Laser refrigeration of optically levitated sodium yttrium fluoride nanocrystals

2021 ◽  
Author(s):  
Danika Luntz-Martin ◽  
R. Felsted ◽  
S. Dadras ◽  
Peter Pauzauskie ◽  
Nickolas Vamivakas
Keyword(s):  
Author(s):  
Padmaja Parameswaran Nampi ◽  
Alexander Vakurov ◽  
Hema Viswambharan ◽  
Jürgen E. Schneider ◽  
Rik Drummond-Brydson ◽  
...  

2021 ◽  
Author(s):  
Peter Pauzauskie ◽  
Alexander Bard ◽  
R. Greg Felsted ◽  
Abbie Ganas ◽  
Anupum Pant ◽  
...  

Abstract Two-step crystallization mechanisms based on spinodal decomposition followed by nucleation are commonly observed both in the laboratory and in nature. While this pathway may require chemical reactions, subsequent nucleation and growth are often considered as separate, discrete events from the reaction itself. Recent work has also shown a distinct intermediate step involving the formation of an amorphous aggregate. Here we report a novel four-step mechanism in the aqueous synthesis of sodium yttrium fluoride involving 1) the segregation of aqueous ions into a dense liquid phase, 2) the formation of an amorphous aggregate, 3) nucleation of a cubic YF3 phase, and 4) subsequent solid-state diffusion of sodium and fluoride ions to form a final NaYF4 phase. The final step involves a continuous, gradual change of the solid phase’s chemical stoichiometry from YF3 toward NaYF4. Unlike previously studied nucleation and growth mechanisms, the stoichiometry of the final solid phase evolves throughout the crystallization process rather than being determined at nucleation. This novel four-step mechanism provides a new perspective into the nucleation and growth of many other crystalline materials given the ubiquity of nonstoichiometric compounds in nature.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Feng Hu ◽  
Qian Wan ◽  
Liping Lu ◽  
Haiying Sun ◽  
Xiyan Zhang ◽  
...  

Multi-component fluoride phosphors BaxNay-nMnYzF2x+y+3z+3m: Er3+m (M=Li, K) sensitive to 1550 nm were synthesized by the low temperature combustion synthesis (LCS) method. The optimum batch formula was determined by the orthogonal...


Nanomaterials ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 936 ◽  
Author(s):  
Wei-Kai Wang ◽  
Yu-Xiu Lin ◽  
Yi-Jie Xu

Yttrium fluoride (YF3) films were grown on sapphire substrate by a radio frequency magnetron using a commercial ceramic target in a vacuum chamber. The structure, composition, and plasma etching behavior of the films were systematically investigated. The YF3 film was deposited at a working pressure of 5 mTorr and an RF power of 150 W. The substrate-heating temperature was increased from 400 to 700 °C in increments of 100 °C. High-resolution transmission electron microscopy (HRTEM) and X-ray diffraction results confirmed an orthorhombic YF3 structure was obtained at a substrate temperature of 700 °C for 2 h. X-ray photoelectron spectroscopy revealed a strongly fluorinated bond (Y–F bond) on the etched surface of the YF3 films. HRTEM analysis also revealed that the YF3 films became yttrium-oxyfluorinated after exposure to fluorocarbon plasma. The etching depth was three times lower on YF3 film than on Al2O3 plate. These results showed that the YF3 films have excellent erosion resistance properties compared to Al2O3 plates.


1995 ◽  
Vol 51 (9) ◽  
pp. 6085-6088 ◽  
Author(s):  
Keith W. Ver Steeg ◽  
Alexander Ya. Karasik ◽  
Roger J. Reeves ◽  
Tasoltan T. Basiev ◽  
Richard C. Powell

1994 ◽  
Vol 69 (1) ◽  
pp. 37-41 ◽  
Author(s):  
Md. Shareefuddin ◽  
M. Narasimha Chary
Keyword(s):  

2004 ◽  
Vol 377 (1-2) ◽  
pp. 162-166 ◽  
Author(s):  
M.D. Mathews ◽  
B.R. Ambekar ◽  
A.K. Tyagi ◽  
J. Köhler

2007 ◽  
Vol 180 (1) ◽  
pp. 260-264 ◽  
Author(s):  
Nicholas F. Stephens ◽  
Philip Lightfoot

1994 ◽  
Vol 22 (2-3) ◽  
pp. 159-164 ◽  
Author(s):  
Md. Shareefuddin ◽  
K. Narasimha Reddy ◽  
M. Narasimha Chary

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