scholarly journals Oily Sludge Recovery using Microwave Pyrolysis Technique

2021 ◽  
Vol 37 (1) ◽  
pp. 40-45
Author(s):  
Khamael M. Abualnaja ◽  
Hala M. Abo-Dief ◽  
Ola A. Abu Ali ◽  
Abdullah Al-Anazi ◽  
Ashraf T. Mohamed
Keyword(s):  
Heating Rate ◽  
Oil Recovery ◽  
Calorific Value ◽  
Oily Sludge ◽  
Pyrolysis Oil ◽  
Nitrogen Flow Rate ◽  
Microwave Pyrolysis ◽  
Pyrolysis Oils ◽  
Temperature Heating ◽  
Pyrolysis Gases

The oily sludge treatments catch widespread attention. But, management of sludge is difficult and costly undertaking. The oil recovery pyrolysis temperature, heating rate and carbon wt.% is discussed. The recovered aliphatic, aromatic, elemental components and gases were obtained with respect to the nitrogen flow rate. The present work showed that as the heating rate increases, both the %pyrolysis oil and gases increases up to 600 OC, while the %pyrolysis char decreases. Beyond 600 OC, the pyrolysis gases% increases, the pyrolysis oil% decreases while the %pyrolysis char continuous decreases. Gas chromatography, and calorific value used to examine the hydrocarbon compositions of the virgin, sludge, and pyrolysis oils.

scholarly journals Biochar from Microwave Pyrolysis of Artemisia Slengensis: Characterization and Methylene Blue Adsorption Capacity

2019 ◽  
Vol 9 (9) ◽  
pp. 1813 ◽  
Author(s):  
Xuhui Li ◽  
Kunquan Li ◽  
Chunlei Geng ◽  
Hamed El Mashad ◽  
Hua Li ◽  
...  
Keyword(s):  
Heating Rate ◽  
Pyrolysis Temperature ◽  
Metal Chloride ◽  
Holding Time ◽  
Optimal Conditions ◽  
Heating Rates ◽  
Microwave Pyrolysis ◽  
Metal Carbonate ◽  
Orthogonal Experiments ◽  
Temperature Heating

In this research, artemisia selengensis was used to produce biochar via microwave pyrolysis. The influence of pyrolysis temperature, heating rates, temperature holding time and additive on the biochar yield and adsorbability were all investigated. The results suggest that the biochar yield decreased with the increase of pyrolysis temperature while the adsorbability of the biochar increased with an increase of the pyrolysis temperature; the biochar yield and its adsorbability could achieve the desired value when the heating rate and temperature holding time were in a specific scope; the biochar yield decreased when an additive was added; the adsorbability of the biochar could be increased by adding ZnCl2 (metal chloride) and Na2CO3 (metal carbonate). According to the orthogonal experiments, the optimal conditions for biochar production were: pyrolysis temperature 550 °C, heating rate 2 °C/s, temperature holding time 15 min, without additive.

scholarly journals Optimization of Sintering Process of Alumina Ceramics Using Response Surface Methodology

2021 ◽  
Vol 13 (12) ◽  
pp. 6739
Author(s):  
Darko Landek ◽  
Lidija Ćurković ◽  
Ivana Gabelica ◽  
Mihone Kerolli Mustafa ◽  
Irena Žmak
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Heating Rate ◽  
Sintering Temperature ◽  
Nonlinear Models ◽  
Slip Casting ◽  
Holding Time ◽  
Alumina Ceramics ◽  
Aqueous Suspensions ◽  
Temperature Heating

In this work, alumina (Al2O3) ceramics were prepared using an environmentally friendly slip casting method. To this end, highly concentrated (70 wt.%) aqueous suspensions of alumina (Al2O3) were prepared with different amounts of the ammonium salt of a polycarboxylic acid, Dolapix CE 64, as an electrosteric dispersant. The stability of highly concentrated Al2O3 aqueous suspensions was monitored by viscosity measurements. Green bodies (ceramics before sintering) were obtained by pouring the stable Al2O3 aqueous suspensions into dry porous plaster molds. The obtained Al2O3 ceramic green bodies were sintered in the electric furnace. Analysis of the effect of three sintering parameters (sintering temperature, heating rate and holding time) on the density of alumina ceramics was performed using the response surface methodology (RSM), based on experimental data obtained according to Box–Behnken experimental design, using the software Design-Expert. From the statistical analysis, linear and nonlinear models with added first-order interaction were developed for prediction and optimization of density-dependent variables: sintering temperature, heating rate and holding time.

scholarly journals Effect of the Incorporation of Biomass in the Carbonization of Waste Electrical and Electronic Equipment

