scholarly journals RELATIONSHIP BETWEEN HEAT OF HYDRATION AND COMPRESSIVE STRENGTH IN BLENDED CEMENTS

2015 ◽  
Vol 69 (1) ◽  
pp. 191-198
Author(s):  
Yuya YODA ◽  
Yutaka AIKAWA ◽  
Daiki ATARASHI ◽  
Etsuo SAKAI
Keyword(s):  
Compressive Strength ◽  
Heat Of Hydration ◽  
Blended Cements

scholarly journals Study of the Properties of Blended Cements Containing Various Types of Slag Cements and Limestone Powder

Materials ◽  
2021 ◽  
Vol 14 (20) ◽  
pp. 6072
Author(s):  
Małgorzata Gołaszewska ◽  
Zbigniew Giergiczny
Keyword(s):  
Particle Size ◽  
Compressive Strength ◽  
Particle Size Distribution ◽  
Rheological Properties ◽  
Size Distribution ◽  
Heat Of Hydration ◽  
Limestone Powder ◽  
Engineering Practice ◽  
Negative Effects ◽  
Blended Cements

It is currently vital to use more environmentally friendly cementitious composites, such as blended slag-limestone cements. However, many properties of slag-limestone cements are not yet fully research, especially in regards to the effect of limestone properties on properties of mortars and concrete. In the research, three types of slag cements were mixed with two types of limestone to obtain multi-component slag-limestone cements. Tests of rheological properties, heat of hydration, and compressive strength were conducted to ascertain the effect of limestone on the cement properties and to check the viability of this type of cement for engineering practice. It was found that the addition of up to 10% of limestone to slag cements did not have negative effects on tested properties; however, the exact influence of limestone was dependent on limestone particle size distribution. Increasing the amount of limestone in limestone-slag cements to 15% significantly decreased the compressive strength of the mortars and decreased hydration heat but had no significant effect on rheological properties.

scholarly journals Effect of Waste Glass on the Properties and Microstructure of Magnesium Potassium Phosphate Cement

Materials ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2073
Author(s):  
Qiubai Deng ◽  
Zhenyu Lai ◽  
Rui Xiao ◽  
Jie Wu ◽  
Mengliang Liu ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Glass Powder ◽  
Setting Time ◽  
Potassium Phosphate ◽  
Heat Of Hydration ◽  
Waste Glass ◽  
Hydration Heat ◽  
Magnesium Potassium Phosphate Cement ◽  
The Matrix ◽  
Powder Content

Waste glass is a bulk solid waste, and its utilization is of great consequence for environmental protection; the application of waste glass to magnesium phosphate cement can also play a prominent role in its recycling. The purpose of this study is to evaluate the effect of glass powder (GP) on the mechanical and working properties of magnesium potassium phosphate cement (MKPC). Moreover, a 40mm × 40mm × 40mm mold was used in this experiment, the workability, setting time, strength, hydration heat release, porosity, and microstructure of the specimens were evaluated. The results indicated that the addition of glass powder prolonged the setting time of MKPC, reduced the workability of the matrix, and effectively lowered the hydration heat of the MKPC. Compared to an M/P ratio (MgO/KH2PO4 mass ratio) of 1:1, the workability of the MKPC with M/P ratios of 2:1 and 3:1 was reduced by 1% and 2.1%, respectively, and the peak hydration temperatures were reduced by 0.5% and 14.6%, respectively. The compressive strength of MKPC increased with an increase in the glass powder content at the M/P ratio of 1:1, and the addition of glass powder reduced the porosity of the matrix, effectively increased the yield of struvite-K, and affected the morphology of the hydration products. With an increase in the M/P ratio, the struvite-K content decreased, many tiny pores were more prevalent on the surface of the matrix, and the bonding integrity between the MKPC was weakened, thereby reducing the compressive strength of the matrix. At less than 40 wt.% glass powder content, the performance of MKPC improved at an M/P ratio of 1:1. In general, the addition of glass powders improved the mechanical properties of MKPC and reduced the heat of hydration.

scholarly journals Calcined Oyster Shell Powder as an Expansive Additive in Cement Mortar

Materials ◽  
2019 ◽  
Vol 12 (8) ◽  
pp. 1322 ◽  
Author(s):  
Joon Ho Seo ◽  
Sol Moi Park ◽  
Beom Joo Yang ◽  
Jeong Gook Jang
Keyword(s):  
Compressive Strength ◽  
Cement Mortar ◽  
Autogenous Shrinkage ◽  
Oyster Shell ◽  
Heat Of Hydration ◽  
Strength Development ◽  
Flow Loss ◽  
Hardened Properties ◽  
Oyster Shell Powder ◽  
Shell Powder

The present study prepared calcined oyster shell powder having chemical composition and crystal structure of calcium oxide and lime, respectively, and investigated the fresh and hardened properties of cement mortar incorporating calcined oyster shell powder as an additive. The test results indicated that the hydration of calcined oyster shell powder promoted the additional formation of Ca(OH)2 at the initial reaction stage, thereby increasing the heat of hydration. In particular, the volumetric increase of calcined oyster shell powder during hydration compensated the autogenous shrinkage of mortar at early ages, ultimately leading to a clear difference in the shrinkage values at final readings. However, an excessive incorporation of calcined oyster shell powder affected the rate of C–S–H formation in the acceleratory period of hydration, resulting in a decrease in the compressive strength development. Meanwhile, the degree of flow loss was inconsequential and rapid flow loss was not observed in the specimens with calcined oyster shell powder. Therefore, considering the fresh and hardened properties of cement mortar, the incorporation of calcined oyster shell powder of approximately 3% by weight of cement is recommended to enhance the properties of cement mortar in terms of compressive strength and autogenous shrinkage.

