<i>Detecting Maleic Anhydride in Starch using Line-Scan Hyperspectral Raman Chemical Imaging</i>

2017 ◽  
Author(s):  
Jianwei Qin ◽  
Moon S Kim ◽  
Kuanglin Chao ◽  
Lisa Bellato
2017 ◽  
Author(s):  
Jianwei Qin ◽  
Moon S. Kim ◽  
Kuanglin Chao ◽  
Maria Gonzalez ◽  
Byoung-Kwan Cho

2015 ◽  
Vol 9 (1) ◽  
pp. 113-123 ◽  
Author(s):  
Jianwei Qin ◽  
Kuanglin Chao ◽  
Moon S. Kim ◽  
Byoung-Kwan Cho

2017 ◽  
Vol 71 (11) ◽  
pp. 2469-2476 ◽  
Author(s):  
Jianwei Qin ◽  
Moon S. Kim ◽  
Kuanglin Chao ◽  
Maria Gonzalez ◽  
Byoung-Kwan Cho

A high-throughput Raman chemical imaging method was developed for direct inspection of benzoyl peroxide (BPO) mixed in wheat flour. A 5 W, 785 nm line laser (240 mm long and 1 mm wide) was used as a Raman excitation source in a push-broom Raman imaging system. Hyperspectral Raman images were collected in a wavenumber range of 103–2881 cm−1 from dry wheat flour mixed with BPO at eight concentrations (w/w) from 50 to 6400 ppm. A sample holder with a sampling volume of 150 × 100 × 2 mm3 was used to present a thin layer (2 mm thick) of the powdered sample for line-scan image acquisition with a spatial resolution of 0.2 mm. A baseline correction method based on adaptive iteratively reweighted penalized least squares was used to remove the fluctuating fluorescence signals from the wheat flour. To isolate BPO particles from the flour background, a simple thresholding method was applied to the single-band fluorescence-free images at a unique Raman peak wavenumber (i.e., 1001 cm−1) preselected for the BPO detection. Chemical images were created to detect and map the BPO particles. Limit of detection for the BPO was estimated in the order of 50 ppm, which is on the same level with regulatory standards. Pixel concentrations were calculated from the percentages of the BPO pixels in the chemical images. High correlation was found between the pixel concentrations and the mass concentrations of the BPO, indicating that the Raman chemical imaging method can be used for quantitative detection of the BPO mixed in the wheat flour.


2014 ◽  
Vol 68 (6) ◽  
pp. 692-695 ◽  
Author(s):  
Jianwei Qin ◽  
Kuanglin Chao ◽  
Moon S. Kim

2009 ◽  
Vol 63 (11) ◽  
pp. 1197-1203 ◽  
Author(s):  
E. D. Emmons ◽  
A. Tripathi ◽  
J. A. Guicheteau ◽  
S. D. Christesen ◽  
A. W. Fountain

Raman chemical imaging (RCI) has been used to detect and identify explosives in contaminated fingerprints. Bright-field imaging is used to identify regions of interest within a fingerprint, which can then be examined to determine their chemical composition using RCI and fluorescence imaging. Results are presented where explosives in contaminated fingerprints are identified and their spatial distributions are obtained. Identification of explosives is obtained using Pearson's cosine cross-correlation technique using the characteristic region (500–1850 cm−1) of the spectrum. This study shows the ability to identify explosives nondestructively so that the fingerprint remains intact for further biometric analysis. Prospects for forensic examination of contaminated fingerprints are discussed.


2012 ◽  
Vol 1 (2) ◽  
pp. 159-183 ◽  
Author(s):  
Márcia C. Breitkreitz ◽  
Ronei J. Poppi

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