Ultrafast Infrared Studies of Ligand Rearrangement at Coordinatively Unsaturated Transition Metal Centers

2000 ◽  
Author(s):  
K.T. Kotz ◽  
H. Yang ◽  
P.T. Snee ◽  
C.K. Payne ◽  
C.B. Harris
Keyword(s):  
Transition Metal ◽  
Metal Centers ◽  
Infrared Studies ◽  
Ultrafast Infrared

Methane activation by ZSM-5-supported transition metal centers

2021 ◽  
Author(s):  
Daniyal Kiani ◽  
Sagar Sourav ◽  
Yadan Tang ◽  
Jonas Baltrusaitis ◽  
Israel E. Wachs
Keyword(s):  
Transition Metal ◽  
Methane Activation ◽  
Group V ◽  
Metal Centers ◽  
Methane Dehydroaromatization

The literature on methane dehydroaromatization (MDA) to benzene using ZSM-5 supported, group V–VIII transition metal-based catalysts (MOx/ZSM-5) is critically reviewed with a focus on in situ and operando molecular insights.

Dioxygen splitting at room temperature over distant binuclear transition metal centers in zeolites for direct oxidation of methane to methanol

2021 ◽  
Author(s):  
Kinga Mlekodaj ◽  
Mariia Lemishka ◽  
Stepan Sklenak ◽  
Jiri Dedecek ◽  
Edyta Tabor
Keyword(s):  
Transition Metal ◽  
Room Temperature ◽  
Direct Oxidation ◽  
Metal Centers ◽  
Oxidation Of Methane ◽  
First Time

Here we demonstrate for the first time the splitting of dioxygen at RT over distant binuclear transition metal (M = Ni, Mn, and Co) centers stabilized in ferrierite zeolite. Cleaved...

Ultrafast Infrared Studies of Bond Activation in Organometallic Complexes

1999 ◽  
Vol 32 (7) ◽  
pp. 551-560 ◽  
Author(s):  
Haw Yang ◽  
Kenneth T. Kotz ◽  
Matthew C. Asplund ◽  
Matthew J. Wilkens ◽  
Charles B. Harris
Keyword(s):  
Bond Activation ◽  
Organometallic Complexes ◽  
Infrared Studies ◽  
Ultrafast Infrared

New Series of Oxalato-Gallophosphate Structures Containing Transition Metal Centers

2005 ◽  
Vol 17 (1) ◽  
pp. 74-80 ◽  
Author(s):  
Wen-Ming Chang ◽  
Sue-Lein Wang
Keyword(s):  
Transition Metal ◽  
Metal Centers

scholarly journals Olefin metathesis in air

2015 ◽  
Vol 11 ◽  
pp. 2038-2056 ◽  
Author(s):  
Lorenzo Piola ◽  
Fady Nahra ◽  
Steven P Nolan
Keyword(s):  
Transition Metal ◽  
Olefin Metathesis ◽  
Functional Group ◽  
High Oxidation State ◽  
Catalytic Systems ◽  
Metal Centers ◽  
Early Transition Metal ◽  
Significant Interest ◽  
High Oxidation ◽  
Metathesis Catalysts

Since the discovery and now widespread use of olefin metathesis, the evolution of metathesis catalysts towards air stability has become an area of significant interest. In this fascinating area of study, beginning with early systems making use of high oxidation state early transition metal centers that required strict exclusion of water and air, advances have been made to render catalysts more stable and yet more functional group tolerant. This review summarizes the major developments concerning catalytic systems directed towards water and air tolerance.

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