Silicate Glass-Ceramics toward Photonic Applications: Pockels Effect and Second-Harmonic Generation

Author(s):  
Kazuya Takano ◽  
Kosuke Funajima ◽  
Yoshihiro Takahashi ◽  
Yoshiki Yamazaki ◽  
Nobuaki Terakado ◽  
...  
2011 ◽  
Vol 94 (7) ◽  
pp. 2080-2086 ◽  
Author(s):  
Hélène Vigouroux ◽  
Evelyne Fargin ◽  
Alexandre Fargues ◽  
Bruno Le Garrec ◽  
Marc Dussauze ◽  
...  

2014 ◽  
Vol 39 (20) ◽  
pp. 5921 ◽  
Author(s):  
Marion Cornet ◽  
Jérôme Degert ◽  
Emmanuel Abraham ◽  
Eric Freysz

2007 ◽  
Vol 30 (2) ◽  
pp. 338-345 ◽  
Author(s):  
Marie Guignard ◽  
Virginie Nazabal ◽  
Xiang-Hua Zhang ◽  
Frédéric Smektala ◽  
Alain Moréac ◽  
...  

2004 ◽  
Vol 51 (8) ◽  
pp. 1223-1232
Author(s):  
M. K. Balakirev ◽  
L. I. Vostrikova ◽  
V. A. Smirnov ◽  
K. Ozga ◽  
I. V. Kityk

2007 ◽  
Vol 274 (2) ◽  
pp. 466-470 ◽  
Author(s):  
Guoping Dong ◽  
Haizheng Tao ◽  
Xiudi Xiao ◽  
Changgui Lin ◽  
Haitao Guo ◽  
...  

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Andrea Alparone

The static and dynamic electronic (hyper)polarizabilities of the equilibrium conformations of 2,2′-bithiophene (anti-gauche and syn-gauche) were computed in the gas phase. The calculations were carried out using Hartree-Fock (HF), Møller-Plesset second-order perturbation theory (MP2), and density functional theory methods. The properties were evaluated for the second harmonic generation (SHG), and electrooptical Pockels effect (EOPE) nonlinear optical processes at the typical λ=1064 nm of the Nd:YAG laser. The anti-gauche form characterized by the S–C2–C2′–S dihedral angle of 137° (MP2/6-311G**) is the global minimum on the potential energy surface, whereas the syn-gauche rotamer (S–C2–C2′–S = 48°, MP2/6-311G**) lies ca. 0.5 kcal/mol above the anti-gauche form. The structural properties of the gauche structures are rather similar to each other. The MP2 electron correlation effects are dramatic for the first-order hyperpolarizabilities of the 2,2′-bithiophenes, decreasing the HF values by ca. a factor of three. When passing from the anti-gauche to the syn-gauche conformer, the static and frequency-dependent first-order hyperpolarizabilities increase by ca. a factor of two. Differently, the electronic polarizabilities and second-order hyperpolarizabilities of these rotamers are rather close to each other. The syn-gauche structure could be discriminated from the anti-gauche one through its much more intense SHG and EOPE signals.


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