Synthesis and Characterization of 2-imino-3–(2-Hydroxylphenyl)-1- Thiazolidin-4-one Substituted Ammine Complexes of Cr(III), Co(III), Ni(II) and Cu(II)

2013 ◽  
Vol 29 (03) ◽  
pp. 1251-1256 ◽  
Author(s):  
ABADI HADUSH ◽  
R.K. UPADHYAY ◽  
TESFAHUN KEBEDE
Keyword(s):  
Synthesis And Characterization ◽  
Ammine Complexes

Synthesis and Characterization of Binuclear and Trinuclear Cobalt(III) Complexes With Imidazolate Bridges

1986 ◽  
Vol 39 (8) ◽  
pp. 1213 ◽  
Author(s):  
CJ Hawkins ◽  
E Horn ◽  
J Martin ◽  
JAL Palmer ◽  
MR Snow
Keyword(s):  
Crystal Structure ◽  
Absorption Spectra ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
The Other ◽  
Synthesis And Characterization ◽  
Ammine Complexes

Two cobalt(III) ammine complexes are described which have an imidazolate ( Im ) ligand bridging cobalt(III) centres . Their electronic absorption spectra, 1H, 13C and 59Co n.m.r . spectra, and electrochemical data are presented. One complex is a bis [ pentaamminecobalt (III)] complex, [(H3N)5Co( Im )Co(NH3)5]5+, and the other has two pentaammineimidazolatocobalt (III) units coordinated in the cis arrangement to tetraamminecobalt (III). The crystal structure of cis - [(NH3)4Co{( Im )Co(NH3)5}2]Cl2(S2O6)2(OH).3.5H2O is reported. The crystals in the form of orange needles are monoclinic: Cc, a 20.18(1), b 17.089(9), c 15.395(7) Ǻ, β 123.76(4)°, Z 4. The structure was refined to R 0.079.

Synthesis and Characterization of the Three Dicyclopentapyrenes

1996 ◽  
Vol 61 (10) ◽  
pp. 3572-3572
Author(s):  
Lawrence T. Scott ◽  
Atena Necula
Keyword(s):  
Synthesis And Characterization

Synthesis and characterization of TiN / Ti / AISI 410 coatings

2018 ◽  
Vol 2 (1) ◽  
pp. 7
Author(s):  
S Chirino ◽  
Jaime Diaz ◽  
N Monteblanco ◽  
E Valderrama
Keyword(s):  
Synthesis And Characterization ◽  
Photoemission Spectroscopy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Columnar Grains ◽  
Tin Thin Films ◽  
Steel Aisi ◽  
Interacting Surfaces ◽  
Stainless Steel Aisi

The synthesis and characterization of Ti and TiN thin films of different thicknesses was carried out on a martensitic stainless steel AISI 410 substrate used for tool manufacturing. The mechanical parameters between the interacting surfaces such as thickness, adhesion and hardness were measured. By means of the scanning electron microscope (SEM) the superficial morphology of the Ti/TiN interface was observed, finding that the growth was of columnar grains and by means of EDAX the existence of titanium was verified.  Using X-ray diffraction (XRD) it was possible to observe the presence of residual stresses (~ -3.1 GPa) due to the different crystalline phases in the coating. Under X-ray photoemission spectroscopy (XPS) it was possible to observe the molecular chemical composition of the coating surface, being Ti-N, Ti-N-O and Ti-O the predominant ones.

Sign in / Sign up

Export Citation Format

Share Document