scholarly journals Improved Photoresponse in Association with a Synthesized Dielectric Material for Quantum Dots Solar Cells

2019 ◽  
Vol 16 (3) ◽  
pp. 230-234
Author(s):  
Subhasis Roy ◽  
Argha Dey ◽  
Bhaskar Chandra Das

A worldwide investigation is being carried out for improving the photoconversion efficiency of solar cells. Among all solar cells, quantum dots solar cell (QDSC) has proven as the best potential for photocurrent generator. The major focus of this research work is comparing the performance of QD based solar cells with and without the addition of synthesized dielectric nanomaterials for reducing recombination problems and higher the exciton generation. The selection of dielectric nanomaterial was carried out based on their good field-effect passivation, screened columbic attraction, enactment as a back reflector, and recombination inhibitor in solar cell. According to the above-mentioned factors lanthanum doped lead titanate Pb0.85La0.15TiO3 (PLT15) is a promising material for this research work. For improving the performance of QD based solar cells, the PLT15 paired mesoporous TiO2 electron transport layer (ETL) film was deposited onto fluorine-doped tin oxide (FTO) coated glass substrate using doctor blading technique followed by annealing the QD deposition onto the coated glass substrate was carried out via dipping of the glass into the QD solution for overnight. The QD used in this research work were namely – PbI3. Finally, the performance study was carried out which indicates that the introduction of dielectric material into the QDSC has proven to be as innovative and as well as efficient for improving the photocurrent conversion efficiency.

2019 ◽  
Vol 43 (18) ◽  
pp. 7130-7135 ◽  
Author(s):  
Xiaomeng Zhu ◽  
Jing Sun ◽  
Shuai Yuan ◽  
Ning Li ◽  
Zhiwen Qiu ◽  
...  

The solar cell with carbon QDs-doped PCBM as its electron transporting layer shows the highest PCE of 18.1%.


Nanomaterials ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 121 ◽  
Author(s):  
Lung-Chien Chen ◽  
Ching-Ho Tien ◽  
Zong-Liang Tseng ◽  
Jun-Hao Ruan

We describe a method to enhance power conversion efficiency (PCE) of MAPbI3 perovskite solar cell by inserting a FAPbX3 perovskite quantum dots (QD-FAPbX3) layer. The MAPbI3 and QD-FAPbX3 layers were prepared using a simple, rapid spin-coating method in a nitrogen-filled glove box. The solar cell structure consists of ITO/PEDOT:PSS/MAPbI3/QD-FAPbX3/C60/Ag, where PEDOT:PSS, MAPbI3, QD-FAPbX3, and C60 were used as the hole transport layer, light-absorbing layer, absorption enhance layer, and electron transport layer, respectively. The MAPbI3/QD-FAPbX3 solar cells exhibit a PCE of 7.59%, an open circuit voltage (Voc) of 0.9 V, a short-circuit current density (Jsc) of 17.4 mA/cm2, and a fill factor (FF) of 48.6%, respectively.


2021 ◽  
Vol 34 (1) ◽  
pp. 58-63
Author(s):  
Naman Shukla ◽  
Dharamlal Prajapati ◽  
Sanjay Tiwari

Perovskite solar cells fabricated with inexpensive and simple technology exhibits high efficiency has witnessed worldwide boom in research. The optimization of solar cell can be done through modeling and simulation. The optical and electrical modeling are the ways to optimize different parameter such as thickness, defect density, doping density and material selection for fabricating stable and highly efficient perovskite solar cells. In this research work, electrical modeling of solar cell is done throughSolar Cell Capacitance Simulator(SCAPS-1D).The architecture of the solar cell is n-i-p device structure. CH3NH3PbI3-xClx acts as light absorber active layer, TiO2 as electron transport layer and Spiro-OMeTADas hole transport layer with device structure FTO/ TiO2/ CH3NH3PbI3-xClx/ Spiro-OMeTAD/Au. The open circuit voltage Voc, short circuit current density Isc, fill factor and power conversion efficiency are 1.28 V, 21.63 mA/cm2, 0.78 and 21.53% respectively. The result showed that the optimize parameter can be applied for fabrication of the solar cell experimentally. Various metal contact materials of the anodeare also studied and analyzed.


2021 ◽  
Author(s):  
Song Fang ◽  
Bo Chen ◽  
Bangkai Gu ◽  
Linxing Meng ◽  
Hao Lu ◽  
...  

UV induced decomposition of perovskite material is one of main factors to severely destroy perovskite solar cells for instability. Here we report a UV stable perovskite solar cell with a...


