scholarly journals Studies on Precision and Accuracy In Microdetermination of Transition Metals Using Ternary Complex EAB-CTAB-Metals

2018 ◽  
Vol 34 (4) ◽  
pp. 1930-1936
Author(s):  
Suparna Deshmukh
Keyword(s):  
Metal Ions ◽  
Absorption Spectra ◽  
Ternary Complex ◽  
Cetyl Trimethyl Ammonium Bromide ◽  
Transition Metal Ions ◽  
Ammonium Bromide ◽  
Sodium Potassium ◽  
Ph Values ◽  
Precision And Accuracy ◽  
Cetyl Trimethyl Ammonium

Complexometric and Analytical studies have carried out by forming ternary complex between Eriochrome Azurol B, and Cetyl Trimethyl Ammonium Bromide CTAB; and some transition metal ions mainly Cu2+, Ni2+ and Cd2+. The absorption spectra of Eriochrome Azurol B ,EAB; a triphenylmethane dye, has studied in the presence as well as in the absence of surfactant, Cetyl Trimethyl Ammonium Bromide, CTAB at pH values ranging from pH 1.00 to 12.00. Hypsochromic shift is observed in the absorption spectra in the presence of surfactant pK values i.e. dissociation constant values are found to decreased, in the presence of surfactant is observed. Composition of chelates EAB:CTAB:Metal is found to be 1:1:1, and effect of foreign ions such as chlorides, nitrates; and sulphates of sodium, potassium and ammonium; has been studied in detail. Stability constants of the chelates are determined. Sensitivity and Stability of chelates formedincreases in the presence of surfactant. Various analytical parameters including range of adherence to Beers Law, Molar Extinction Constants, Sandells Sensitivity, were studied for all systems by its interaction with and without CTAB. Precision and Accuracy of the method suggested for microdetermination of metal ions is determined and found out that method is both precise as well as accurate.

Study on Separation/Enrichment of Trace Nickel in Water Samples Using Ammonium Sulfate-Dithizone-Cetyl Trimethyl Ammonium Bromide System

2014 ◽  
Vol 665 ◽  
pp. 233-236
Author(s):  
Chang Qing Tu ◽  
Xin Rong Wen
Keyword(s):  
Metal Ions ◽  
Ammonium Sulfate ◽  
Water Samples ◽  
Cetyl Trimethyl Ammonium Bromide ◽  
Ammonium Bromide ◽  
Optimum Conditions ◽  
Novel Method ◽  
Cetyl Trimethyl Ammonium

The paper presents a novel method for the separation/enrichment of trace Ni2+ using (NH4)2SO4-dithizone(H2Dz)-cetyl trimethyl ammonium bromide(CTMAB) system.The effects of different parameters on the enrichment yield of Ni2+ have been investigated. The possible enrichment mechanism of Ni2+ was discussed.The results showed that under the optimum conditions,the water-insoluble chelate of Ni(H2Dz)2 which formed by Ni2+ and H2Dz was quantificationally floated onto CTMAB foam phase.In this condition, Cd2+、Zn2+、Mn2+、Fe2+ and Co2+ could not be floated.Therefore, Ni2+ was separated completely from the above metal ions. The proposed method has been successfully applied to the separation/enrichment of Ni2+ in various water samples, and the recoveries were 94.2%～103.8%.

scholarly journals Metal Binding Proteins

Encyclopedia ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 261-292
Author(s):  
Eugene A. Permyakov
Keyword(s):  
Metal Ions ◽  
Metal Binding ◽  
Transition Metal Ions ◽  
Short Review ◽  
Sodium Potassium ◽  
Physical Chemical ◽  
Physiological Properties ◽  
Cell Processes ◽  
Living Organisms ◽  
Potassium Magnesium

Metal ions play several major roles in proteins: structural, regulatory, and enzymatic. The binding of some metal ions increase stability of proteins or protein domains. Some metal ions can regulate various cell processes being first, second, or third messengers. Some metal ions, especially transition metal ions, take part in catalysis in many enzymes. From ten to twelve metals are vitally important for activity of living organisms: sodium, potassium, magnesium, calcium, manganese, iron, cobalt, zinc, nickel, vanadium, molybdenum, and tungsten. This short review is devoted to structural, physical, chemical, and physiological properties of proteins, which specifically bind these metal cations.

scholarly journals Preparation of Porous Hydroxyapatite Using Cetyl Trimethyl Ammonium Bromide as Surfactant for the Removal of Lead Ions from Aquatic Solutions

