Structure and Properties of Chromium- and Zinc-Oxide Layers Formed on Zircaloy-2 in High-Temperature Water

2002 ◽  
Vol 137 (1) ◽  
pp. 60-71 ◽  
Author(s):  
Orlin L. Blajiev ◽  
Chihiro Matsuura ◽  
Daisuke Hiroishi ◽  
Kenkichi Ishigure
Scanning ◽  
2018 ◽  
Vol 2018 ◽  
pp. 1-12
Author(s):  
Soon-Hyeok Jeon ◽  
Geun Dong Song ◽  
Do Haeng Hur

The aim of this work is to characterize the oxide layer structure of Alloy 690TT in high-temperature water with different dissolved hydrogen (DH) contents by using an X-ray photoelectron spectroscopy. Under the low DH contents (0.4494–0.8988 mg/kg), the oxide layers were composed of an outermost layer of Ni(OH)2 and Cr(OH)3 enriched in Ni, an intermediate layer of hydroxides and oxides enriched in Cr, and an inner Cr2O3 layer. Outermost NiO coexists with small amount of Cr2O3 layer, while in the inner oxide only Cr2O3 remains. The oxide layers at medium and high DH contents (3.1458– 8.9880 mg/kg) consisted of an outermost layer of Ni(OH)2 and Cr(OH)3 enriched in Cr, an intermediate layer of metallic Ni, hydroxides and oxides enriched in Cr, and an inner Cr2O3 layer. In addition, boron compounds containing B3+ ions were accumulated in the thick and porous NiO layer formed at low DH contents, whereas the accumulation of boron compounds did not occur in the thin and dense polyhedral oxide layer formed at medium and high DH contents.


2015 ◽  
Vol 19 (12) ◽  
pp. 3511-3519 ◽  
Author(s):  
M. Santamaria ◽  
F. Di Franco ◽  
F. Di Quarto ◽  
M. Pisarek ◽  
S. Zanna ◽  
...  

Author(s):  
M.I. Ariëns ◽  
V. Chlan ◽  
P. Novák ◽  
L.G.A. van de Water ◽  
A.I. Dugulan ◽  
...  

2011 ◽  
Vol 66 (18) ◽  
pp. 4029-4035 ◽  
Author(s):  
Sonja Vidojkovic ◽  
Victor Rodriguez-Santiago ◽  
Mark V. Fedkin ◽  
David J. Wesolowski ◽  
Serguei N. Lvov

2021 ◽  
pp. 129834
Author(s):  
Zhan Li ◽  
Yuzhen Deng ◽  
Nikita Dewangan ◽  
Jiawei Hu ◽  
Zhigang Wang ◽  
...  

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