scholarly journals Upconversion and Spectroscopic Properties of Rare Earth Codoped Lead Borate Glass Matrix

2017 ◽  
Vol 14 (2) ◽  
pp. 140-145 ◽  
Author(s):  
K. Goud ◽  
Ch. Ramesh ◽  
B. Appa Rao

To develop efficient upconversion laser materials in the visible region an active lead borate glasses doped with Er3+/Yb3+ rare earth ions (GEY) has been studied extensively. In this investigation characterization techniques like Optical absorption, FTIR and photoluminescence were recorded and the data was analyzed. To evaluate the values of Ω2, Ω4 and Ω6 Judd-Ofelt theory has been applied to the f ↔ f transitions. Based on Judd–Ofelt theory branching ratio (βr) oscillator strength and the radiative life time (τR) values were determined. The upconversion spectra exhibited three emission bands at around 525 nm (2H11/2 ® 4I15/2), 545 nm (4S3/2 ® 4I15/2) and 660 nm (4F9/2 ® 4I15/2). The energy transfer mechanism between Yb3+ and Er3+ was discussed very clearly. Comparing the data obtained in other Er3+/Yb3+ doped materials, the lead bismuth gallium borate glasses doped with 0.6 mol% of Er2O3­/0.2 mol% of Yb2O3 ions are suitable materials for developing red upconversion lasers in the visible region.

Laser Physics ◽  
2010 ◽  
Vol 20 (3) ◽  
pp. 649-655 ◽  
Author(s):  
W. A. Pisarski ◽  
Ł. Grobelny ◽  
J. Pisarska ◽  
R. Lisiecki ◽  
G. Dominiak-Dzik ◽  
...  

1986 ◽  
Vol 41 (6) ◽  
pp. 866-870 ◽  
Author(s):  
H.-D. Autenrieth ◽  
S. Kemmler-Sack

By activation of the new host lattices Ba2La2B2+Te2O12 (B = Zn, Mg) with trivalent rare earth ions Ln3+ = Pr. Sm, Eu, Tb, Dy, Ho, Tm an emission in the visible region is observed. The influence of the electronic structure and concentration on the relative emission efficiency as well as the host lattice participation in the energy transfer processes are discussed.


2018 ◽  
Vol 215 (16) ◽  
pp. 1700889 ◽  
Author(s):  
Renata Ratajczak ◽  
Elzbieta Guziewicz ◽  
Slawomir Prucnal ◽  
Grzegorz Łuka ◽  
Roman Böttger ◽  
...  

1985 ◽  
Vol 40 (5) ◽  
pp. 503-507 ◽  
Author(s):  
R. Braun ◽  
R. Otto ◽  
W. Wischert ◽  
S. Kemmler-Sack

By activation of the host lattices Sr3La2W2O12 and Ca2La0,5Na0,5WO6 with the trivalent rare earth ions Ln3+ = Pr, Sm, Eu, Tb, Dy, Ho, Er a cathodoluminescence in the visible region is obtained. The influence of the electronic structure and concentration of the activator on the relative emission efficiency as well as the host lattice participation in the energy transfer processes are discussed.


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