scholarly journals Thermodynamics Studies for 6-(4-chlorophenyl)-1,2,3,4-tetrahydro-4-oxo-2-thioxopyrimidine-5-carbonitrile in 60% Dimethyl Sulphoxide at Different Temperatures

2020 ◽  
Vol 36 (6) ◽  
pp. 1240-1242
Author(s):  
Manoj R. Gaware
Keyword(s):  
Low Temperatures ◽  
Ternary Mixture ◽  
Dimethyl Sulphoxide ◽  
Thermodynamic Study ◽  
Entropy Term ◽  
Different Temperatures ◽  
Structure Breaking

Viscometric studies for ternary mixture of 6-(4-chlorophenyl)-1,2,3,4-tetrahydro-4-oxo-2-thioxopyrimidine-5-carbonitrile in 60% dimethyl sulphoxide was carried out at different temperatures ranging between 298 and 313 K over different concentration. From viscometric data ΔG, ΔS and ΔH were evaluated. The result shows that the magnitude of ΔG and ΔH are negative while ΔS is positive showing spontaneity of reaction according to thermodynamics pointing structure breaking takes place between solute and solvent. As ΔH is negative and ΔS positive, the reaction is spontaneous at low temperatures (decreasing the magnitude of the entropy term). The thermodynamic study reveals that as concentration increases spontaneity of reaction decreases.

scholarly journals A Comparative Electrochemical and Morphological Investigation on the Behavior of NiCr and CoCr Dental Alloys at Various Temperatures

Metals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 256
Author(s):  
Florentina Golgovici ◽  
Mariana Prodana ◽  
Florentina Gina Ionascu ◽  
Ioana Demetrescu
Keyword(s):  
Low Temperatures ◽  
Artificial Saliva ◽  
Electrochemical Stability ◽  
Morphological Investigation ◽  
Dental Alloys ◽  
Ion Release ◽  
Icp Ms ◽  
Different Temperatures ◽  
Good Concordance ◽  
Increasing Temperature

The purpose of our study is to compare the behavior of two reprocessed dental alloys (NiCr and CoCr) at different temperatures considering the idea that food and drinks in the oral cavity create various compositions at different pH levels; the novelty is the investigation of temperature effect on corrosion parameters and ion release of dental alloys. Electrochemical stability was studied together with morphology, elemental composition and ions release determination. The results obtained are in good concordance: electrochemistry studies reveal that the corrosion rate is increasing by increasing the temperature. From SEM coupled with EDS, the oxide film formed on the surface of the alloys is stable at low temperatures and a trend to break after 310K. ICP-MS results evidence that in accordance with increasing temperature, the quantities of ions released from the alloys immersed in artificial saliva also increase, though they still remain small, less than 20 ppm.

Kinetics and Mechanism of Oxidation of Aliphatic Secondary Alcohols by Benzimidazolium Fluorochromate in Dimethyl Sulphoxide Solvent

2021 ◽  
Vol 37 (3) ◽  
pp. 626-633
Author(s):  
Bhawana Arora ◽  
Jitendra Ojha ◽  
Pallavi Mishra
Keyword(s):  
Activation Parameters ◽  
Sigmatropic Rearrangement ◽  
Dimethyl Sulphoxide ◽  
Secondary Alcohols ◽  
Hydrogen Ions ◽  
Reaction Conditions ◽  
First Order Kinetics ◽  
Aqueous Solvent ◽  
Ester Formation ◽  
Different Temperatures

