scholarly journals Spectroscopic characterization of low-phonon Er-doped BaF2 single crystal for mid-IR lasers

2021 ◽  
Vol 11 (2) ◽  
pp. 575
Author(s):  
Ei Ei Brown ◽  
Zackery D. Fleischman ◽  
Jason McKay ◽  
Mark Dubinskii
2008 ◽  
Vol 63 (5) ◽  
pp. 525-529 ◽  
Author(s):  
Olaf Reckeweg ◽  
Jesse Reiherzer ◽  
Armin Schulz ◽  
Francis J. DiSalvo

Pale grey-blue, transparent single crystals of Ba2[BN2]Cl (I4132 (no. 214), a = 1462.88(1) pm, Z = 24) are obtained by the reaction of Ba, BaCl2, BN and NaN3 in arc-welded Ta ampoules at 1200 K. The crystal structure was determined by single crystal X-ray structure analysis. The Raman and IR spectra of the title compound show the expected fundamental frequencies (νs = 1038; νas = 1969 and 2087; δ = 616 / 636 cm−1) for a nitridoborate unit with D∞h symmetry. The [N-B-N] structure obtained by X-ray single crystal structure determination corroborates this finding within the standard deviations of the measurement with d(B-N) = 132.3(8) pm and ∡ (N-B-N) = 178.5(13)°. Our results compare well to the data reported for cubic and orthorhombic Ba3[BN2]2 as well as to the isotypic compound Ba2[BN2]Br.


2015 ◽  
Vol 70 (7) ◽  
pp. 491-496 ◽  
Author(s):  
Oscar E. Piro ◽  
Gustavo A. Echeverría ◽  
Eduardo E. Castellano ◽  
Beatriz S. Parajón-Costa ◽  
Enrique J. Baran

AbstractThree new acesulfamate salts, NaC4H4NO4S, RbC4H4NO4S and CsC4H4NO4S, were prepared by reactions in aqueous solutions and thoroughly characterized. Their crystal and molecular structures were determined by single crystal X-ray diffraction methods. They crystallize in the monoclinic space group P21/a with a = 7.2518(2), b = 8.9414(4), c = 10.5929(4) Å, β = 99.951(3)°, V = 676.52(4) Å3 for the Na salt; a = 7.4663(3), b = 9.6962(4), c = 10.4391(4) Å, β = 95.150(3)°, V = 752.68(5) Å3 for the Rb salt and a = 7.5995(4), b = 9.9439(4), c = 10.8814(6) Å, β = 91.298(5)°, V = 822.08(7) Å3 for the Cs salt, and Z = 4 molecules per unit cell. The three compounds are isotypic to each other and to the previously reported potassium salt. The metal ions are in irregular polyhedral coordination with six neighboring acesulfamate anions through their nitrogen and carbonyl and sulfoxide oxygen atoms. The FTIR spectra of the compounds were also recorded and are briefly discussed.


2008 ◽  
Vol 104 (10) ◽  
pp. 103114 ◽  
Author(s):  
Andrea Arcangeli ◽  
Daniela Parisi ◽  
Alessandra Toncelli ◽  
Mauro Tonelli ◽  
Marco Bazzan ◽  
...  

2014 ◽  
Vol 151 ◽  
pp. 123-129 ◽  
Author(s):  
Adam Strzęp ◽  
Witold Ryba-Romanowski ◽  
Radosław Lisiecki ◽  
Xiaodong Xu ◽  
Jun Xu ◽  
...  

2019 ◽  
Vol 207 ◽  
pp. 251-257 ◽  
Author(s):  
M. Kowalczyk ◽  
M. Kaczkan ◽  
A. Majchrowski ◽  
M. Malinowski

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