Proceedings ◽  
2021 ◽  
Vol 52 (1) ◽  
pp. 4
Author(s):  
Roberta Mota-Panizio ◽  
Luis F. Carmo-Calado ◽  
Octávio Alves ◽  
Catarina Nobre ◽  
J. L. Silveira ◽  
...  
Keyword(s):  
Heating Rate ◽  
Lignocellulosic Biomass ◽  
Residence Time ◽  
Calorific Value ◽  
Electronic Equipment ◽  
Initial Value ◽  
Carbonization Process ◽  
Chlorine Removal

The behavior of chars from the carbonization process were studied when the lignocellulosic biomass was incorporated into the waste of electrical and electronic equipment for chlorine removal. Tests were performed at 300°C with a heating rate of 15°C/min and residence time of 60 min. Compositions studied had 100, 75, 50, 25 and 0% of waste electrical and electronic equipment (WEEE) in the mixtures. The composition of 50% WEEE with 50% lignocellulosic biomass presented the best char properties, having an increment of the calorific value in 5.5% relative to the initial value, and chlorine removal of 23.4% when compared to the forestry biomass.

scholarly journals A Review on the Thermochemical Recycling of Waste Tyres to Oil for Automobile Engine Application

Energies ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3837
Author(s):  
Mohammad I. Jahirul ◽  
Farhad M. Hossain ◽  
Mohammad G. Rasul ◽  
Ashfaque Ahmed Chowdhury
Keyword(s):  
Diesel Engine ◽  
Engine Performance ◽  
Calorific Value ◽  
High Viscosity ◽  
Combustion Efficiency ◽  
Fuel Additive ◽  
Pyrolysis Oil ◽  
Performance And Emission ◽  
Automobile Engines ◽  
Direct Use

Utilising pyrolysis as a waste tyre processing technology has various economic and social advantages, along with the fact that it is an effective conversion method. Despite extensive research and a notable likelihood of success, this technology has not yet seen implementation in industrial and commercial settings. In this review, over 100 recent publications are reviewed and summarised to give attention to the current state of global tyre waste management, pyrolysis technology, and plastic waste conversion into liquid fuel. The study also investigated the suitability of pyrolysis oil for use in diesel engines and provided the results on diesel engine performance and emission characteristics. Most studies show that discarded tyres can yield 40–60% liquid oil with a calorific value of more than 40 MJ/kg, indicating that they are appropriate for direct use as boiler and furnace fuel. It has a low cetane index, as well as high viscosity, density, and aromatic content. According to diesel engine performance and emission studies, the power output and combustion efficiency of tyre pyrolysis oil are equivalent to diesel fuel, but engine emissions (NOX, CO, CO, SOX, and HC) are significantly greater in most circumstances. These findings indicate that tyre pyrolysis oil is not suitable for direct use in commercial automobile engines, but it can be utilised as a fuel additive or combined with other fuels.

STRUCTURAL CHARACTERISTICS OF (Ba,Sr)TiO3 THIN FILMS BY RAPID THERMAL ANNEALING

2007 ◽  
Vol 14 (01) ◽  
pp. 141-145
Author(s):  
Q. Y. ZHANG ◽  
S. W. JIANG ◽  
Y. R. LI
Keyword(s):  
Thin Films ◽  
Grain Size ◽  
Heating Rate ◽  
Thermal Annealing ◽  
Rapid Thermal Annealing ◽  
Rapid Heating ◽  
Structural Characteristics ◽  
High Heating Rate ◽  
Duration Time ◽  
Temperature Heating

The rapid thermal annealing (RTA) process was adapted to crystallize the amorphous ( Ba,Sr ) TiO 3 thin films prepared on Si (111) substrates by RF magnetic sputtering deposition. The effect of annealing temperature, heating rate and duration time on crystallization was studied through X-ray diffraction and atomic force microscopy. The result shows that the crystallinity and grain size were strongly dependent on the temperature, heating rate, and duration time. Higher heating rate leads to smaller grain size. In high heating rate, the grain size shows different dependence of temperature from that of low heating rate. For a heating rate of 50°C/s, the grain size decreased with temperature increasing below 700°C, while after that temperature, the grain size increased slightly with the temperature increasing. At a certain temperature, the crystallinity and surface roughness improved with increase in annealing time, while grain size changed little. The effect of rapid heating rate on the nucleation and grain growth has been discussed, which contributes to the limited grain size of the annealed ( Ba,Sr ) TiO 3 thin films.

scholarly journals Enhanced Separation of Oil and Solids in Oily Sludge by Froth Flotation at Normal Temperature

