Dependence of the absorption coefficient of vibration–rotation transitions of dipole molecules on the resonance radiation polarization

1984 ◽  
Vol 9 (11) ◽  
pp. 490
Author(s):  
V. E. Zuev ◽  
Yu. N. Ponomarev ◽  
B. A. Tikhomirov
Keyword(s):  
Absorption Coefficient ◽  
Resonance Radiation ◽  
Radiation Polarization ◽  
Vibration Rotation

Emissivity Calculations for Diatomic Gases

1951 ◽  
Vol 18 (1) ◽  
pp. 53-58
Author(s):  
S. S. Penner
Keyword(s):  
Absorption Coefficient ◽  
Atmospheric Pressure ◽  
Radiant Heat ◽  
Published Data ◽  
Radiant Heat Transfer ◽  
Effective Width ◽  
Combustion Chambers ◽  
Average Absorption Coefficient ◽  
Vibration Rotation ◽  
Simplified Procedure

Abstract An approximate method for estimating radiant-heat transfer from gaseous emitters has been developed. An average absorption coefficient is used for an effective width of an entire vibration-rotation band. The procedure for determining an average absorption coefficient in terms of integrated absorption can be justified, approximately, for very large total pressures where the spectral half-width is no longer small compared with the rotational spacing. Because of this limitation, it is to be expected that the procedure proposed here will be particularly useful only in estimating gaseous emissivities for emitters in high-pressure combustion chambers. Nevertheless, it appears that the simplified procedure yields reasonable results even at relatively low total pressures. Thus a comparison of calculated and observed emissivities for CO at atmospheric pressure shows satisfactory agreement, especially at large optical densities. Representative emissivity calculations over a wide temperature range are described. Emissivity calculations on CO, NO, HF, HCl, HBr, and HI can be carried out very rapidly by the use of recently published data on these gases.

Reordering the Absorption Coefficient Within the Wide Band for Predicting Gaseous Radiant Exchange

1996 ◽  
Vol 118 (2) ◽  
pp. 394-400 ◽  
Author(s):  
P. Y. C. Lee ◽  
K. G. T. Hollands ◽  
G. D. Raithby
Keyword(s):  
Absorption Coefficient ◽  
Smooth Curve ◽  
Wide Band ◽  
Computational Effort ◽  
Complex Nature ◽  
Smooth Curves ◽  
Exact Answer ◽  
Radiant Exchange ◽  
Vibration Rotation ◽  
Isothermal Gas

The “exact” calculation of the radiant transfer in gaseous enclosures has remained impractical for design; the highly complex nature of the absorption spectrum of the gases has meant that an inordinately large computational effort is required to effect an exact answer. In this paper we show how the complex absorption distribution for an isothermal gas can be replaced by a set of smooth curves. This procedure can be visualized as one of actually reordering the full complex absorption distribution within each vibration-rotation band, and then replacing it by a smooth curve. Such a smooth curve can then be readily approximated by a stepwise function, and radiant exchange calculations can be carried out at each step and then summed over all the steps to get the total exchange. This paper explains how the reordered curve can be obtained and gives some sample plots of the reordered absorption coefficient curve. Fitted functions for the rearranged curves have been provided, and some solutions to the radiant exchange problems are given and compared to line-by-line solutions. About 50 to 200 steps in the stepwise curve are found to be adequate in order to obtain an answer within a few percent of the exact answer.

Is there a “universal” MAC equation?

1990 ◽  
Vol 48 (2) ◽  
pp. 228-229
Author(s):  
Robert E. Ogilvie
Keyword(s):  
Absorption Coefficient ◽  
Atomic Absorption ◽  
Atomic Number ◽  
X Ray ◽  
Time Period ◽  
Image Position

The search for an empirical absorption equation begins with the work of Siegbahn (1) in 1914. At that time Siegbahn showed that the value of (μ/ρ) for a given element could be expressed as a function of the wavelength (λ) of the x-ray photon by the following equationwhere C is a constant for a given material, which will have sudden jumps in value at critial absorption limits. Siegbahn found that n varied from 2.66 to 2.71 for various solids, and from 2.66 to 2.94 for various gases.Bragg and Pierce (2) , at this same time period, showed that their results on materials ranging from Al(13) to Au(79) could be represented by the followingwhere μa is the atomic absorption coefficient, Z the atomic number. Today equation (2) is known as the “Bragg-Pierce” Law. The exponent of 5/2(n) was questioned by many investigators, and that n should be closer to 3. The work of Wingardh (3) showed that the exponent of Z should be much lower, p = 2.95, however, this is much lower than that found by most investigators.

Spectre de vibration-rotation de l’acide chlorhydrique gazeux

1965 ◽  
Vol 62 ◽  
pp. 600-603 ◽  
Author(s):  
Armand Lévy ◽  
Inga Rossi ◽  
Colette Joffrin ◽  
Nguyen Van Thanh
Keyword(s):  
Vibration Rotation

Linear and Nonlinear Optical Properties of Natural Dyes Freestanding Films and Application in Optical Limiting

2020 ◽  
pp. 139-143
Keyword(s):  
Absorption Coefficient ◽  
Water Solution ◽  
Optical Limiting ◽  
Refraction Index ◽  
Laser Wavelength ◽  
Solid State Laser ◽  
Natural Dyes ◽  
Linear And Nonlinear ◽  
532 Nm ◽  
Absorbance Spectra

Natural dyes were followed and prepared from a pomegranate, purple carrot, and eggplant peel. The absorbance spectra was measured in the wavelength range 300-800 nm. The linear properties measurements of the prepared natural dye freestanding films were determined include absorption coefficient (α0), extinction coefficient (κ), and linear refraction index (n). The nonlinear refractive index n2 and nonlinear absorption coefficient β2 of the natural dyes in the water solution were measured by the optical z-scan technique under a pumped solid state laser at a laser wavelength of 532 nm. The results indicated that the pomegranate dye can be promising candidates for optical limiting applications with significantly low optical limiting of 3.5 mW.

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