parallel, a cyano-containing analogue, ( E)-4-[2-(pyridin-4-yl)vinyl]benzonitrile is also synthesized and studied for its silver(I) coordination chemistry. These new compounds are fully characterized by mass spectrometry, elemental analysis and spectroscopic techniques. The methylated product of ( E)-1-(9-anthryl)-3-{4-[2-(pyridin-4-yl)vinyl]phenyl}prop-2-en-1-one and a silver complex of ( E)-4-[2-(pyridin-4-yl)vinyl]benzonitrile are structurally determined by X-ray crystallography.

scholarly journals Geochemistry and Mineralogy of Ice-Dammed Lake Sediments of the Lębork Deposit

2021 ◽  
Author(s):  
Radosław Rogoziński ◽  
Alina Maciejewska
Keyword(s):  
Chemical Composition ◽  
Lake Sediments ◽  
Inductively Coupled Plasma ◽  
Mineralogical Composition ◽  
Raw Material ◽  
Element Analysis ◽  
X Ray ◽  
Dominant Component ◽  
Clay Deposits ◽  
Dammed Lake

AbstractVarved clay deposits from ice-dammed lakes are a particularly important and broadly applied raw material used for the production of high-quality ceramics (red bricks, roof tiles, etc.), but the mineralogy and geochemistry of these sediments are not fully understood. The aim of the present study was to determine the chemical and mineralogical composition of ice-dammed lake sediments of the Lębork deposit. Major-element analysis of the compositions of selected samples from the ice-dammed lake clays was performed by X-ray fluorescence (XRF) and trace elements were determined by inductively coupled plasma-mass spectrometry. The mineralogical composition of clay samples was determined by X-ray diffraction (XRD). Analyses of the chemical composition of the ice-dammed lake clays of the Lębork deposit showed that the dominant component was SiO2 with a mean content of 56.13 wt.%; the second most abundant component was Al2O3, with a mean content for the entire deposit of 11.61 wt.%. Analysis by ICP-MS indicated the presence of rare earth elements (REE), e.g. cerium, neodymium, lanthanum, and praseodymium; their mean contents are: 56.9, 27.0, 26.3, and 7.3 ppm, respectively. Mineralogical analysis of the varved clays identified quartz, muscovite, calcite, and clay minerals – illite, kaolinite, and montmorillonite. The material filling the Lębork basin is characterized by small lateral and vertical variability in chemical composition. The results of the present study may be of considerable importance in determining the parent igneous, metamorphic, and sedimentary rocks, the weathering products of which supplied material to the ice-dammed lake, as well as in determining the mechanisms and character of the sedimentation process itself.

Cobalt(II) Mercury Tetrathiocyanate Complexes with Lewis Bases

1973 ◽  
Vol 51 (3) ◽  
pp. 438-447 ◽  
Author(s):  
R. Makhija ◽  
L. Pazdernik ◽  
R. Rivest
Keyword(s):  
Magnetic Susceptibility ◽  
Powder Diffraction ◽  
Elemental Analysis ◽  
Far Infrared ◽  
Crystalline Solid ◽  
Ultraviolet Spectroscopy ◽  
X Ray ◽  
Lewis Bases ◽  
Polydentate Ligands

A new series of octahedral cobalt(II) complexes are formed when CoX2(X = Cl, Br, I, SCN) reacts with Hg(SCN)2 in the presence of Lewis bases. These complexes of stoichiometry CoHg(SCN)4•2L (L = THF, dioxane, pyridine, aniline) are pink to violet solids which slowly decompose to the blue crystalline solid, CoHg(SCN)4, the stable magnetic susceptibility standard. On further reaction of CoHg(SCN)4•2THF with mono-, bi-, and polydentate ligands in dry ethanol, complexes of the following types are obtained: CoHg(SCN)4•2L (L = PΦ3), CoHg(SCN)4•2LL (LL = trien), CoHg(SCN)4•3LL (LL = en, bipy), and CoHg(SCN)4•4LL (LL = phen). The stoichiometry of these were determined by elemental analysis. Possible structures of these are discussed with the help of mid and far infrared, visible, and ultraviolet spectroscopy, magnetic susceptibility, and X-ray powder diffraction. Some new i.r. bands like Co—P, Co—N, and Hg—S are assigned in the low region.

scholarly journals The Voyage of Metals in the Universe from Cosmological to Planetary Scales: the need for a Very High-Resolution, High Throughput Soft X-ray Spectrometer

2021 ◽  
Author(s):  
F. Nicastro ◽  
J. Kaastra ◽  
C. Argiroffi ◽  
E. Behar ◽  
S. Bianchi ◽  
...  
Keyword(s):  
Chemical Composition ◽  
High Resolution ◽  
Deep Understanding ◽  
High Resolution Spectroscopy ◽  
X Ray ◽  
Viable Solution ◽  
Surrounding Space ◽  
Nuclear Processes ◽  
The Universe ◽  
Very High

AbstractMetals form an essential part of the Universe at all scales. Without metals we would not exist, and the Universe would look completely different. Metals are primarily produced via nuclear processes in stars, and spread out through winds or explosions, which pollute the surrounding space. The wanderings of metals in-and-out of astronomical objects are crucial in determining their own evolution and thus that of the Universe as a whole. Detecting metals and assessing their relative and absolute abundances and energetics can thus be used to trace the evolution of these cosmic components. The scope of this paper is to highlight the most important open astrophysical problems that will be central in the next decades and for which a deep understanding of the Universe’s wandering metals, their physical and kinematical states, and their chemical composition represents the only viable solution. The majority of these studies can only be efficiently performed through High Resolution Spectroscopy in the soft X-ray band.

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