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
S. Wageh ◽  
Mahfoudh Raïssi ◽  
Thomas Berthelot ◽  
Matthieu Laurent ◽  
Didier Rousseau ◽  
...  

AbstractPoly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) mixed with single-wall nanotubes (SWNTs) (10:1) and doped with (0.1 M) perchloric acid (HClO4) in a solution-processed film, working as an excellent thin transparent conducting film (TCF) in organic solar cells, was investigated. This new electrode structure can be an outstanding substitute for conventional indium tin oxide (ITO) for applications in flexible solar cells due to the potential of attaining high transparency with enhanced conductivity, good flexibility, and good durability via a low-cost process over a large area. In addition, solution-processed vanadium oxide (VOx) doped with a small amount of PEDOT-PSS(PH1000) can be applied as a hole transport layer (HTL) for achieving high efficiency and stability. From these viewpoints, we investigate the benefit of using printed SWNTs-PEDOT-PSS doped with HClO4 as a transparent conducting electrode in a flexible organic solar cell. Additionally, we applied a VOx-PEDOT-PSS thin film as a hole transporting layer and a blend of PTB7 (polythieno[3,4-b] thiophene/benzodithiophene): PC71BM (phenyl-C71-butyric acid methyl ester) as an active layer in devices. Zinc oxide (ZnO) nanoparticles were applied as an electron transport layer and Ag was used as the top electrode. The proposed solar cell structure showed an enhancement in short-circuit current, power conversion efficiency, and stability relative to a conventional cell based on ITO. This result suggests a great carrier injection throughout the interfacial layer, high conductivity and transparency, as well as firm adherence for the new electrode.


2015 ◽  
Vol 15 (11) ◽  
pp. 8790-8796 ◽  
Author(s):  
Eung-Kyu Park ◽  
Jae-Hyoung Kim ◽  
Dong-Hoon Lee ◽  
Kwang-Su Kim ◽  
Jin-Ha Kal ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (24) ◽  
pp. 14534-14541
Author(s):  
M. S. Chowdhury ◽  
Kazi Sajedur Rahman ◽  
Vidhya Selvanathan ◽  
A. K. Mahmud Hasan ◽  
M. S. Jamal ◽  
...  

Organic–inorganic perovskite solar cells (PSCs) have recently emerged as a potential candidate for large-scale and low-cost photovoltaic devices.


2021 ◽  
Vol 24 (3) ◽  
pp. 341-347
Author(s):  
K. Bhavsar ◽  
◽  
P.B. Lapsiwala ◽  

Perovskite solar cells have become a hot topic in the solar energy device area due to high efficiency and low cost photovoltaic technology. However, their function is limited by expensive hole transport material (HTM) and high temperature process electron transport material (ETM) layer is common device structure. Numerical simulation is a crucial technique in deeply understanding the operational mechanisms of solar cells and structure optimization for different devices. In this paper, device modelling for different perovskite solar cell has been performed for different ETM layer, namely: TiO2, ZnO, SnO2, PCBM (phenyl-C61-butyric acid methyl ester), CdZnS, C60, IGZO (indium gallium zinc oxide), WS2 and CdS and effect of band gap upon the power conversion efficiency of device as well as effect of absorber thickness have been examined. The SCAPS 1D (Solar Cell Capacitance Simulator) has been a tool used for numerical simulation of these devices.


2022 ◽  
Vol 12 (1) ◽  
Author(s):  
Dong In Kim ◽  
Ji Won Lee ◽  
Rak Hyun Jeong ◽  
Jin-Hyo Boo

AbstractOver the past number of years, the power conversion efficiency of perovskite solar cells has remained at 25.5%, reflecting a respectable result for the general incorporation of organometallic trihalide perovskite solar cells. However, perovskite solar cells still suffer from long-term stability issues. Perovskite decomposes upon exposure to moisture, thermal, and UV-A light. Studies related to this context have remained ongoing. Recently, research was mainly conducted on the stability of perovskite against non-radiative recombination. This study improved a critical instability in perovskite solar cells arising from non-radiative recombination and UV-A light using a passivation layer. The passivation layer comprised a polyaniline (PANI) polymer as an interfacial modifier inserted between the active layer and the electron transport layer. Accordingly, the UV-A light did not reach the active layer and confined the Pb2+ ions at PANI passivation layer. This study optimized the perovskite solar cells by controlling the concentration, thickness and drying conditions of the PANI passivation layer. As a result, the efficiency of the perovskite solar cell was achieved 15.1% and showed over 84% maintain in efficiency in the ambient air for one month using the 65 nm PANI passivation layer.


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