Oxidation of secondary alcohols is an important part of synthetic organic chemistry. Various studies are carried out at different reaction conditions to determine the best mechanistic pathways. In our study, oxidation of different secondary alcohols was done by using Benzimidazolium Fluorochromate in Dimethyl Sulphoxide, which is a non-aqueous solvent. Oxidation resulted in the formation of ketonic compounds. The reaction showed first order kinetics both in BIFC and in the alcohols. Hydrogen ions were used to catalyze the reaction. We selected four different temperatures to carry out our study. The correlation within the activation parameters like enthalpies and entropies was in accordance with the Exnerʼs criterion. The deuterated benzhydrol (PhCDOHPh) oxidation exhibited an important primary kinetic isotopic effect (kH / kD = 5.76) at 298 K. The solvent effect was studied using the multiparametric equations of Taft and Swain. There was no effect of addition of acrylonitrile on the oxidation rate. The mechanism involved sigmatropic rearrangement with the transfer of hydrogen ion taking place from alcohol to the oxidant via a cyclic chromate ester formation.

scholarly journals The effects of environmental temperature on the properties of myofibrillar adenosine triphosphatase from various species of fish

1973 ◽  
Vol 133 (4) ◽  
pp. 735-738 ◽  
Author(s):  
Ian A. Johnston ◽  
Neil Frearson ◽  
Geoffrey Goldspink
Keyword(s):  
Low Temperatures ◽  
Half Life ◽  
Adenosine Triphosphatase ◽  
Environmental Temperature ◽  
Cold Water ◽  
Warm Water ◽  
Adenosine Triphosphatase Activity ◽  
Water Fish ◽  
Different Temperatures ◽  
Myotomal Muscle

1. Myofibrillar adenosine triphosphatase (ATPase) activities were measured for white myotomal muscle of 19 species of fish. 2. The activity was measured at different temperatures and after periods of preincubation at 37°C. 3. The inactivation half-life at 37°C depended on environmental temperature, increasing as the temperature increased. 4. Cold-water fish had higher myofibrillar adenosine triphosphatase activity at low temperatures than had warm-water fish. 5. The significance of these results is discussed.

scholarly journals CONSEQUENCES OF PRESOWING INFLUENCE OF LOW AND VARIABLE TEMPERATURES ON CARROT AND RADISH SEEDS

2019 ◽  
pp. 62-64
Author(s):  
S. R. Gasanov ◽  
S. A. Mammadova
Keyword(s):  
Low Temperatures ◽  
Raphanus Sativus ◽  
Seed Treatment ◽  
Growth And Yield ◽  
Average Weight ◽  
Vegetable Crops ◽  
Root Crops ◽  
Different Temperatures ◽  
Sowing Seed ◽  
The Impact

The study of the dynamics of plant growth and yield of vegetable crops (carrot variety Absheron winter (Daucus carota subsp. sativus (Hoffm.) Schьbl.) and radish variety Virovsky white (Raphanus sativus var.radicula Pers.)) was conducted in the field conditions after presowing exposure to different temperatures: I option – sowing of seeds exposed to low temperatures (for 15 days the swollen for 24 hours seeds were kept at a temperature of 0±1°С); Option II - sowing of seeds exposed to variable temperatures (for 5 days, the swollen for 24 hours seeds were exposed to variable temperatures of + 20°C (8 hours) and 0±1°C (16 hours) and then 10 days at a temperature of 0±1°C; K1 – sowing dry seeds; K2 – sowing soaked seeds. The impact on the seeds of low and variable temperatures caused an increase in growth processes, both in radish and carrot. Both studied crops showed a tendency to increase the yield to a greater extent when exposed to swollen seeds with variable temperatures. Thus, the average weight of radish crops exceeded the control variant by 47.1% and carrots by 27.6%. The yield of root crops per m2increased by 36.4% for radish and 30.0% for carrot. To increase the productivity of vegetable crops, we recommend using the studied methods of pre-sowing seed treatment in practice.