Processes ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 2163
Author(s):  
Wenying Li ◽  
Hongyang Lin ◽  
Yang Yang ◽  
Zhenxiao Shang ◽  
Qiuhong Li ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Oil Content ◽  
Froth Flotation ◽  
Hazardous Materials ◽  
Impeller Speed ◽  
Oily Sludge ◽  
Shear Effect ◽  
Flotation Reagent ◽  
Shengli Oilfield ◽  
Pulp Viscosity

Oily sludge (OS) contains a large number of hazardous materials, and froth flotation can achieve oil recovery and non-hazardous disposal of OS simultaneously. The influence of flotation parameters on OS treatment and the flotation mechanism were studied. OS samples were taken from Shengli Oilfield in May 2017 (OSS) and May 2020 (OST), respectively. Results showed that Na2SiO3 was the suitable flotation reagent treating OSS and OST, which could reduce the viscosity between oil and solids. Increasing flotation time, impeller speed and the ratio of liquid to OS could enhance the pulp shear effect, facilitate the formation of bubble and reduce pulp viscosity, respectively. Under the optimized parameters, the oil content of OST residue could be reduced to 1.2%, and that of OSS could be reduced to 0.6% because of OSS with low heavy oil components and wide solid particle size distribution. Orthogonal experimental results showed that the impeller speed was the most significant factor of all parameters for OSS and OST, and it could produce shear force to decrease the intensity of C-H bonds and destabilize the OS. The oil content of residue could be reduced effectively in the temperature range of 24–45 °C under the action of high impeller speed.

Analysis of Bio-Oil Produced by Co-Pyrolysis of Mahua Seed and Polystyrene

2015 ◽  
Vol 787 ◽  
pp. 771-775
Author(s):  
Debalaxmi Pradhan ◽  
R.K. Singh
Keyword(s):  
Heating Rate ◽  
Fossil Fuel ◽  
Synergetic Effect ◽  
Blend Ratio ◽  
Yield And Quality ◽  
Bio Oil ◽  
Quality Of Products ◽  
Temperature Heating

TheProduction of biofuel from biomass sources is believed to reduce the reliance of fossil fuel and its cost. This investigation was aimed to produce and characterize the bio-oil obtained from co-pyrolysis. Two different feed stocks were used for co-pyrolysis; one is Mahua seed (MS) and the other one is Polystyrene (PS). The effect in addition of plastic to biomass in pyrolysis process were investigated on the yield and quality of products. Experiments were conducted in a semi-batch pyrolysis reactor under various parameters of temperature, heating rate and blending ratio. The results indicated that a temperature of 525 °C, and blend ratio of 1:1is maximumwith a heating rate of 20 °C/min. The yield of bio-oil obtained from the co-pyrolysis was found to be approximately 71%, which was higher about 22% than that of yield obtained from pyrolysis of Mahua seed (MS) alone. Further the bio-oil was characterized using different spectroscopic and chromatographic analyses. The analysis of the results for characterization of bio-oil indicated that the synergetic effect increased the bio-oil yield and its quality.

Biosurfactants as demulsifying agents for oil recovery from oily sludge – performance evaluation

2013 ◽  
Vol 67 (12) ◽  
pp. 2875-2881 ◽  
Author(s):  
Evans M. N. Chirwa ◽  
Tshepo Mampholo ◽  
Oluwademilade Fayemiwo
Keyword(s):  
Oil Recovery ◽  
Sodium Dodecyl ◽  
Cost Effective ◽  
Solid Particles ◽  
Second Step ◽  
Oily Sludge ◽  
Waste Sludge ◽  
Complex Interactions ◽  
Oil Water ◽  
Living Organisms

The oil producing and petroleum refining industries dispose of a significant amount of oily sludge annually. The sludge typically contains a mixture of oil, water and solid particles in the form of complex slurry. The oil in the waste sludge is inextractible due to the complex composition and complex interactions in the sludge matrix. The sludge is disposed of on land or into surface water bodies thereby creating toxic conditions or depleting oxygen required by aquatic animals. In this study, a fumed silica mixture with hydrocarbons was used to facilitate stable emulsion (‘Pickering’ emulsion) of the oily sludge. The second step of controlled demulsification and separation of oil and sludge into layers was achieved using either a commercial surfactant (sodium dodecyl sulphate (SDS)) or a cost-effective biosurfactant from living organisms. The demulsification and separation of the oil layer using the commercial surfactant SDS was achieved within 4 hours after stopping mixing, which was much faster than the 10 days required to destabilise the emulsion using crude biosurfactants produced by a consortium of petrochemical tolerant bacteria. The recovery rate with bacteria could be improved by using a more purified biosurfactant without the cells.

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