Ultrafast Spin-State Conversion in Solvated Transition Metal Complexes Probed with Femtosecond Soft X-ray Spectroscopy

2010 ◽  
Author(s):  
Nils Huse ◽  
Hana Cho ◽  
Tae Kyu Kim ◽  
Lindsey Jamula ◽  
James K. McCusker ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Spin State ◽  
X Ray

scholarly journals Ultrafast Spin-State Dynamics in Transition-Metal Complexes Triggered by Soft-X-Ray Light

2017 ◽  
Vol 118 (2) ◽  
Author(s):  
Huihui Wang ◽  
Sergey I. Bokarev ◽  
Saadullah G. Aziz ◽  
Oliver Kühn
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Spin State ◽  
X Ray

scholarly journals Photo-Induced Spin-State Conversion in Solvated Transition Metal Complexes Probed via Time-Resolved Soft X-ray Spectroscopy

2010 ◽  
Vol 132 (19) ◽  
pp. 6809-6816 ◽  
Author(s):  
Nils Huse ◽  
Tae Kyu Kim ◽  
Lindsey Jamula ◽  
James K. McCusker ◽  
Frank M. F. de Groot ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Spin State ◽  
Time Resolved ◽  
X Ray

Preparation, properties and structure of some intermediate nido- and arachno-monocarbaboranes

1981 ◽  
Vol 46 (10) ◽  
pp. 2345-2353 ◽  
Author(s):  
Karel Baše ◽  
Bohumil Štíbr ◽  
Jiří Dolanský ◽  
Josef Duben
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Nmr Spectra ◽  
Liquid Ammonia ◽  
X Ray Diffraction ◽  
X Ray ◽  
H Nmr ◽  
Starting Compound

The 6-N(CH3)3-6-CB9H11 carbaborane reacts with sodium in liquid ammonia with the formation of 6-CB9H12- which was used as a starting compound for preparing the 4-CB8H14, 9-L-6-CB9H13 (L = (CH3)2S, CH3CN and P(C6H5)3), 1-(η5-C5H5)-1,2-FeCB9H10-, and 2,3-(η5-C5H5)2-2,31-Co2CB9H10- carboranes. The 4-CB8H14 compound was dehydrogenated at 623 K to give 4-(7)-CB8H12 carborane. Base degradation of 6-N(CH3)3-6-CB9H11 in methanol resulted in the formation of 3,4-μ-N(CH3)3CH-B5H10. The structure of all compounds was proposed on the basis of their 11B and 1H NMR spectra and X-ray diffraction was used in the case of the transition metal complexes.

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