Identification of Neoformed Ni-Phyllosilicates Upon Ni Uptake in Montmorillonite: A Transmission Electron Microscopy and Extended X-Ray Absorption Fine Structure Study

2006 ◽  
Vol 54 (2) ◽  
pp. 209-219 ◽  
Author(s):  
Rainer Dāhn ◽  
Michel Jullien ◽  
André M. Scheidegger ◽  
Christophe Poinssot ◽  
Bart Baeyens ◽  
...  
2003 ◽  
Vol 91 (10) ◽  
Author(s):  
Mohamed Merroun ◽  
C. Hennig ◽  
A. Rossberg ◽  
T. Reich ◽  
S. Selenska-Pobell

SummaryWe used a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, Transmission Electron Microscopy (TEM) and Energy-Dispersive X-ray (EDX) analysis to conduct molecular scale studies on U(VI) interaction with three recently described eco-types of


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Hiroyuki Ikemoto ◽  
Takafumi Miyanaga

AbstractIn this review, we make a survey of the structure studies for the chalcogen elements and several chalcogenides in liquid, amorphous and nanosized state by using X-ray absorption fine structure (XAFS). The chalcogen elements have hierarchic structures; the chain structure constructed with the strong covalent bond as a primary structure, and the weaker interaction between chains as a secondary one. Existence of these two kinds of interactions induces exotic behaviors in the liquid, amorphous and nanosized state of the chalcogen and chalcogenides. XAFS is a powerful structure analysis technique for multi-element systems and the disordered materials, so it is suitable for the study of such as liquid, amorphous and nanosized mixtures. In section 2, the structures for the liquid state are discussed, which show the interesting semiconductor-metal transition depending on their temperatures and components. In section 3, the structure for the amorphous states are discussed. Especially, some of chalcogens and chalcogenides present the photostructural change, which is important industrial application. In section 4, the structures of nanosized state, nanoparticles and isolated chain confined into the narrow channel, are discussed. The studies of the nanoparticle and the isolated chain reveal the alternative role between the intrachain covalent bonds and the interchain interaction.


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