Spectroscopic study on the photophysical properties of chlorine substituted tetraphenylporphyrinhistidine and its zinc (?) complexes

2003 ◽  
Vol 48 (17) ◽  
pp. 1794
Author(s):  
Huijuan ZHANG
2015 ◽  
Vol 44 (26) ◽  
pp. 11984-11996 ◽  
Author(s):  
Daniel A. Evans ◽  
Lucia Myongwon Lee ◽  
Ignacio Vargas-Baca ◽  
Alan H. Cowley

Bis(imino)acenaphthene (BIAN) zinc complexes with para-substituted aryl groups have been synthesized and investigated from the standpoint of their photophysical properties.


2012 ◽  
Vol 392 ◽  
pp. 292-299 ◽  
Author(s):  
Zihong Zhou ◽  
Wen Li ◽  
Xiaohua Hou ◽  
Langqiu Chen ◽  
Xiang Hao ◽  
...  

2015 ◽  
Vol 44 (46) ◽  
pp. 20032-20044 ◽  
Author(s):  
Prateeti Chakraborty ◽  
Jaydeep Adhikary ◽  
Sugata Samanta ◽  
Ishani Majumder ◽  
Chiara Massera ◽  
...  

The role of para substituents of three dinuclear zinc(ii) complexes on the structure, photophysical properties and their different weak interactions is investigated.


2007 ◽  
Vol 11 (02) ◽  
pp. 130-138 ◽  
Author(s):  
Eva H. Mørkved ◽  
Nils Kr. Afseth ◽  
Petr Zimcik

Magnesium and zinc complexes of azaphthalocyanines (AzaPc) with eight peripheral aromatic (phenyl) or heteroaromatic (pyridyl, thienyl, furyl) substituents are studied from the point of view of their singlet oxygen (ΦΔ) and fluorescence (Φ F ) quantum yields, and UV-vis absorption spectra. Zn complexes have higher ΦΔ than Mg complexes by a factor of two, whereas the Mg complexes have higher Φ F than Zn complexes, also by a factor of two. Thienyl AzaPc have the highest ΦΔ among all studied substances (0.635 for Zn complex) followed by phenyl and pyridyl derivatives. The order of Φ F values is then reversed - the highest values were reached for pyridyl and phenyl derivatives followed by thienyl AzaPc. Both furyl AzaPc were unstable towards light and decomposed giving very low ΦΔ and Φ F . The Q-bands of the furyl and thienyl AzaPc were red-shifted for approx. 20 nm compared to phenyl and pyridyl derivatives indicating lower sterical hindrance between five-membered rings and thus allowing better conjugation of π-systems. Pyridyl-, thienyl- and furyl-substituted pyrazino[2,3-b]pyrazine-2,3-dicarbonitriles were also prepared but decomposed during attempted cyclotetramerizations.


2017 ◽  
Vol 1130 ◽  
pp. 951-962 ◽  
Author(s):  
Jesús Baldenebro-López ◽  
Alberto Báez-Castro ◽  
Daniel Glossman-Mitnik ◽  
Herbert Höpfl ◽  
Adriana Cruz-Enríquez ◽  
...  

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