Thermodynamic study and preferential solvation of sulfamerazine in acetonitrile + methanol cosolvent mixtures at different temperatures

2021 ◽  
pp. 118172
Author(s):  
Rossember E. Cárdenas ◽  
Claudia Patricia Ortiz ◽  
William E. Acree Jr ◽  
Abolghasem Jouyban ◽  
Fleming Martínez ◽  
...  
Keyword(s):  
Preferential Solvation ◽  
Thermodynamic Study ◽  
Different Temperatures ◽  
Cosolvent Mixtures

scholarly journals Unbeeinflußbarkeit ihrer Wirkung auf Ribonuclease durch Cystamin und tiefe Temperaturen

1966 ◽  
Vol 21 (12) ◽  
pp. 1165-1170 ◽  
Author(s):  
H. Jung
Keyword(s):  
Cross Section ◽  
Low Temperatures ◽  
Room Temperature ◽  
High Efficiency ◽  
Reduction Factor ◽  
Biological Damage ◽  
Nuclear Collisions ◽  
Different Temperatures ◽  
Fast Protons ◽  
Mev Protons

Slow protons having energies below 1.5 keV dissipate their kinetic energy in matter through elastic nuclear collisions. By this process atoms are displaced out from their original positions in macromolecules. This was recently shown to cause biological damage with high efficiency. Experiments are described to test the possibility of modifying the sensitivity of ribonuclease towards elastic collisions by protective agents and by low temperatures. When cystamine is present during irradiation dry ribonuclease is protected against the action of “ionizing” fast protons (2 MeV), the dose reduction factor being 1.8. But no protection is observed when inactivation is achieved by elastic nuclear collisions (proton energy 1 keV and 1.4 keV). Similar results were obtained when the irradiations were carried out at different temperatures. Using 2 MeV protons the radiosensitivity of ribonuclease was found to be 3 times higher at room temperature than at 125 °K, but when using slow protons of 1.4 keV energy the inactivation cross section turned out to be independent of temperature. This shows that the action of elastic nuclear collisions can be modified neither by cystamine nor by low temperatures.

Thermodynamic study of the NaCl + MgCl2 + H2O mixed system by emf measurements at different temperatures

1997 ◽  
Vol 101 (8) ◽  
pp. 1136-1145 ◽  
Author(s):  
Felipe Hernández-Luis ◽  
Luis Fernández-Mérida ◽  
Miguel A. Esteso ◽  
Héctor R. Galleguillos-Castro
Keyword(s):  
Thermodynamic Study ◽  
Mixed System ◽  
Emf Measurements ◽  
Different Temperatures

scholarly journals The effects of low temperatures on intracellular transport of newly synthesized albumin and haptoglobin in rat hepatocytes

1986 ◽  
Vol 237 (1) ◽  
pp. 33-39 ◽  
Author(s):  
E Fries ◽  
I Lindström
Keyword(s):  
Endoplasmic Reticulum ◽  
Golgi Complex ◽  
Low Temperatures ◽  
Intracellular Transport ◽  
Rat Hepatocytes ◽  
Subcellular Fractionation ◽  
Isolated Rat Hepatocytes ◽  
Different Temperatures ◽  
Lag Period ◽  
Time Courses

Isolated rat hepatocytes were pulse-labelled with [35S]methionine at 37 degrees C and subsequently incubated (chased) for different periods of time at different temperatures (37-16 degrees C). The time courses for the secretion of [35S]methionine-labelled albumin and haptoglobin were determined by quantitative immunoprecipitation of the detergent-solubilized cells and of the chase media. Both proteins appeared in the chase medium only after a lag period, the length of which increased markedly with decreasing chase temperature: from about 10 and 20 min at 37 degrees C to about 60 and 120 min at 20 degrees C for albumin and haptoglobin respectively. The rates at which the proteins were externalized after the lag period were also strongly affected by temperature, the half-time for secretion being 20 min at 37 degrees C and 200 min at 20 degrees C for albumin; at 16 degrees C no secretion could be detected after incubation for 270 min. Analysis by subcellular fractionation showed that part of the lag occurred in the endoplasmic reticulum and that the rate of transfer to the Golgi complex was very temperature-dependent. The maximum amount of the two pulse-labelled proteins in Golgi fractions prepared from cells after different times of chase decreased with decreasing incubation temperatures, indicating that the transport from the Golgi complex to the cell surface was less affected by low temperatures than was the transport from the endoplasmic reticulum to the Golgi complex.

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