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1617
Author(s):  
Silviu-Adrian Predoi ◽  
Carmen Steluta Ciobanu ◽  
Mikael Motelica-Heino ◽  
Mariana Carmen Chifiriuc ◽  
Monica Luminita Badea ◽  
...  
Keyword(s):  
Cetyl Trimethyl Ammonium Bromide ◽  
Morphological Changes ◽  
Low Cost ◽  
Lead Ions ◽  
Ammonium Bromide ◽  
Porous Hydroxyapatite ◽  
X Ray ◽  
Composition And Structure ◽  
Cetyl Trimethyl Ammonium ◽  
Co Precipitation

In the present study, a new low-cost bioceramic nanocomposite based on porous hydroxyapatite (HAp) and cetyl trimethyl ammonium bromide (CTAB) as surfactant was successfully obtained by a simple chemical co-precipitation. The composition and structure of the HAp-CTAB were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM), scanning electron microscope (SEM) equipped with an energy dispersive X-ray (EDX) spectrometer, and N2 adsorption/desorption analysis. The capacity of HAp-CTAB nanocomposites to remove the lead ions from aqueous solutions was studied by adsorption batch experiments and proved by Langmuir and Freundlich models. The Pb2+ removal efficiency of HAp-CTAB biocomposite was also confirmed by non-destructive ultrasound studies. The cytotoxicity assays showed that the HAp-CTAB nanocomposites did not induce any significant morphological changes of HeLa cells after 24 h of incubation or other toxic effects. Taken together, our results suggests that the obtained porous HAp-CTAB powder could be used for the decontamination of water polluted with heavy metals, such as Pb2+.

Influence of Different Dispersants on the Dispersion Property of Nano-Aluminium Powders

2011 ◽  
Vol 71-78 ◽  
pp. 122-125 ◽  
Author(s):  
Ling Li Song ◽  
Ren Yuan Zhang ◽  
Ling Bo Mao ◽  
Wen Jie Zhu ◽  
Miao Yan Zheng
Keyword(s):  
Sodium Dodecyl Sulfate ◽  
Ultrasonic Vibration ◽  
Cetyl Trimethyl Ammonium Bromide ◽  
Sodium Dodecyl ◽  
Dispersion Property ◽  
Ammonium Bromide ◽  
Aluminum Powders ◽  
Ultrasonic Time ◽  
Dodecyl Sulfate ◽  
Cetyl Trimethyl Ammonium

The influences of dispersant type, supersonic time and concentration on the dispersion property of the nano-aluminium powders in glycol water were systematically studied by using Sodium dodecyl sulfate (SDS)，cetyl trimethyl ammonium bromide (CTAB) and sodium hexa metah posphate（SHMP）as dispersants. During the first stage of the experiments, influences of dispersant type and ultrasonic time with these dispersants were evaluated. The next stage of the study was focused on SHMP concentration. The influence of SHMP concentration was assessed. The results show that with the increasing of ultrasonic time, the dispersion property of nano-aluminum powders first increases and then decreases, and SHMP is the best one. The excellent dispersing condition on the dispersion property of nano-aluminium is: 5g/L SHMP and 50 min ultrasonic vibration.

scholarly journals SYNTHESIS OF COPPER NANOPARTICLES USING ASCORBIC ACID AND CETYL TRIMETHYL AMMONIUM BROMIDE

2018 ◽  
Vol 11 (14) ◽  
pp. 62
Author(s):  
Saurabh Singh ◽  
Bimlesh Kumar ◽  
Narendra Kumar Pandey ◽  
Barinder Kaur ◽  
Arun Kumar ◽  
...  
Keyword(s):  
Ascorbic Acid ◽  
Copper Nanoparticles ◽  
Cetyl Trimethyl Ammonium Bromide ◽  
Ammonium Bromide ◽  
Distilled Water ◽  
Bromide Solution ◽  
Cetyl Trimethyl Ammonium ◽  
Dialysis Bag ◽  
Spray Dried ◽  
Glass Beaker

Objective: The present study highlights the development of a method to synthesize copper nanoparticles (CuNPs).Methods: CuNPs were developed using 0.01 M copper penta sulfate and 0.11 M of ascorbic acid (AA) and 0.03 M of cetyl trimethyl ammonium bromide solution. The synthesized CuNPs were differentiated through filtration and washed by water (deionized). CuNPs were kept in dialysis bag 70 KD in a 250 mL glass beaker along with distilled water. The assembly was kept on a magnetic stirrer for 24 h at 500 rpm. Then, the dialysis bag containing CuNPs solution was filtered by a filter assembly with 0.2 μm nylon filter. The filtered CuNPs were spray dried with the help of spray drier.Results: The prepared CuNPs were found to be 440 nm with zeta potential of −10 mV and polydispersity index 0.314.Conclusion: The investigation deciphers the promising and material technique to synthesis of CuNPs by methods for synthetic reduction utilizing strategy using AA (0.2 M) and sodium hydroxide (1 M), and Syloid 244FP.

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