scholarly journals Strength Development and Thermogravimetric Investigation of High-Volume Fly Ash Binders

Materials ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3344 ◽  
Author(s):  
Zhiyuan Zhou ◽  
Massoud Sofi ◽  
Elisa Lumantarna ◽  
Rackel San Nicolas ◽  
Gideon Hadi Kusuma ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Temperature Rise ◽  
Bound Water ◽  
High Volume ◽  
Heat Of Hydration ◽  
New Method ◽  
Hydration Properties ◽  
Adiabatic Temperature Rise ◽  
High Volume Fly Ash

To address sustainability issues by facilitating the use of high-volume fly ash (HVFA) concrete in industry, this paper investigates the early age hydration properties of HVFA binders in concrete and the correlation between hydration properties and compressive strengths of the cement pastes. A new method of calculating the chemically bound water of HVFA binders was used and validated. Fly ash (FA) types used in this study were sourced from Indonesia and Australia for comparison. The water to binder (w/b) ratio was 0.4 and FA replacement levels were 40%, 50% and 60% by weight. Isothermal calorimetry tests were conducted to study the heat of hydration which was further converted to the adiabatic temperature rise. Thermo-gravimetric analysis (TGA) was employed to explore the chemically bound water (WB) of the binders. The results showed that Australian FA pastes had higher heat of hydration, adiabatic temperature rise, WB and compressive strength compared to Indonesian FA pastes. The new method of calculating chemically bound water can be successfully applied to HVFA binders. Linear correlation could be found between the WB and compressive strength.

scholarly journals Beneficial Effect of Incorporation of Slag on the Hydration Heat, Mechanical Properties and Durability of Cement Containing Limestone Powder

2020 ◽  
Vol 330 ◽  
pp. 01047
Author(s):  
Toufik Boubekeur ◽  
Bensaid Boulekbache ◽  
Mohamed Salhi ◽  
Karim Ezziane ◽  
EL.Hadj Kadri
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Ordinary Portland Cement ◽  
Blended Cement ◽  
Dilution Effect ◽  
High Strength ◽  
Limestone Powder ◽  
Blended Cements ◽  
Hydration Mechanism ◽  
Durability Performance

This paper presents the experimental results of a wide research program, tending to determine the hydration mechanism, mechanical properties and the durability performance of ternary cement containing limestone powder and slag. The limestone powder increase the hydration at early ages inducing a high strength at, but it can reduce the later strength due to the dilution effect. On the other hands, Slag (S) contributes to increase the compressive strength at later ages. Hence, at medium blended cement (OPC-LP-S) with better performance could be produced. Results show at later age the Slag is very effective in producing ternary blended cements with similar on higher compressive strength than the ordinary Portland cement at 28 and 90 days. For durability, the incorporation of the slag into the cement containing limestone powder improves remarkably resistance to attack by acids and sulfates and it has been found that the durability of the cements never depends on the mechanical strength.

Porosity In The Microstructure Of Blended Cements Containing Fly Ash

1988 ◽  
Vol 137 ◽  
Author(s):  
H. H. Patel ◽  
P. L. Pratt ◽  
L. J. Parrott
Keyword(s):  
Compressive Strength ◽  
Image Analysis ◽  
Fly Ash ◽  
Blended Cement ◽  
Total Porosity ◽  
Major Change ◽  
Relative Volume ◽  
Blended Cements ◽  
Backscattered Electron ◽  
Electron Imaging

AbstractThe changes in porosity of OPC and an OPC-fly ash blended cement during hydration have been studied at water/solids ratios of 0.35, 0.47 and 0.59, cured for times of up to 1 year at 25°C. The porosity was measured indirectly by methanol exchange and methanol adsorption techniques and, directly, by quantitative image analysis using backscattered electron imaging in the scanning electron microscope. Measurements of porosity and of remaining anhydrous material by image analysis showed good correlation with indirect methods. Measurement of the diffusion of methanol and of the compressive strength were made in parallel with the determination of the porosity during hydration and attempts were made to relate the properties to the microstructure. For both binders the reduction of total porosity with increased reaction was small. The major change in pore structure was the subdivision of coarse pores by gel to form finer pores. Compressive strength and diffusion properties were dominated by the relative volume of coarse pores.

Microstructure and Porosity of Metakaolin Blended Cements

1988 ◽  
Vol 136 ◽  
Author(s):  
P. Bredy ◽  
M. Chabannet ◽  
J. Pera
Keyword(s):  
Compressive Strength ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Hydrated Cement ◽  
Cement Pastes ◽  
Blended Cements ◽  
Mercury Intrusion ◽  
Pozzolanic Cement

ABSTRACTFive compositions with 10% to 50% metakaolin for cement substitution were studied. The rate of hydration was studied from the compressive strength after up to 6 months of curing and from the hydrates formed (DTA-XRD). The metakaolin addition considerably reduced portlandite content in the hydrated cement and contributed to the formation of hydrated gehlenite which is not present in OPC paste. The microstructure study (SEM) shows that pozzolanic cement pastes were less crystallized than plain pastes. Mercury intrusion was used to measure porosity of hydrated cement pastes. The porosity with blended cements was higher than that with OPC, except for 10 and 20% metakaolin substitution. Evolution of the pore size distribution was studied: the pozzolanic pastes enhance small diameters.

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