scholarly journals Generation of silver nanoparticles with controlled size and spatial distribution by pulsed laser irradiation of silver ion-doped glass

2014 ◽  
Vol 22 (5) ◽  
pp. 5076 ◽  
Author(s):  
Stefan Wackerow ◽  
Amin Abdolvand
2004 ◽  
Vol 99-100 ◽  
pp. 65-72
Author(s):  
Yuri S. Kaganovsky ◽  
I. Antonov ◽  
M. Rosenbluh ◽  
J. Ihlemann ◽  
A.A. Lipovskii

Two types of silver-doped glass were used for direct laser recording of 2D and 3D photonic crystals. The first contained a diffusion layer (20 microns thick) with embedded silver nanoclusters of 20-nm average radius. 2D and 3D photonic crystals of submicron lattice parameters were fabricated by nanosecond pulsed laser irradiation (l, = 355 nm) using four or five coherent intersecting beams. Under irradiation the clusters absorbing light energy are heated to high temperatures and become mobile due to the formation of liquid shells around them. Adjacent clusters move towards each other and towards the irradiated surface under local temperature gradients, form agglomerates and merge in periodically located "spots" of high light intensity in the interference field. The second type of glass, photosensitive to UV irradiation, contained in the bulk Ag+ and Ce3+ ions. Under UV irradiation excited electrons passed from Ce3+ to Ag+. The Ag atoms became neutral and under subsequent heat treatment of the glass at elevated temperatures have a tendency to form nanoclusters, thus “developing” the UV recorded patterns. Using nanosecond pulsed irradiation of 308 nm we have recorded 3D photonic crystals in the bulk of such glass.


2008 ◽  
Vol 311 (1) ◽  
pp. 172-184 ◽  
Author(s):  
Jean-Philippe Blondeau ◽  
Stéphane Pellerin ◽  
Vanessa Vial ◽  
Krzysztof Dzierże¸ga ◽  
Nadia Pellerin ◽  
...  

2017 ◽  
Vol 14 (1) ◽  
pp. 50-53 ◽  
Author(s):  
Gabriel Ortega-Mendoza ◽  
Oscar Goiz ◽  
Alfonso Padilla-Vivanco ◽  
Carina Toxqui-Quitl ◽  
Placido Zaca-Moran ◽  
...  

Background: Metal nanoparticles have been widely investigated due to their unique optical, mechanical, and chemical properties compared with those of the same bulk material. These properties can be tuned by controlling their size or shape, in this sense, several nanomaterials have been obtained by means of both chemical and physical methods. For instance, silver nanoparticles have been obtained in liquid media by using laser ablation or chemical reduction techniques. Another way to obtain a colloidal silver nanoparticles is through the well-known pulsed laser irradiation method which can produce a stable colloidal solution in a few minutes of irradiation and without stabilizing molecules or ligands. Methods: Silver nanopowder suspended in ethanol was irradiated with a pulsed laser at 532 nm via optical fiber. Previously, the fiber was prepared by cleaving and removing its coating and then placed in the middle of a cell. The pulse width was 15 ns and the pulse repetition frequency was 10 kHz. Scanning and transmission electron microscopes were used to observe the silver nanoparticles before and after laser irradiation, respectively. The samples were analyzed by means of UV-Vis spectrophotometer to observe the absorption spectra. Results: The absorption spectra show that particle size distribution increases according to the irradiation time. The colloidal solution showed a color change (from gray to yellow) after having irradiated it for 5 minutes. From TEM images, it can be observed that silver nanopowder was transformed to semispherical particles with diameters smaller than 1μm, however, due to the wide particle size distribution the colloidal solution was centrifuged for 30 min to separate the nanoparticles. Conclusion: The pulsed laser irradiation method via optical fiber was successfully used to obtain a stable yellow colloidal solution. Photomelting, photofusion, and photofragmentation are the responsible phenomena for the change in morphology and size of the silver nanopowder.


2003 ◽  
Author(s):  
Yuri Kaganovskii ◽  
Irena Antonov ◽  
David Ianetz ◽  
Michael Rosenbluh ◽  
Andrey A. Lipovskii

1993 ◽  
Vol 3 (12) ◽  
pp. 2173-2188
Author(s):  
N. G. Chechenin ◽  
A. V. Chernysh ◽  
V. V. Korneev ◽  
E. V. Monakhov ◽  
B. V. Seleznev

1983 ◽  
Vol 44 (C5) ◽  
pp. C5-449-C5-454 ◽  
Author(s):  
P. Baeri ◽  
M. G. Grimaldi ◽  
E. Rimini ◽  
G. Celotti

1983 ◽  
Vol 44 (C5) ◽  
pp. C5-23-C5-36 ◽  
Author(s):  
H. Kurz ◽  
L. A. Lompré ◽  
J. M. Liu

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